Research Areas 

Research Projects


Selected Publications

[Complete list in pdf file]

 
Dr. Satoshi Kawata
Associate Professor
E-mail: kawata [at] chem.sci.osaka-u.ac.jp

B.Sc., Tohoku University, Japan (1983)
M.Sc., Tohoku University, Japan (1985)
Ph.D., Tohoku University, Japan (1988)
Postdoc, Queen's University, Canada (1995-1996)
 

Assistant Professor
Tokyo Metropolitan University, Japan (1989-1997)
Associate Professor
Shizuoka University, Japan (1997-2001)

  • Coordination Chemistry, Materials Chemistry, Crystal Engineering, and Supramolecular Chemistry
  • Molecular Design and Functionalities of Coordination Space


2006

  • K. Yoneda, K. Adachi, K. Nishio, M. Yamasaki, A. Fuyuhiro, M. Katada, S. Kaizaki, and S. Kawata "An [Fe3O] Core Wrapped by Two [FeL3] Units"
    (Angew. Chem. Int. Ed., 2006, 45, 5459-5461)

  • K. Yamada, H. Tanaka, S. Yagishita, K. Adachi, T. Uemura, S. Kitagawa, S. Kawata,
    "Stepwise Guest Adsorption with Large Hysteresis in a Coordination Polymer {[Cu(bhnq)(THF)2](THF)}n Constructed from a Flexible Hinge-like Ligand"

    (Inorg. Chem., 2006, 45, 4322-4324)

    K. Yoneda, K. Adachi, S. Hayami, Y. Maeda, M. Katada, A. Fuyuhiro, S. Kawata, and S. Kaizaki
    "A Steep One-Step [HS-HS] to [LS-LS] Spin Transition in a 4,4-Bipyridine Linked One-Dimensional Coordination Polymer Constructed from a Pyrazolato Bridged Fe(II) Dimer"

    (Chem. Commun., 2006, 45-47. Hot Articles with inside front cover)


2005

  • K. Adachi, Y. Sugiyama, K. Yoneda, K. Yamada, K. Nozaki, A. Fuyuhiro, and S. Kawata
    "Triple Hydrogen Bond Directed Crystal Engineering of Metal Assembled Complexes: The Effect of a Novel Organic-Inorganic Module on Supramolecular Structure"

    (Chem. Eur. J., 2005, 11, 6616-6628)
  • K. Nakano, N. Suemura, K. Yoneda, S. Kawata, and S. Kaizaki
    "Substituent effect of the coordinated pyridine in a series of pyrazolato bridged dinuclear diiron(II) complexes on the spin-crossover behavior"

    (Dalton Trans., 2005, 740-743)


2004

  • K. Yamada, S. Yagishita, H. Tanaka, K. Adachi, K. Tohyama, H. Kumagai, K. Inoue, S. Kaizaki, R. Kitaura, H.-C. Chang, S. Kitagawa, and S. Kawata
    "Metal-Complex Assemblies Constructed from the Flexible Hinge-Like Ligand H2bhnq. Structural Versatility and Dynamic Behavior in the Solid State"
    (Chem. Eur. J., 2004, 10, 2647-2660 with frontispiece)
  • M. Kawahara, M. K. Kabir, K. Yamada, K. Adachi, H. Kumagai, Y. Narumi, K. Kindo, S. Kitagawa, and S. Kawata
    "Module-Based Assembly of Copper(II)-chloranilate Compounds: Syntheses, Crystal Structures and Magnetic Properties of {[Cu2(CA)(terpy)2][Cu(CA)2]} and {[Cu2(CA)(terpy)2(dmso)2][Cu(CA)2(dmso)2](EtOH)} (H2CA = chloranilic acid, terpy = 2,2':6',2"-terpyridine, dmso = dimethylsulfoxide)"
    (Inorg. Chem., 2004, 43, 92-100)
  • K. Nakano, S. Kawata, K. Yoneda, A. Fuyuhiro, T. Yagi, S. Nasu, S. Morimoto, and S. Kaizaki
    "Direct Two-Step Spin-Crossover through [HS-HS]---[LS-LS] at the Plateau in Dinuclear Diiron(II) Complex [{Fe(NCBH3)(4phpy)}2(m-bpypz)2] "
    (Chem. Commun., 2004, 2892-2893)

    2003

    • K. Nagayoshi, M. K. Kabir, H. Tobita, K. Honda, M. Kawahara, M. Katada, K. Adachi, H. Nishikawa, I. Ikemoto, H. Kumagai, Y. Hosokoshi, K. Inoue, S. Kitagawa, and S. Kawata
      "Design of Novel Inorganic-Organic Hybrid Materials Based on Iron-Chloranilate Mononuclear Complexes: Characteristics of Hydrogen Bond-Supported Layers toward the Intercalation of Guests"
      (J. Am. Chem. Soc., 2003, 125, 221-232)
    • H. Kumagai, M. Endo, M. Kondo, S. Kawata, and S. Kitagawa "Reactions between Vanadium(III) and a Pyridylketone oxime Ligand and Structures of Reaction Products"
      (Coord. Chem. Rev., 2003, 237, 197-203)
    • M. K. Kabir, H. Tobita, H. Matsuo, K. Nagayoshi, K. Yamada, K. Adachi, Y. Sugiyama, S. Kitagawa, and S. Kawata
      "Crystal Engineering Using the Versatility of 2,5-Dichloro-3,6-dihydroxy-1,4-benzoquinone with Organic and Metal Complex
      Partners"
      (Cryst. Growth Des., 2003, 3, 791-798)


    2002

    • H. Kumagai, S. Kawata, and S. Kitagawa
      "Fabrication of Infinite Two-Dimensional Sheets of Tetragonal Metal(II) Lattices. X-ray Crystal Structure and Magnetic Properties of [M(CA)(pyz)]n (M2+ = Mn2+ and Co2+; H2CA = Chloranilic Acid; pyz = Pyrazine)"
      (Inorg. Chim. Acta, 2002, 337, 387-392)
    • S. Kitagawa and S. Kawata
      "New Dimensions of Coordination Compounds of Oxocarbon Ligands. Structures and Properties"
      (Coord. Chem. Rev., 2002, 224, 11-34)
    • S. Kawata, K. Adachi, Y. Sugiyama, M. K. Kabir, and S. Kaizaki "Proton-transfer-mediated crystal engineering using 1,4,5,6-tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile with 4,4'-bipyridine"
      (CrystEngComm, 2002, 4, 496-498)
    • H. Kumagai, M. Arishima, S. Kitagawa and S. Kawata
      "New Hydrogen Bond-Supported 3-D Molecular Assembly from Polyoxovanadate and Tetramethylbiimidazole" (Inorg. Chem., 2002, 41, 1989-1992)
    • H. Kumagai, S. Kitagawa M. Maekawa, S. Kawata, H. Kiso and M Munakata
      "Preparation, Crystal Structures and Spectroscopic Properties of Vanadium(III) Complexes having [V-O-V]4+ Core" (J. Chem. Soc., Dalton Trans., 2002 2390-2396)

    2001
    • K. Adachi, H. Irikawa, K. Shiratori, Y. Sugiyama, and S. Kawata
      "One-dimensional Helical Chain in the cocrystal of CHCl3 and trans-2,3,5,6,11,11b-hexahydro-3-oxo-1H-indolizino[8,7-b]indole- 5-carboxylic acid methyl ester: a channel type inclusion complex"
      (CrystEngComm, 2001,3, 128-130)
    • M. K. Kabir, M. Kawahara, H. Kumagai, K. Adachi, S. Kawata, T. Ishii and S. Kitagawa
      "The Rational Syntheses of Manganese-Chloranilate Compounds: Crystal Structures and Magnetic Properties"
      (Polyhedron, 2001, 20, 1417-1422)
    • K. Adachi, Y. Sugiyama, H. Kumagai, K. Inoue, S. Kitagawa, and S. Kawata
      "Crystal Structures and Magnetic Properties of Novel Coordination Polymers with Rectangular Lattice Constructed from Pyrazine Derivative"
      (Polyhedron, 2001, 20, 1411-1415)
    • K. Adachi, S. Kawata, M. K. Kabir, H. Kumagai, K. Inoue, and S. Kitagawa
      "Design and Construction of Coordination Polymers Based on the Topological Property of the Multidentate Ligand"
      (Chem. Lett., 2001, 50)

    2000
    • Y. Sugiyama, K. Adachi, S. Kawata, H. Kumagai, K. Inoue, M. Katada and S. Kitagawa
      "Triple hydrogen bond directed crystal engineering of metal assembled complexes: the effect of bifunctional ligand on supramolecular structure"
      (CrystEngComm, 2000, 2, 174-176)
    • S. Kawata, H. Kumagai, K. Adachi, and S. Kitagawa
      "Novel Layered Structures Constructed from Metal(II)-Chloranirate Monomer Compounds"
      (J. Chem. Soc., Dalton Trans., 2000, 2409-2417)
    • M. K. Kabir, N. Miyazaki, S. Kawata, K. Adachi, H. Kumagai,K. Inoue, S. Kitagawa, K. Iijima, and M. Katada
      "Novel Layered Structures Constructed From Iron-Chloranilate Compounds"
      (Coord. Chem. Rev., 2000,198,157-165)

    1999
    • M. Katada, T. Nawa, H. Kumagai, S. Kawata, and S. Kitagawa
      "Synthsis and 151Eu- and 57Fe-Moessbauer spectroscopic studies of new europium-iron complexes"
      (J. Radioanal. Nucl. Chem. 1999, 239, 227-232)

    1998
    • S. Kawata, S. Kitagawa, H. Kumagai, T. Ishiyama, K. Honda, H. Tobita, K. Adachi, and M. Katada
      "Novel Intercalation Host System Based on Transition Metal (Fe2+,Co2+, Mn2+)-Chloranilate Coordination Polymers. Single Crystal Structures and Properties"
      (Chem. Mater. 1998, 10, 3902-3912)
    • S. Kawata, S. Kitagawa, M. Enomoto, H Kumagai, and M. Katada
      "Mixed Ligand Copper(II) Coordination Polymers Constructed by Cu-bpm-Cu Dimer Unit (bpm = 2, 2'- bipyrimidine) as a Building Block. Crystal Structures and Magnetic Properties of [Cu(bpm)(SO4)](H2O)n, [Cu2(bpm)(suc)0.5(ClO4)2(OH)(H2O)2]n, and [Cu(bpm)1.5(suc)0.5(ClO4)(H2O)2]n (suc = succinate)"
      (Inorg. Chim. Acta, 1998, 283, 80-90)
    • M. Umeya, S. Kawata, H. Matsuzaka, S. Kitagawa, H. Nishikawa, K. Kikuchi and I. Ikemoto
      "X-Ray crystal structure, magnetic and electric properties of TTF trimer-based salts of FeCl4,[TTF7(FeCl4)2]"
      (J. Mater. Chem. 1998, 8, 295-300)
    • S. Kawata, S. Kitagawa, H. Kumagai, S. Iwabuchi, and M. Katada
      "The Structural Characterization of the Novel Ribbon-Sheet, [Cu2Cl2(pyz)]n (pyz = pyrazine)"
      (Inorg. Chim. Acta, 1998, 267, 143-145)

    1997
    • S. Kawata, S. R. Breeze, S. Wang, J. E. Greedan, and N. P. Raju
      "Structural interconversionfacilitated by a bifunctional ligand: a covalently linked 2D CuII sheet[Cu(3-pyOH)2(O2CCF3)2]n and a Hydrogen-bond linked 2D CuII sheet [Cu(3-pyOH)2(O2CCF3)2(thf)2]n"
      (J. Chem. Soc.,Chem. Commun., 1997, 717-718 )
    • R. Miyamoto, S. Kawata, M. Iwaizumi, H. Akashi, and T. Shibahara
      "EPR Studies of the Mixed-metal Cubane-type Complex Having a [Mo3CuS4]4+ Core"
      (Inorg. Chem., 1997, 36, 542-546)
    • H. Kumagai, S. Kawata, S. Kitagawa, K. Kanamori, and K. Okamoto
      "Preparation and Structure of a Novel Tetranuclear Mixed-Valence Vanadium(IV/V) Complex Having Alkoxo and Oxo Groups"
      (Chem. Lett., 1997, 249-250 )

    1996
    • M.Sato,Y.Hayashi,S.Kumakura, N.Shimizu,M.Katada, and S.Kawata
      "Synthesis and Oxidation of Iron(II) Ferrocenylacetylide Diphoshine Complexes. A Novel Type ofMixed-Valence Complexes"
      (Organometallics,1996, 15, 721-728)
    • S. Kawata, S. Kitagawa, H. Kumagai, C. Kudo, H. Kamesaki, T. Ishiyama, R. Suzuki, M. Kondo, and M. Katada
      "Rational Design of Novel Intercalation System. Layer-Gap Control of Crystalline Coordination Polymers, [Cu(CA)(H2O)m](G)n (m = 2 and G = 2,5-dimethylpyrazine and phenazine; m = 1, G =1,2,3,4,6,7,8,9-octahydrophenazine)"
      (Inorg. Chem., 1996, 35, 4449-4461)

    1995
    • M. Munakata, Liang Ping Wu, M.Yamamoto, T. Kuroda-Sowa, M. Maekawa, S. Kawata, and S. Kitagawa
      "Co-ordinative Versatility of 3,5-Bis(2-Pyridyl)Pyrazolein Silver and Copper Compounds"
      (J. Chem. Soc., Dalton Trans., 1995, 4099-4104)
    • S. Kitagawa, T. Ohkubo, S. Kawata, M. Kondo, M. Katada, and H. Kobayashi
      "An Oxalate-Linked Copper(II) Coordination Polymer, [Cu2(oxalate)2(pyrazine)3]n, Constructed with Two Different Copper Units. X-ray Crystallographic and Electronic Structures"
      (Inorg. Chem., 1995, 34, 4790-4796)
    • N. Okabe, Y. Ohba, S. Suzuki, S. Kawata, K. Kikuchi, Y. Achiba, and M. Iwaizumi
      "Fourier transform EPR studies of metallofullerene (La@C82) in CS2 solution"
      (Chem. Phys. Lett.,1995, 235, 654-655)
    • S. Kitagawa, M. Kondo, S. Kawata, S. Wada, M. Maekawa, and M. Munakata
      "Molecular Cavity for tetrahedral and Y-shaped Anions. Synthetic and Structural Studies of Macrocyclic Dicopper(I) and Disilver(I) Compounds of 1,6-bis(diphenylphosphino)hexane"
      (Inorg. Chem., 1995, 34, 1455-1465)
    • S. Kawata, S. Kitagawa, H. Machida, T. Nakamoto, M. Kondo, M. Katada, K. Kikuchi, and I. Ikemoto
      "Oxamide oxime-based copper(II) coordination polymers. Two- and three-dimensional structures controlled by dicarboxylates"
      (Inorg. Chim. Acta, 1995, 229, 211-219 )
    • K. Asamaki, T. Nakamoto, S. Kawata, M. Katada, K. Endo, and H. Sano
      "Structure and Mixed-Valence States of Trinuclear Iron(II,III,III) Pivalate Complex"
      (Inorg. Chim. Acta, 1995, 236, 155-161)

    1994
    • H. Yokoi, T. Mitani, Y. Mori, and S. Kawata
      "Complex Formation between Iron(III) and Tartaric and Citric Acids in a Wide pH Range 1 to 13 as Studied by Magnetic Susceptibility Measurements"
      (Chem. Lett., 1994, 281-284)
    • M. Sato, H. Shintate, Y. Kawata, M. Sekino, M. Katada, and S. Kawata
      "Oxidized Ruthenium Ferrocenylacetylide Complexes, [(h-C5Me5)L2RuCCFc]PF6 ( L = Phosphines). Electron-Delocalized Heterobinuclear Mixed-Valence Complexes"
      (Organometallics, 1994, 13, 1956-1962)
    • S. Kawata, S. Kitagawa, M. Kondo, I. Furuchi, and M. Munakata
      "Two-Dimensional Sheets of Tetragonal Copper(II) Lattice: X-ray Crystal Strucure and Magnetic Properties of [Cu(C6O4Cl2)(C4H4N2)]n"
      (Angew. Chem. Int. Ed. Engl., 1994, 33, 1759-1761)
    • H. Kumagai, S. Kawata, M. Kondo, S. Kitagawa, and, M. Katada
      "Crystal Structure of Binuclear Vanadium(III) Complex with a New Tripodal Ligand, [V2Cl4(tped)(EtOH)2]2EtOH"
      (Inorg. Chim. Acta, 1994, 224, 199-200)
      S. Suzuki, Y. Kojima, Y. Nakao, T. Wakabayashi, S. Kawata, K. Kikuchi, Y. Achiba, and T. Kato
      "ESR detection of non-equivalent scandium trimer"
      (Chem. Phys. Lett., 1994, 229, 512-516)

    1993
    • T. Nakamoto, M. Katada, S. Kawata, S. Kitagawa, K. Kikuchi, I. Ikemoto, K. Endo, and H. Sano
      "Abrupt Conversion of Mixed-Valence State in Trinuclear Iron Cyanoacetate Complex"
      (Chem. Lett., 1993, 1463-1466)
    • S. Kitagawa, S. Kawata, Y. Nozaka, and M. Munakata
      "Synthesis and Crystal Structures of Novel Copper(I) Co-ordiantion Polymers and a Hexacopper(I) Cluster of Quinone-2-thione"
      (J.Chem.Soc.Dalton Trans. 1993, 1399-1404)
      S. Kitagawa, S. Kawata, M. Kondo, Y. Nozaka, and M. Munakata
      "Synthesis and Structures of Infinite Sheet Copper(I) Complex Polymers with 2,6-dimethylpyrazine, [Cu2(C6H8N2)3](ClO4)2(C3H6O)2 and with 2- chloropyrazine, [Cu2(C4H3N2Cl)4.5](ClO4)2 "
      (Bull.Chem.Soc.Jpn. 1993, 66, 3387-3392)

    1992
    • S. Kawata, M. Nakamura, Y. Yamashita, K. Asai, K. Kikuchi, I. Ikemoto, M. Katada, and H. Sano
      "Synthesis and Characterization of a New m-Alkoxodiiron(III) Complex with NO5 Donor Set Environments"
      (Chem. Lett., 1992, 135-138)
    • M. Watanabe, T. Iwamoto, S. Kawata, A. Kubo, H. Sano, and I. Motoyama
      "13C CP-MAS,13C,and 1H NMR Spectroscopic Study of Mixed-Valence 1,1"-Biruthenocenium Salts"
      (Inorg. Chem., 1992, 31,177-182)
    • S. Suzuki, S. Kawata, H. Shiromaru, K. Yamauchi, K. Kikuchi, T. Kato, and Y. Achiba
      "Isomers and 13C Hyperfine Structures of Metal-Encapsulated Fullerenes M@C82 (M= Sc,Y, and La)"
      (J. Phys. Chem.,1992, 96, 7159-7161)
    • S. Kawata, K. Yamauchi, S. Suzuki, K. Kikuchi, H. Shiromaru, M. Katada, K. Saito, I. Ikemoto, and Y. Achiba
      "The Origin of the ESR Signal of C60 Seen in the Powder and in Benzene Solution. The Indication of the Reaction of C60 with Oxygen Induced by Photoexcitation"
      (Chem. Lett., 1992, 1659-1662)
    • H. Yokoi, Y. Mori, T. Mitani, and S. Kawata
      "A Magnetic Study of the Iron(III) Complexes of Polyols and Sugars in Aqueous Solution"
      (Bull. Chem. Soc. Jpn., 1992, 65, 1898-1902)
    • S. Kawata, H. Kosugi, H. Uda, M. Iwaizumi, and H. Yokoi
      "Solution Equilibrium and EPR Study of the Dinuclear Copper(II) Complexes of Aminopolycarboxylic Acids with an Alcohol OH Group in the Alkyl Chain Linkage"
      (Bull. Chem. Soc. Jpn., 1992, 65, 2910-2921)
      S. Kitagawa, Y. Nozaka, M. Munakata and S. Kawata
      "Synthesis and Crystal Structures of Tetra- and Hexanuclear Copper(I) Complexes of Pyrimidine Derivatives, [Cu4(C4H8N2S)4](ClO4)4 and [Cu6(C5H5N2S)6]"
      (Inorg.Chim.Acta, 1992, 197, 169-175)

    1991 and before
    • Y. Ohba, S. Kawata, M. Satoh, H. Yokoi, and M. Iwaizumi
      "ESEEM and ENDOR Studies of Triplet State Copper(II) Complex Dimer"
      (Electron Magnetic Resonance of Disordered Systems, 1991,175-191)
    • S. Kawata, H. Yokoi, and M. Iwaizumi
      "Electron Paramagnetic Resonance Study of the Dimer Formation of Bis- (acetylacetonato)-oxo-vanadium(IV)"
      (Bull.Chem.Soc.Jpn., 1990, 63, 2511-2515)
      S. Kawata, H. Yokoi, and M. Iwaizumi
      "EPR Investigation of the Binuclear Copper(II) Complexes with 3,12-Bis(carboxymethyl) 6,9-dioxa-3,12-diazatetradecanedioic Acid"
      (Bull. Chem. Soc.Jpn.,1990, 63, 3414-3419)
    • M. Kikkawa, Y. Sasaki, S. Kawata, Y. Hatakeyama, F. B. Ueno, and S. Saito
      "Photochemical and Thermal Decomposition of (DD, LL)-(m-Hydroxo)(m-peroxo)bis- [bis(ethylenediamine)cobalt(III)] Ions in Basic Aqueous Solution"
      (Inorg. Chem., 1985, 24, 4096-4100)
    • H. Yokoi, S. Kawata, and M. Iwaizumi
      "Interaction Modes between Heavy Metal Ions and Water-Soluble Polymers.1. Spectroscopic and Magnetic Reexamination of the Aqueous Solutions of Cupric Ions and Poly(vinyl alcohol)"
      (J. Am. Chem. Soc., 1986, 108, 3358-3361)
    • H. Yokoi, S. Kawata, and M. Iwaizumi
      "Interaction Modes between Heavy Metal Ions and Water-Soluble Polymers. 2. Spectroscopic and Magnetic Reexamination of the Aqueous Solutions of Cupric Ions and Poly(acrylic acid)"
      (J. Am. Chem. Soc., 1986, 108, 3361-3365)
    • S. Kawata, M. Iwaizumi, H. Kosugi, and H. Yokoi
      "Binuclear Copper(II) Complexes of Aminopolycarboxylic Acids with an Alcoholic OH Group in the Alkyl Chain Linkage. Model Complexes for Type 3 Copper with Respect to Bridging Ligands"
      (Chem. Lett, 1987, 2321-2324)
    • S. Kawata, M. Iwaizumi, H. Kosugi, and H. Yokoi
      "A Green Complex from the Reaction of a Binuclear Copper(II) Complex of 2-Hydroxy-1,4-butanediamine-N,N,N',N'- tetraacetic Acid and H2O2"
      (Bull.Chem.Soc.Jpn., 1988, 61, 2195-2196)
    • S. Kawata, H. Yokoi, and M. Iwaizumi
      "Electron Paramagnetic Resonance Study of the Dimer Formation of Bis- (acetylacetonato)-oxo-vanadium(IV)"
      (Bull.Chem.Soc.Jpn., 1990, 63, 2511-2515)
    • S. Kawata, H. Yokoi, and M. Iwaizumi
      "EPR Investigation of the Binuclear Copper(II) Complexes with 3,12-Bis(carboxymethyl) 6,9-dioxa-3,12-diazatetradecanedioic Acid"
      (Bull. Chem. Soc.Jpn.,1990, 63, 3414-3419)