Project Research Center for Fundamental Sciences, Graduate School of Science, Osaka University Harada Group
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Recognition of Polymer Side Chains by Cyclodextrins

Enhancement of the Selectivity by the Steric Effect of Polymer Main Chain Stimuli-Responsive Hydrogels
Enhancement of the Selectivity by Multi-Site Interaction Side Chain Polyrotaxanes with Unidirectional Inclusion
Interaction of Cyclodextrins with Polymer Micelles    

Stimuli-Responsive Hydrogels

Stimuli-responsive hydrogels are obtained from cyclodextrins, dodecyl-modified poly(sodium acrylate), and stimuli-responsive competitive guests.
(Tomatsu, I. et al. Macromolecules 2005, 38, 5223-5227; Tomatsu, I. et al. Macromol. Rapid Commun. 2006, 27, 238-241.)

Photoresponsive systems which exhibit contrasting viscosity changes are constructed from cyclodextrin-modified poly(sodium acrylate)s and azobenzene-modified poly(sodium acrylate)
(Tomatsu, I. et al. J. Am. Chem. Soc. 2006, 128, 2226-2227)

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