大阪大学大学院理学研究科 附属基礎理学プロジェクト研究センター 原田グループ ロゴ
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Publication List (2010-2006)


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2010

Photoswitchable Supramolecular Hydrogels Formed by Cyclodextrin and Azobenzene Polymers
Tamesue, S.; Takashima, Y.;Yamaguchi, H.; Shinkai, S.; Harada, A.
Angew. Chem. 2010, 122 (41), 7623-7626; Angew. Chem. Int. Ed. 2010, 49 (41), 7461-7464.

Switching from altro-α-Cyclodextrin
Dimer to pseudo[1]Rotaxane Dimer through Tumbling

Yamauchi, K.; Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Org. Lett. 2010, 12 (6), 1284-1286.

Formation of Side-Chain hetero-Polypseudorotaxane Composed of α- and β-Cyclodextrins with a Water-Soluble Polymer Bearing Two Recognition Sites
Taura, D.; Li, S.; Hashidzume, A.; Harada, A.
Macromolecules 2010, 43, 1706-1713.

A Molecular Reel: Shuttling of a Rotor by Tumbling of a Macrocycle
Yamauchi, K.; Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Org. Chem. 2010,75(4), 1040-1046.
[J. Org. Chem. Featured Article]

Supramolecular Polymers Based on Cyclodextrins and Their Derivatives
Harada, A.;Hashidzume, A
Aust. J. Chem. 2010, 63, 599-610.

Photocontrolled Size Changes of Doubly-Threaded Dimer Based on an α-CD Derivative with Two Recognition Sites
Li, S.; Taura, D.; Hashidzume, A.; Takashima, Y.; Yamaguchi, H.; Harada A.
Chem. Lett. 2010, 39(3), 242-243.

Light-Switchable Janus [2]Rotaxanes Based on α-Cyclodextrin Derivatives Bearing Two Recognition Sites Linked with Oligo(ethylene glycol)
Li, S.; Taura, D.; Hashidzume, A.; Harada A.
Chem. Asian. J. 2010, 5 (10), 2281-2289.

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2009

Polymeric Rotaxanes
Harada, A.; Hashidzume, A.; Yamaguchi, H.; Takashima, Y.
Chem. Rev. 2009, 109(11), 5974-6023.

Cyclodextrin-Based Supramolecular Polymers
Harada, A.; Takashima, Y.; Yamaguchi, H.
Chem. Soc. Rev.
2009, 38, 875 - 882.

Social Self-Sorting: Alternating Supramolecular Oligomer Consisting of Isomers
Tomimasu, N.; Kanaya, A.; Takashima,Y.; Yamaguchi, H.; Harada, A.*
J. Am. Chem. Soc. 2009, 131(34), 12339-12343.

Face Selective Translation of a Cyclodextrin Ring along an Axle
Oshikiri, T.; Yamaguchi, H.; Takashima, Y.; Harada, A.
Chem. Commun. 2009, (37), 5515-5517.
[Chem. Commun.  Hot Article !!]     [A News Release]       [A News Release]
Cover Picture: Chem. Commun.

Macromolecular Recognition of Cyclodextrin: Inversion of Selectivity of beta-Cyclodextrin toward Adamantyl Groups Induced by Macromolecular Chains
Taura, D.; Taniguchi, Y.; Hashidzume, A.; Harada, A.*
Macromol. Rapid Commun. 2009, 30(20), 1741-1744.

Nanospheres with Polymerization Ability Coated by Polyrotaxane
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Org. Chem.2009, 74 (5), 1858-1863.

Artificial Polymerases and Molecular Chaperones (Highlight)
Harada, A.
J. Polym. Sci. Part A: Polymer Chemistry 2009, 47(18), 4469-4481.
Cover Picture: J. Polym. Sci. Part A.

Switching of Polymerization Activity of Cinnamoyl-alpha-Cyclodextrin
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Org. Biomol. Chem. 2009, 7, 1646 - 1651.

Asymmetric Hydrogenation with Antibody–Achiral Rhodium Complex
Yamaguchi, H.; Hirano, T.; Kiminami, H.; Harada, A.
J. Biol. Inorg. Chem. 2009, 14 (S1), S128-S129.

Photo-Polymerization of Amphiphilic N,O-Diacylated Serine Based Monomers in their Micellar States for an Encapsulation
Tomatsu, I.; Hashidzume, A.; Harada, A.*
Macromol. Chem. Phys. 2009, 210(19), 1640-1646.

Supramolecular Assemblies of Oligothiophene Derivatives Bearing β-Cyclodextrin
Sakamoto, K.; Takashima, Y.; Yamaguchi, H.; Harada, A.

Synthetic Metals 2009, 159, (9-10), 977-981.

Photoinduced Hydrogen Evolution System with an Antibody-Porphyrin Complex as a Photosensitizer
Yamaguchi, H.; Onji, T.; Ohara, H.; Ikeda, N.; Harada, A.*
Bull. Chem. Soc. Jpn. 2009, 82(11), 1341-1346.
BCSJ Award Article.

Self-Assembly of One- and Two-Dimensional Hemoprotein Systems by Polymerization through Heme-Heme Pocket Interactions
Kitagishi, H.; Kakikura, Y.; Yamaguchi, H.; Oohora, K.; Harada, A.; Hayashi, T.
Angew. Chem. Int. Ed. 2009, 48(7), 1271-1274.
Inside Cover: Angew. Chem. Int. Ed.

Supramolecular Polymers
Hashidzume, A.; Harada, A.
Nettowaku Porima 2009, 30, 273-282.

超分子の動的機能発現ー分子マシンのブレークスルー
原田明
別冊化学 化学のブレークスルー[有機化学編], 化学同人編集部編, 化学同人, 2009, 77-80.

共役高分子の超分子形成による機能化に関する研究
高島義徳, 原田明
次世代共役ポリマーの超階層制御と革新機能, 赤木和夫監修, CMC出版, 2009, 88-96.

切れてもつながるゴム?!
高島義徳, 原田明
化学, 化学同人, 2009, 2, 59-60.

シクロデキストリンによる包接と超分子形成
高島義徳, 原田明
超分子 サイエンス&テクノロジー ‐基礎からイノベーションまで‐, 国武豊喜監修, NTS, 2009, 105-118.

抗体エンジニアリング
山口浩靖, 原田明
超分子 サイエンス&テクノロジー ‐基礎からイノベーションまで‐, 国武豊喜監修, NTS, 2009, 990-999.

自己組織化による超分子・分子マシンの構築
原田明, 山口浩靖
高分子, 2009, 58(7), 457-460.

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2008

Ring-Opening Polymerization of Cyclic Esters by Cyclodextrins
Harada, A.; Osaki, M.; Takashima, Y.; Yamaguchi, H.
Acc. Chem. Res. 2008, 41(9), 1143-1152.

Single-Molecular Imaging of Rotaxane Based on Glass Substrates : Observations of Rotary Movement of a Rotor
Nishimura, D.; Takashima, Y.; Aoki, H.; Takahashi, T.; Yamaguchi, H.; Ito, S.; Harada, A.
Angew. Chem. Int. Ed. 2008, 47(32), 6077-6079.
[Angew. Chem. News Release]      [Science Daily News Release]    [Nano Werk News Release]      
[Nanotechwire News Release]       [Innovations report News Release]   
[Medical News Today News Release]      

Molecular Puzzle Ring: pseudo[1]Rotaxane from a Flexible Cyclodextrin Derivative
Miyawaki, A.; Kuad, P.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2008, 130, 17062-17069.

Switching between Supramolecular Dimer and Non-Threaded Supramolecular Self-Assembly of Stilbene Amide alpha-Cyclodextrin by Photoirradiation
Yamauchi, K.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc.2008, 130(15), 5024-5025.

Formation of Supramolecular Isomers; Poly[2]rotaxane and Supramolecular Assembly
Miyawaki, A.; Miyauchi, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Commun. 2008, (4), 456 - 458.

Relative Rotational Motion between alpha-Cyclodextrin Derivatives and a Stiff Axle Molecule
Nishimura, D.; Oshikiri, T.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
 J. Org. Chem. 2008, 73(7), 2496-2502.

Cooperative Complexation of alpha-Cyclodextrin with Alternating Copolymers of Sodium Maleate and Dodecyl Vinyl Ether with Varying Molecular Weights
Taura, D.; Hashidzume, A.; Okumura, Y.; Harada, A.
Macromolecules 2008, 41 (10), 3640-3645.

Stereo Selective Complex Formation between Polybutadiene and Cyclodextrins in Bulk
Kuratomi, Y.; Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromol. Rapid Commun. 2008, 29(11), 910-913.

Branched Supramolecular Polymers Formed by Bifunctional Cyclodextrin Derivatives
Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Tetrahedron 2008, 64, 8355-8361.

Construction of Chemical-Responsive Supramolecular Hydrogels from Guest-Modified Cyclodextrins
Deng, W.; Yamaguchi, H.; Takashima, Y.; Harada, A.
Chem. Asian J.
2008, 3(4), 687-695.

Cover Picture: Chemistry An Asian Journal  p.639.

Functionalized Antibodies as Biosensing Materials and Catalysts
Yamaguchi, H.; Harada, A.
Chem. Lett. (Highlight Review) 2008, 37, 1184-1189.

Chemical Sensors Based on Cyclodextrin Derivatives
Ogoshi, T.; Harada, A.
Sensors 2008, 8, 4961-4982.

Enhancement of Water Solubility of Single-Walled Carbon Nanotubes by Formation of Host-Guest Complexes of Cyclodextrins with Various Guest Molecules
Ogoshi, T.;Ikeya, M.; Yamagishi, T.; Nakamoto Y.; Harada, A.
J. Phys. Chem. C, 2008, 112, 13079-13083.

Fabrication and Characterization of a Novel Inclusion Complex of Chiral Monomer Derived from (+)-Camphor with β-Cyclodextrins
Liu, J.-H.; Hung, H.-J.;Harada, A.
Langmuir 2008, 24, 7442-7449.

Preparation and Properties of Polyrotaxanes Formed by Cyclodextrins and Oligo(thiophene)s : Effect of Insulating Cyclodextrins
Takashima, Y.; Sakamoto, K.; Yamaguchi, H.; Kamitori, S.; Harada, A.
"In Chemistry, Physics, and Biology in Macromolecular Science," Proceedings of OUMS '07, Takahiro Sato, Eds., Osaka University Press, Suita, Osaka, Japan, 2008, 13-29.

シクロデキストリンナノチュー ブ
原田 明
シクロデキストリンの応用技術, 【ナノ超分子編】第23章, 寺尾啓二,小宮山真監修,  シーエムシー出版, 2008, 303-314.

有機機能性材料化学−基本原理から応用原理まで
原田 明, 樋口弘行 編著
三共出版 (ISBN 978-4-7827-0557-5), 2008.

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2007

A Chemical-Responsive Supramolecular Hydrogel from Modified Cyclodextrins
Deng, W.; Yamaguchi, H.; Takashima, Y.; Harada, A.
Angew. Chem. Int. Ed. 2007, 46(27), 5144-5147.

An Artificial Molecular Chaperone: Poly-pseudo-rotaxane with an Extensible Axle
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2007, 129(46), 14452-14457.

External Stimulus-Responsive Supramolecular Structures Formed by a Stilbene Cyclodextrin Dimer
Kuad, P.; Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2007, 129(42), 12630-12631.

Supramolecular Hemoprotein Linear Assembly by Successive Interprotein Heme-Heme Pocket Interactions
Kitagishi, H.; Oohora, K.; Yamaguchi, H.; Sato, H.; Matsuo, T.; Harada, A.; Hayashi, T.
J. Am. Chem. Soc. 2007, 129(34), 10326-10327.

Thermal and Photochemical Switching of Conformation of Poly(ethylene glycol)-Substituted Cyclodextrin with an Azobenzene Group at the Chain End
Inoue, Y.; Kuad, P.; Okumura, Y.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2007, 129(20), 6396-6397.

Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs and Cyclodextrins
Ogoshi, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2007, 129(16), 4878-4879.

Face Selective [2] and [3] Rotaxanes: Kinetic Control of Threading Direction of Cyclodextrins
Oshikiri, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Eur. J. 2007, 13(25), 7091-7098.

Contraction of Supramolecular Double-Threaded Dimer Formed by alpha-Cyclodextrin with a Long Alkyl Chain
Tsukagoshi, S.; Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Org. Lett. 2007, 9(6), 1053-1055.

Preparation and Properties of Rotaxanes Formed by Dimethyl-beta-cyclodextrin and Oligo(thiophene)s with beta-Cyclodextrin Stoppers
Sakamoto, K.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Org. Chem. 2007, 72(2), 459-465.

Self-Threading and Dethreading Dynamics of Poly(ethylene glycol)-Substituted Cyclodextrins with Different Chain Lengths
Inoue, Y.; Miyauchi, M.; Nakajima, H.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2007, 40(9), 3256-3262.

Polymerization of Lactones Initiated by Cyclodextrins: Effects of Cyclodextrins on the Initiation and Propagation Reactions
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2007, 40(9), 3154-3158.

Macromolecular Recognition: Interaction of Cyclodextrins with an Alternating Copolymer of Sodium Maleate and Dodecyl Vinyl Ether
Taura, D.; Hashidzume, A.; Harada, A.
Macromol. Rapid Commun. 2007, 28(24), 2306-2310.

Cover Picture: Macromol. Rapid Commun. 24/2007 (p 2281)

Supramolecular Polymers Formed by Bifunctional Cyclodextrin Derivatives
Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Lett.
2007, 36(7), 828-829.

Polymerization of Lactones and Lactides Initiated by Cyclodextrins
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Kobunshi Ronbunshu, 2007, 64(10), 607-616.

Water Soluble Single-Walled Carbon Nanotubes Using Inclusion Complex of Cyclodextrin with an Adamantane Derivative
Ogoshi, T.; Yamagishi, A.; Nakamoto, Y.; Harada, A
Chem. Lett, 2007, 36, 1026-1027.

Construction of Supramolecules by Macromolecular Recognition and Study of Their Dynamic Behaviors
Harada, A
Kagaku to Kogyo, 2007, 60, 792-794.

Construction of Functionalized Catalysts Using Monoclonal Antibodies with Nonchiral Rhodium Complexes
Yamaguchi, H; Hirano, T; Kiminami, H.; Harada, A.
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.), 2007, 48, 707-708.

Solvent-Free Synthesis of Pseudopolyrotaxane and Polyrotaxane: Efficient Threading Complexation of a Cyclodextrin Wheel and a Linear Polymer Axle to Yield Pseudopolyrotaxane and Its Fixation to Polyrotaxane by the Direct Grinding of a Solid Mixture
Liu, R.; Maeda, T.; Kihara,N.; Harada,A.; Takata, T.
J. Polym. Sci., Part A: Polym. Chem., 2007, 45, 1571-1574.

Solvent-Free Synthesis of Unmodified Cyclodextrin-Based Pseudopolyrotaxane and Polyrotaxane by Grinding
Liu, R.;Harada,A.; Takata, T.
Polym. J., 2007, 39, 21-23.

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2006

Cyclodextrin-Based Supramolecular Polymers
Harada, A.; Hashidzume, A.; Takashima, Y.
Adv. Polym. Sci. 2006, 201, 1-43.

Cyclodextrin-Based Side Chain Polyrotaxane with Unidirectional Inclusion in Aqueous Media
Tomatsu, I.; Hashidzume, A.; Harada, A.
Angew. Chem. Int. Ed. 2006, 45(28), 4605-4608.

Novel Switchable Hydrogels via Supramolecular Cross-Linking of Adamantyl Containing LCST-Copolymers with Cyclodextrin Dimers
Kretschmann, O.; Choi, S. -W.; Miyauchi, M.; Tomatsu, I.; Harada, A.; Ritter, H.
Angew. Chem. Int. Ed. 2006, 45(26), 4361-4365.

Self-Threading of a Poly(ethylene glycol) Chain in a Cyclodextrin-Ring: Control of the Exchange Dynamics by Chain Length
Inoue, Y.; Miyauchi, M.; Nakajima, H.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2006, 128(28), 8994-8995.

Contrast Viscosity Changes upon Photoirradiation for Mixtures of Poly(acrylic acid)-Based alpha-Cyclodextrin and Azobenzene Polymers
Tomatsu, I.; Hashidzume, A.; Harada, A.
J. Am. Chem. Soc. 2006, 128 (7), 2226-2227.

Competitive Photoinduced Electron Transfer by the Complex Formation of Porphyrin with Cyclodextrin Bearing Viologen
Deng, W.; Onji, T.; Yamaguchi, H.; Ikeda, N.; Harada, A.
Chem. Commun. 2006, (40), 4212-4214.

Cyclodextrin-Grafted Poly(phenylene ethynylene) with Chemical-Responsive Properties
Ogoshi, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Commun. 2006, (35), 3702-3704.

Selection between Pinching-Type and Supramolecular Polymer-Type Complexes by alpha-Cyclodextrin-beta-Cyclodextrin Hetero-Dimer and Hetero-Cinnamamide Guest Dimers
Takahashi, H.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Org. Chem. 2006, 71(13), 4878-4883.

Asymmetric Hydrogenation with Antibody-Achiral Rhodium Complex
Yamaguchi, H.; Hirano, T.; Kiminami, H.; Taura, D.; Harada, A.
Org. Biomol. Chem. 2006, 4(19), 3571 - 3573.

News/ Hot Paper (September 14, 2006)

Spectroscopic Study on the Interaction of Cyclodextrins with Naphthyl Groups Attached to Poly(acrylamide) Backbone
Harada, A.; Ito, F.; Tomatsu, I.; Shimoda, K.; Hashidzume, A.; Takashima, Y.; Yamaguchi, H.; Kamitori, S.
J. Photochem. Photobiol., A 2006, 179 (1-2), 13-19.

Complex Formation of Cyclodextrins with Various Thiophenes and Their Polymerization in Water: Preparation of pseudo-Polyrotaxanes Containing Poly(thiophene)s
Takashima, Y.; Sakamoto, K.; Oizumi, Y.; Yamaguchi, H.; Kamitori, S.; Harada, A.
J. Incl. Phenom. Macrocycl. Chem. 2006, 56(1-2), 45-53.

Rotaxanes with Unidirectional Cyclodextrin Arrays
Yamaguchi, H.; Oshikiri, T.; Harada, A.
J. Phys. Condens. Matter 2006, 18(33), S1809-S1816.

Redox-Responsive Hydrogel System Using the Molecular Recognition of beta-Cyclodextrin
Tomatsu, I.; Hashidzume, A.; Harada, A.
Macromol. Rapid Commun. 2006, 27(4), 238-241.

Interaction of Cyclodextrins with Side Chains of Water Soluble Polymers: A Simple Model for Biological Molecular Recognition and its Utilization for Stimuli-Responsive Systems
Hashidzume, A.; Tomatsu, I.; Harada, A.
Polymer 2006, 47(17), 6011-6027.

Syntheses of Group 4 Transition Metal Complexes Bearing 2-Pyridinethiolate Ligands and their Catalytic Activities for Ethylene Polymerization
Takashima, Y.;  Nakayama, Y.; Hashiguchi, M.; Hosoda, T.; Yasuda, H.; Hirao T.; Harada, A.
Polymer 2006, 47(16), 5762-5774.

Macromolecular Recognition by Cyclodextrins. Interaction of Cyclodextrins with Polymethacrylamides Bearing Hydrophobic Amino Acid Residues
Hashidzume, A.; Harada, A.
Polymer 2006, 47(10), 3448-3454.

Polymer Formation Utilizing 'Crisscross' Addition (Crisscross Addition Polymerization) of Acetaldehyde Azine and 1,4-Phenylene Diisocyanate
Hashidzume, A.; Shiota, J.; Ueno, Y.; Noda, T.; Takashima, Y.; Harada, A.; Kamachi, M.
Polymer
2006, 47(2), 501-505.

Enhancement of Photoinduced Electron Transfer from Porphyrin to Methyl Viologen by Binding of an Antibody for Porphyrin
Onji, T.; Ohara, H. Yamaguchi, H.; Ikeda, N.; Harada A.
Chem. Lett. 2006, 35(10), 1126-1127.

Synthesis of a Water-Soluble Iridium(III) Complex with pH and Metal Cation Sensitive Photoluminescence
Konishi, K.; Yamaguchi, H.; Harada, A.
Chem. Lett. 2006, 35(7), 720-721.

Formation of Chiral Supramolecular Polymer Based on Modified Cyclodextrin by Host-Guest Interactions
Miyawaki, A.; Miyauchi, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Kobunshi Ronbunshu 2006, 63(5), 306-314.

Supramplecular Polymers Based on Cyclodextrins
Harada, A.
J. Polym. Sci. A. Polym. Chem. 2006, 44(17), 5113-5119.

Polymers Involving Cyclodextrin Moieties
Harada, A.; Hashidzume, A.; Miyauchi, M.
In Cyclodextrins and Their Complexes: Chemistry, Analytical Methods, Applications, Dodziuk H. Ed. Wiley, 2006.

Construction of Redox-Induced Systems Using Antigen-Combining Sites of Antibodies and Functionalization of Antibody Supramolecules
Yamaguchi, H.; Harada, A.
In Redox Systems under Nano-Space Control, Hirao, T. Ed. Springer, Heidelberg, 2006, 263-291.

基礎高分子科学
[共著83名] 原田 明
高分子学会編, 東京化学同人, 東京, 2006, 1-450.

ポリロタキサン
原田 明・山口浩靖
ナノマテ リアル工学大系 第2巻「ナノ金属」 新展開編第2節「超分子金属錯体」[4], フジ・テクノシステム, 東京, 2006, 750-759.

シクロデキストリンナノチューブ
原田 明,
環状・筒状超分子新素材の応用技術, 高田十志和編, シーエムシー出版, 東京, 2006, 125-137.

バイオインスパイアードマテリアル
原田 明・山口浩靖・高島義徳
ファ イバー スーパーバイオミメティックス~近未来の新技術創成~ 第6編 第2章 第1節 2, NTS, 東京, 1086-1092.

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