Osaka U 大阪大学 大学院理学研究科 高分子科学専攻　The University of Osaka, Department of Macromolecular Science

高分子合成化学研究室The Polymer Synthesis Chemistry Group

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研究業績 Publications（寺島教授；Terashima）



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研究業績 Publications（金澤准教授；Kanazawa）

1. 原著論文 Original Papers        2. 総説・解説 Reviews and Tutorial Papers       
3. その他 Miscellaneous Publication

1. 原著論文 Original Papers (2000-)


  1. Allyl Bromide/AgSbF6/Tetrahydropyran Initiating System for Living Cationic Ring-Opening Polymerization of Oxiranes with Diverse Reactivities
    Yamada, H.; Aoshima, S.; Kanazawa, A.*
    Macromolecules 2025, 58, 8225–8234.
    [Introduced in Synfacts (Thieme) in Nov, 2025]

  2. Facile Synthesis of Graft Polymers with Poly(vinyl ether) Graft Chains Using Poly(cyclic acetal)s as Macroinitiators for Living Cationic Polymerization
    Nomura, K.; Aoshima, S.; Kanazawa, A.*
    Macromolecules 2025, 58, 7397–7405.

  3. Furfural-Derived 5-Alkoxy-2(5H)-furanones as Cationically Copolymerizable Cyclic Hemiacetal Esters
    Higashibata, N.; Aoshima, S.; Kanazawa, A.*
    Polym. Chem. 2025, 16, 3119–3128. [Special Issue: "Pioneering Investigators"] [Open Access]

  4. Ring-Opening Polymerization of Six-Membered 1,3-Dioxa-2-silacycloalkanes by an Organobase Catalyst: Precision Polymerization and Monomer Regeneration by Polymer Degradation
    Tanaka, I.; Aoshima, S.; Kanazawa, A.*
    Polym. Chem. 2025, 16, 2211–2215. [Open Access]

  5. Sequence-Controlled Cationic Terpolymerization of Styrene Derivatives, Oxiranes, and Aromatic Aldehydes: Synthesis of Acidically or Oxidatively Degradable Terpolymers
    Eguchi, Y.; Aoshima, S.; Kanazawa, A.*
    Macromolecules 2025, 58, 4655–4664.

  6. Unexpected Increase in Water Solubility by the Introduction of Hydrophobic Units into Imidazolium-Based Polymeric Ionic Liquids with Carboxylate Counteranions
    Maruyama, N.; Aoshima, S.*; Kanazawa, A.*
    Polym. Chem. 2025, 16, 1792–1797. [Open Access]

  7. Sugar-Derived Cyclic Acetals as Comonomers for Cationic Copolymerization with Vinyl Ethers
    Katto, A.; Aoshima, S.; Kanazawa, A.*
    Macromolecules 2024, 57, 6255–6266.

  8. Cationic Alternating Copolymerization of Vinyl Esters and 3-Alkoxyphthalides: Side Chain-Crosslinkable Polymers for Acid-Degradable Single-Chain Nanoparticles
    Kamigaki, K.; Aoshima, S.; Kanazawa, A.*
    ACS Macro Lett. 2024, 13, 754–760.

  9. Metal-Free, Photoinitiated Cationic Terpolymerization of Vinyl Ethers, Oxiranes, and Ketones: Simultaneous Control of Monomer Sequence and Molecular Weight by the Formation of Long-Lived Propagating Species
    Eguchi, Y.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2024, 57, 3346–3357.

  10. Dual Control of Stereoregularity and Molecular Weight in Cationic Polymerization of Vinyl Ether by Tunable TADDOLs/TiCl4 Initiating Systems
    Watanabe, H.; Mishima, Y.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2024, 15, 1062–1069. [Open Access]

  11. Cationic Ring-Opening Copolymerization of a Cyclic Acetal and γ-Butyrolactone: Monomer Sequence Transformation and Polymerization–Depolymerization Control by Vacuuming or Temperature Change
    Takebayashi, K.; Kanazawa, A.*; Aoshima, S.*
    Polym. J. 2024, 56, 309–317. [Special Issue: "Polymer Degradation for a Sustainable Future"] [Open Access]

  12. Imidazolium-Based Polymeric Ionic Liquids with Diverse Carboxylates: Precision Synthesis and LCST- and UCST-Type Thermoresponsivity in Water
    Matsuo, N.; Ueda, M.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2023, 14, 4804–4808.

  13. Photoinduced Superacceleration of Metal-Free Living Cationic Polymerization Using Diaryliodonium Salts as Organic Lewis Acid Catalysts
    Mishima, Y.; Kanazawa, A.; Aoshima, S.*
    Macromolecules 2023, 56, 6941–6950.

  14. Cationic Ring-Opening Copolymerization of Cyclic Acetals and 1,3-Dioxolan-4-ones via the Activated Monomer Mechanism and Transacetalization Reaction
    Takebayashi, K.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2023, 56, 5524–5533.

  15. 3-Alkoxyphthalides as Nonhomopolymerizable, Highly Reactive Comonomers for ABC Pseudo-Periodic Terpolymers and Degradable Polymers via Cationic Co- and Terpolymerizations with Oxiranes and/or Vinyl Ethers
    Takahashi, Y.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2023, 56, 4198–4207.

  16. Alternating Cationic Copolymerization of Vinyl Ethers and Sequence-Programmed Cyclic Trimer Consisting of One Vinyl Ether and Two Aldehydes for ABCC-Type Periodic Terpolymer
    Naito, T.; Kanazawa, A.*; Aoshima, S.*
    Polym. Chem. 2023, 14, 2829–2837. [Open Access]

  17. Sequence-Controlled Polymer Synthesis Derived from Alcohols, Cyclic Enol Ethers, and Vinyl Ethers: Selective Generation of 2-Alkoxy Cyclic Ethers Followed by Living Cationic Alternating Copolymerization by the One-Pot Process
    Maruyama, K.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2023, 56, 4190–4197.

  18. Two-Step Degradable ABAC-Type Periodic Poly(Cyclic Acetal)s Synthesized by Sequence-Programmed Monomer Formation and Subsequent Polyaddition Based on Cyclotrimerization of One Vinyl Monomer and Two Aldehydes
    Naito, T.; Kanazawa, A.; Aoshima, S.*
    Giant 2023, 14, 100159. [Special Issue: "Precision Macromolecules: Synthesis, Self-Assembly, and Functions"] [Open Access]

  19. Tandem Polymerization Consisting of Cyclotrimerization and Tishchenko Reaction: Synthesis of Acid- and Alkali-Degradable Polymers with Cyclic Acetal and Ester Structures in the Main Chain
    Naito, T.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2022, 13, 5757–5768.

  20. Alternating-Like Cationic Copolymerization of Styrene Derivatives and Benzaldehyde: Precise Synthesis of Selectively Degradable Copoly(styrenes)
    Nara, T.; Kanazawa, A.; Aoshima, S.*
    Macromolecules 2022, 55, 6852–6859.

  21. Cationic Polymerizability of Vinyl Acetate: Alternating Copolymerization with 1,3-Dioxolan-4-ones and Branched Copolymer Formation with Cyclic Acetals
    Azuma, J.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2022, 55, 6110–6119.

  22. Degradable Silyl Ether Polymers Synthesized by Sequence-Controlled Cationic Terpolymerization of 1,3-Dioxa-2-silacycloalkanes with Vinyl Ethers and Aldehydes
    Hada, R.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2022, 55, 5474–5484.

  23. Role of the Counteranion in the Stereospecific Living Cationic Polymerization of N-Vinylcarbazole and Vinyl Ethers: Mechanistic Investigation and Synthesis of Stereo-Designed Polymers
    Watanabe, H.; Kanazawa, A.; Okumoto, S.; Aoshima, S.*
    Macromolecules 2022, 55, 4378–4388.

  24. Alternating Cationic Copolymerization of Vinyl Ethers and Aryl-Substituted Cyclic Acetals: Structural Investigation of Cyclic Acetals on the Copolymerizability
    Maruyama, K.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2022, 55, 4034–4045.

  25. Cationic Copolymerization of o-Phthalaldehyde and Vinyl Monomers with Various Substituents on the Vinyl Group or in the Pendant: Effects of the Structure and Reactivity of Vinyl Monomers on Copolymerization Behavior
    Hayashi, K.; Kanazawa, A.; Aoshima, S.*
    Macromolecules 2022, 55, 3276–3286.

  26. Living and Alternating Cationic Copolymerization of o-Phthalaldehyde and Various Bulky Enol Ethers: Elucidation of the “Limit” of Polymerizable Monomers
    Hayashi, K.; Kanazawa, A.; Aoshima, S.*
    Macromolecules 2022, 55, 1365–1375.

  27. ABC-Type Periodic Terpolymer Synthesis by a One-Pot Approach Consisting of Oxirane- and Carbonyl-Derived Cyclic Acetal Generation and Subsequent Living Cationic Alternating Copolymerization with a Vinyl Monomer
    Maruyama, K.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2022, 55, 799–809.

  28. Copolymerizability Evaluation in Cationic Vinyl-Addition and Ring-Opening Copolymerization of Vinyl Ethers and Oxiranes: Effects of Bulkiness and the Number of Substituents Introduced into Oxiranes
    Kawamura, Y.; Hotta, D.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2021, 54, 7460–7468.

  29. Living Cationic Ring-Opening Homo- and Copolymerization of Cyclohexene Oxide by “Dormant” Species Generation Using Cyclic Ethers as Lewis Basic Additives
    Inoue, M.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2021, 54, 5124–5135.

  30. Unzipping and Scrambling Reaction-Induced Sequence Control of Copolymer Chains via Temperature Changes during Cationic Ring-Opening Copolymerization of Cyclic Acetals and Cyclic Esters
    Higuchi, M.; Kanazawa, A.*; Aoshima, S.*
    J. Polym. Sci. 2021, 59, 2730–2741. [Special Issue: "Early Career Investigators"] [Inside Back Cover]
         

  31. The “Solid-State” Ring-Opening Cationic Polymerization of 1,3,5-Trioxane: Frozen Polymerization for Suppression of Oligomer Formation and Synthesis of Ultrahigh Molecular Weight Polymers
    Suemitsu, C.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2021, 12, 822–830. [Cover Picture]
         

  32. tert-Butyl Esters as Potential Reversible Chain Transfer Agents for Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization of Vinyl Ethers and Oxiranes
    Hotta, D.; Kanazawa, A.*; Aoshima, S.*
    Macromol. Rapid Commun. 2021, 42, 2000479. [Special Issue: "Young Talents in Polymer Science"]

  33. Precise Synthesis of Amphiphilic Diblock Copolymers Consisting of Various Ionic Liquid-Type Segments and Their Influence on Physical Gelation Behavior in Water
    Yokota, D.; Kanazawa, A.; Aoshima, S.*
    RSC Adv. 2020, 10, 42378–42387. [Open Access]

  34. Cationic Polymerization of Phenyl Vinyl Ethers: Investigations of the Propagation Mechanism, the Living Polymerization of Ortho-Substituted Derivatives, and the Step-Growth Polymerization of Divinyl Derivatives
    Asakawa, T.; Kanazawa, A.; Aoshima, S.*
    Macromolecules 2020, 53, 6887–6897.

  35. Cationic Copolymerization of Styrene Derivatives and Oxiranes via Concurrent Vinyl-Addition and Ring-Opening Mechanisms: Multiblock Copolymer Formation via Occasional Crossover Reactions
    Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2020, 53, 5255–5265.

  36. Metal-Free Living Cationic Polymerization Using Diaryliodonium Salts as Organic Lewis Acid Catalysts
    Haraguchi, R.; Nishikawa, T.; Kanazawa, A.; Aoshima, S.*
    Macromolecules 2020, 53, 4185–4192.

  37. Stereoselective Cationic Polymerization of Vinyl Ethers by Easily and Finely Tunable Titanium Complexes Prepared from Tartrate-Derived Diols: Isospecific Polymerization and Recognition of Chiral Side Chains
    Watanabe, H.; Yamamoto, T.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2020, 11, 3398–3403. [Selected as a "Polymer Chemistry Recent HOT Article"]

  38. Design of Graft Architectures via Simultaneous Kinetic Control of Cationic Vinyl-Addition Polymerization of Vinyl Ethers, Coordination Ring-Opening Polymerization of Cyclic Esters, and Merging at the Propagating Chain End
    Higuchi, M.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2020, 53, 3822–3831.

  39. Tandem Unzipping and Scrambling Reactions for the Synthesis of Alternating Copolymers by the Cationic Ring-Opening Copolymerization of a Cyclic Acetal and a Cyclic Ester
    Higuchi, M.; Kanazawa, A.*; Aoshima, S.*
    ACS Macro Lett. 2020, 9, 77–83.

  40. Stereoregularity Effect on Hole Mobility in Poly(N-vinylcarbazole) Thin Film Evaluated by MIS-CELIV Method
    Kim, W.-J.; Nishikawa, Y.; Watanabe, H.; Kanazawa, A.; Aoshima, S.; Fujii, A.*; Ozaki, M.
    Jpn. J. Appl. Phys. 2020, 59, SDDA01.

  41. Desilylation-Triggered Degradable Silylacetal Polymers Synthesized via Controlled Cationic Copolymerization of Trimethylsilyl Vinyl Ether and Cyclic Acetals
    Kato, R.; Kanazawa, A.*; Aoshima, S.*
    ACS Macro Lett. 2019, 8, 1498–1503.

  42. ABC Pseudo-Periodic Sequence Control by Cationic Orthogonal Terpolymerization of Vinyl Ether, Oxirane, and Ketone
    Mimura, M.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2019, 52, 7572–7583.

  43. Controlled Cationic Copolymerization of Vinyl Monomers and Cyclic Acetals via Concurrent Vinyl-Addition and Ring-Opening Mechanisms: The Systematic Study of Structural Effects on the Copolymerization Behavior
    Maruyama, K.; Kanazawa, A.*; Aoshima, S.*
    Polym. Chem. 2019, 10, 5304–5314.

  44. Facile One-Shot Synthesis of Functional Star-Shaped Polymers by Domino-Type Living Cationic Copolymerization
    Yamada, M.; Yoshizaki, T.; Kanazawa, A.; Kanaoka, S.*; Aoshima, S.*
    J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 2166–2174.

  45. Alternating Degradable Copolymers of an Ionic Liquid-Type Vinyl Ether and a Conjugated Aldehyde: Precise Synthesis by Living Cationic Copolymerization and Dual Rare Thermosensitive Behavior in Solution
    Yokota, D.; Kanazawa, A.; Aoshima, S.*
    Macromolecules 2019, 52, 6241–6249.

  46. Structure-Property Relationship of Phenoxyimine Ligands/Metal Chloride Initiating Systems for Controlled Cationic Polymerizations of Alkyl Vinyl Ethers
    Kigoshi, S.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 2021–2029.

  47. Screening of Metal Complex Catalysts Using Bidentate Schiff Base Ligands for Controlled Cationic Polymerization of Vinyl Ethers Using In Situ Complexation Method
    Kigoshi, S.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    Polym. Chem. 2019, 10, 4209–4219.

  48. Dual Stimuli-Responsive Copolymers with Precisely Arranged Degradable Units: Synthesis by Controlled Alternating Copolymerization of Oxyethylene-Containing Vinyl Ethers and Conjugated Aldehydes
    Matsumoto, S.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    Polym. Chem. 2019, 10, 4134–4141.

  49. Exceptional Copolymerizability of o-Phthalaldehyde in Cationic Copolymerization with Vinyl Monomers
    Hayashi, K.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2019, 10, 3712–3717.

  50. Tetradentate Schiff Base Ligand/MCln Initiating Systems for the Controlled Cationic Polymerization of Isobutyl Vinyl Ether: Effects of the Ligand Framework
    Kigoshi, S.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 989–996.

  51. Polyaddition of Vinyl Ethers and Phthalaldehydes via Successive Cyclotrimerization Reactions: Selective Model Reactions and Synthesis of Acid-Degradable Linear Poly(Cyclic Acetal)s
    Naito, T.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2019, 10, 1377–1385.

  52. Metal-Free Photoinitiated Controlled Cationic Polymerization of Isopropyl Vinyl Ether Using Diaryliodonium Salts
    Nishikawa, T.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2019, 10, 1056–1061.

  53. Cationic Ring-Opening Co- and Terpolymerizations of Lactic Acid-Derived 1,3-Dioxolan-4-ones with Oxiranes and Vinyl Ethers: Nonhomopolymerizable Monomer for Degradable Co- and Terpolymers
    Hyoi, K.; Kanazawa, A.*; Aoshima, S.*
    ACS Macro Lett. 2019, 8, 128–133. [Supplementary Cover]
         

  54. Controlled Cationic Polymerization of 1-Methoxy-1,3-Butadiene: Long-Lived Species-Mediated Reaction and Control over Microstructure with Weak Lewis Bases
    Togo, Y.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 288–296. [Special Issue for Prof. Mitsuo Sawamoto]

  55. Generation of “Living” Species Using Perfluoroalkylsulfonic Acids in Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization via Crossover Reactions
    Hotta, D.; Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2018, 51, 7983–7992.

  56. Precise Synthesis of UCST-Type Amphiphilic Diblock Copolymers with Pendant Imidazolium Ionic Liquid Segments and Their Thermosensitive Physical Gelation at Extremely Low Concentrations in Water
    Yokota, D.; Kanazawa, A.; Aoshima, S.*
    Polym. Chem. 2018, 9, 5080–5085.

  57. Synthesis of Highly Defined Graft Copolymers Using a Cyclic Acetal Moiety as a Two-Stage Latent Initiating Site for Successive Living Cationic Polymerization and Ring-Opening Anionic Polymerization
    Yokoyama, N.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    Macromolecules 2018, 51, 884–894.

  58. Precision Synthesis of Polylactide-Based Thermoresponsive Block Copolymers via Successive Living Cationic Polymerization of Vinyl Ether and Ring-Opening Polymerization of Lactide
    Seki, Y.; Kanazawa, A.; Kanaoka, S.; Fujiwara, T.; Aoshima, S.*
    Macromolecules 2018, 51, 825–835.

  59. The Influence of the Substituents of Oxiranes on Copolymerization with Vinyl Ethers via Concurrent Cationic Vinyl-Addition and Ring-Opening Mechanisms
    Miyamae, Y.; Kanazawa, A.*; Tamaso, K.; Morino, K.; Ogawa, R.; Aoshima, S.*
    Polym. Chem. 2018, 9, 404–413. [Cover Picture]
         

  60. Cationic Terpolymerization of Vinyl Ethers, Oxetane, and Ketones via Concurrent Vinyl-Addition, Ring-Opening, and Carbonyl-Addition Mechanisms: Multiblock Polymer Synthesis and Mechanistic Investigation
    Kanazawa, A.*; Aoshima, S.*
    Macromolecules 2017, 50, 6595–6605.

  61. フッ素含有ビニルエーテルとアルデヒド類の制御カチオン交互共重合による分解型含フッ素ポリマーの精密合成 (Precision Synthesis of Degradable Alternating Copolymers of Fluorine-containing Vinyl Ethers and Conjugated Aldehydes)
    松本 涼香; 金澤 有紘; 金岡 鐘局; 青島 貞人 (Matsumoto, S.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.)
    高分子論文集 (Kobunshi Ronbunshu) 2017, 74, 608–615. [written in Japanese]
  62. Tandem Reaction of Cationic Copolymerization and Concertedly Induced Hetero-Diels–Alder Reaction Preparing Sequence-Regulated Polymers
    Matsumoto, S.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    J. Am. Chem. Soc. 2017, 139, 7713–7716.

  63. リビングカチオン重合のキャッピング反応によるマクロモノマーの精密合成および選択的カチオン共重合 (Precision Synthesis of Macromonomers by End-Capping During Living Cationic Polymerization and Their Subsequent Selective Cationic Copolymerization)
    横山 憲文; 金澤 有紘; 青島 貞人 (Yokoyama, N.; Kanazawa, A.; Aoshima, S.
    高分子論文集 (Kobunshi Ronbunshu) 2017, 74, 360–364. [written in Japanese]
  64. Stereospecific Living Cationic Polymerization of N‑Vinylcarbazole through the Design of ZnCl2‑Derived Counteranions
    Watanabe, H.; Kanazawa, A.; Aoshima, S.*
    ACS Macro Lett. 2017, 6, 463–467.

  65. Concurrent Cationic Vinyl-Addition and Coordination Ring-Opening Copolymerization via Orthogonal Propagation and Transient Merging at the Propagating Chain End
    Higuchi, M.; Kanazawa, A.*; Aoshima, S.*
    ACS Macro Lett. 2017, 6, 365–369.

  66. Controlled Cationic Copolymerization of Vinyl Monomers and Cyclic Acetals via Concurrent Vinyl-Addition and Ring-Opening Mechanisms
    Shirouchi, T.; Kanazawa, A.*; Kanaoka, S.; Aoshima, S.*
    Macromolecules 2016, 49, 7184–7195.

  67. Biphasic Synthesis of "Block" Copolymers and Star-Shaped Polymers via Monomer-Selective Cationic Copolymerization in Organic/Fluorinated Solvents
    Yamada, M.; Nishikawa, T.; Kanazawa, A.; Kanaoka, S.*; Aoshima, S.*
    J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 2656–2661.

  68. Cationic Polymerization of p-Methylstyrene Using Various Metal Chlorides: Design Rationale of Initiating Systems for Controlled Polymerization of Styrenes
    Saitoh, R.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    Polym. J. 2016, 48, 933–940.

  69. Shape-Switching Self-Assembly in Water of New Diblock Copolymers with UCST-Type and LCST-Type Segments
    Yoshimitsu, H.; Korchagiva, E.; Kanazawa, A.; Kanaoka, S.; Winnik, F.*; Aoshima, S.*
    Polym. Chem. 2016, 7, 2062–2068.

  70. Cationic Polymerization of Vinyl Ethers with Alkyl or Ionic Side Groups in Ionic Liquids
    Yoshimitsu, H.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 1774–1784.

  71. Quantitative and Ultrafast Synthesis of Well-Defined Star-Shaped Poly(p-Methoxystyrene) via One-Pot Living Cationic Polymerization
    Yoshizaki, T.; Kanazawa, A.; Kanaoka, S.*; Aoshima, S.*
    Macromolecules 2016, 49, 71–79. [Open Access]

  72. Synthesis of Block or Graft Copolymers Containing Poly(Styrene Derivatives) Segments by Living Cationic Polymerization Using Acetal Moieties as Latent Initiating Sites
    Yokoyama, N.; Yoshida, H.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    Polym. Chem. 2015, 6, 6316–6324.

  73. Exclusive One-Way Cycle Sequence Control in Cationic Terpolymerization of General-Purpose Monomers via Concurrent Vinyl-Addition, Ring-Opening, and Carbonyl-Addition Mechanisms
    Kanazawa, A.*; Aoshima, S.*
    ACS Macro Lett. 2015, 4, 783–787. [Open Access]

  74. ビニルエーテルとスチレン類を有する新規ブロックポリマーの精密合成および高感度温度応答性フィルムの創製 (Precision Synthesis of Block Copolymers of 2-Methoxyethyl Vinyl Ether with Styrene Derivatives and Preparation of Highly Thermosensitive Films)
    吉﨑 友哉; 金澤 有紘; 金岡 鐘局; 青島 貞人 (Yoshizaki, T.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.)
    高分子論文集 (Kobunshi Ronbunshu) 2015, 72, 486–490. [written in Japanese]
  75. 含フッ素セグメントをもつブロックコポリマーの精密合成および水/有機層間を往復可能な高分子ミセルの創製 (PreciseSynthesis of Fluorine-Containing Block Copolymers for the Creation of Micelles that Reversibly Transfer between Aqueous and Organic Phases)
    山中 悠司; 金澤 有紘; 金岡 鐘局; 青島 貞人 (Yamanaka, Y.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.)
    高分子論文集 (Kobunshi Ronbunshu) 2015, 72, 480–485. [written in Japanese]
  76. Controlled Radical Polymerization of Styrene with Magnetic Iron Oxides Prepared through Hydrothermal, Bioinspired, and Bacterial Processes
    Kanazawa, A.*; Satoh, K.; Kanaoka, S.; Kakihana, M.; Kobayashi, M.; Sato, J.; Imai, H.; Oaki, Y.; Arakaki, A.; Katagiri, K.; Kamigaito, M.*; Aoshima, S.*
    RSC Adv. 2015, 5, 51122–51129.

  77. Sequence-Controlled Degradable Polymers by Controlled Cationic Copolymerization of Vinyl Ethers and Aldehydes: Precise Placement of Cleavable Units at Predetermined Positions
    Kawamura, M; Kanazawa, A.; Kanaoka, S.; Aoshima, S.*
    Polym. Chem. 2015, 6, 4102–4108.

  78. Frequency Control of Crossover Reactions in Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization of Vinyl Ethers and Oxiranes: Specific Roles of Weak Lewis Bases and Solvent Polarity
    Kanazawa, A.*; Aoshima, S.*
    Polym. Chem. 2015,  6, 5675–5682. ["Emerging Investigators" Issue]

  79. New Initiating Systems for Cationic Polymerization of Plant-Derived Monomers: GaCl3/Alkylbenzene-Induced Controlled Cationic Polymerization of β-Pinene
    Karasawa, Y.; Kimura, M.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Polym. J. 2015, 47, 152–157.

  80. In Situ and Readily Prepared Metal Catalysts and Initiator for Living Cationic Polymerization of Isobutyl Vinyl Ether: Dual-Purpose Salphen as a Ligand Framework for ZrCl4 and an Initiating Proton Source
    Kigoshi, S.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Polym. Chem. 2015, 6, 30–34.

  81. Alkoxyoxirane, a Unique Cyclic Monomer: Controlled Cationic Homopolymerization Mediated by Long-Lived Species and Copolymerization with Vinyl Ether via Alkoxy Group Transfer
    Kanazawa, A.; Kanda, S.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2014, 47, 8531–8540.

  82. Rational Design of Oxirane Monomers for Efficient Crossover Reactions in Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization with Vinyl Ethers
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2014, 47, 6635–6644.

  83. Design of Benign Initiator for Living Cationic Polymerization of Vinyl Ethers: Facile in Situ Generation of Vinyl Ether–Hydrogen Halide Adducts and Subsequent Controlled Polymerization without a Lewis Acid Catalyst
    Kanazawa, A.; Hashizume, R.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2014, 47, 1578–1585. [Open Access]

  84. Controlled Cationic Alternating Copolymerization of Various Enol Ethers and Benzaldehyde Derivatives: Effects of Enol Ether Structures
    Ishido,Y.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1334–1343.

  85. Efficient Design for Stimuli-Responsive Polymers with Quantitative Acid-Degradability: Specifically Designed Alternating Controlled Cationic Copolymerization and Facile Complete Degradation
    Aoshima, S.; Oda Y.; Matsumoto S.; Shinke Y.; Kanazawa, A.; Kanaoka, S.
    ACS Macro Lett. 2014, 3, 80–85.

  86. Chemically Recyclable Alternating Copolymers with Low Polydispersity from Conjugated/Aromatic Aldehydes with Vinyl Ethers: Selective Degradation to Another Monomer at Ambient Temperature
    Ishido, Y; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Polym. Chem. 2014, 5, 43–47.

  87. Precise Synthesis of pH-Responsive Copolymers with Naphthoic Acid Side Groups via Living Cationic Polymerization
    Shinke, Y.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 5239–5247.

  88. Selectively Degradable Alternating Copolymers of Isobutyl Vinyl Ether and Plant-Derived Aldehydes with Acyclic Side Chains: Effects of Side Group Structures on Copolymerization Behaviors
    Ishido, Y; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4684–4693.

  89. Precision Synthesis of Graft Copolymers via Living Cationic Polymerization of p-Acetoxystyrene Followed by Friedel-Crafts-Type Termination Reaction
    Shinke, Y.; Yamamoto, H.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4675–4683.

  90. Living Cationic Polymerization of Vinylnaphthalene Derivatives
    Shinke, Y.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4828–4834.

  91. Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization Using B(C6F5)3 as a Catalyst: Copolymerization of Vinyl Ethers and Isobutylene Oxide via Crossover Propagation Reactions
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Am. Chem. Soc. 2013, 135, 9330–9333. [Open Access]

  92. Well-Defined Polymeric Ionic Liquids with an Upper Critical Solution Temperature in Water
    Yoshimitsu, H.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2012, 45, 9427–9434. [Open Access]

  93. Structure Effects of Lewis Acids on the Living Cationic Polymerization of p-Methoxystyrene: Distinct Difference in Polymerization Behavior from Vinyl Ethers
    Kanazawa, A.; Shibutani, S.; Yoshinari, N.; Konno, T.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2012, 45, 7749–7757.

  94. Biologically Synthesized or Bioinspired Process-Derived Iron Oxides as Catalysts for Living Cationic Polymerization of Vinyl Ether
    Kanazawa, A.; Kanaoka, S.; Yagita, N.; Oaki, Y.; Imai, H.; Oda, M.; Arakaki, A.; Matsunaga, T.; Aoshima, S.
    Chem. Commun. 2012, 48 10904–10906.

  95. Living Cationic Polymerization of Vinyl Ethers with a Naphthyl Group: Decisive Effect of the Substituted Position on Naphthalene Ring
    Shinke, Y.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 5041–5048.

  96. Domino Synthesis of Star-Shaped Polymers Based on Monomer Selective Living Cationic Polymerization: Highly Controlled Star Polymer Formation
    Kanaoka, S.; Yamada, M.; Ashida, J.; Kanazawa, A.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 4594–4598.

  97. Cationic Addition Polymerization of 1,4-Dioxene using GaCl3 as Lewis Acid Catalyst: Long-Lived Species-Mediated Polymerization
    Uchigami, K.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 4571–4578.

  98. New Degradable Alternating Copolymers from Naturally Occurring Aldehydes: Well-Controlled Cationic Copolymerization and Complete Degradation
    Ishido, Y.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2012, 45, 4060–4068.

  99. 高感度温度応答性フィルムの創製：ブロックコポリマー構造設計およびフィルム作成条件の影響 (Design and synthesis of thermo-responsive films with high sensitivity: effects of primary architectures of diblock copolymers and conditions for film formation)
    瀧下 大貴; 金澤 有紘; 金岡 鐘局; 青島 貞人 (Takishita, H.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.)
    高分子論文集 (Kobunshi Ronbunshu) 2012, 69, 305–308. [written in Japanese]
  100. リビングカチオン重合による温度応答性フィルムの創製：様々な応答パターンを有するスマートフィルム (Thermo-responsive films obtained from various block copolymers by living cationic polymerization: smart films with various transition patterns)
    瀧下 大貴; 辻本 浩行; 金澤 有紘; 金岡 鐘局; 青島 貞人 (Takishita, H.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.)
    高分子論文集 (Kobunshi Ronbunshu) 2012, 69, 300–304. [written in Japanese]
  101. A Stepping Stone to Stereospecific Living Cationic Polymerization: Cationic Polymerization of Vinyl Ethers Using Iron(II) Sulfate
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 3702–3708.

  102. Cationic Polymerization of Isobutyl Vinyl Ether Using Alcohols Both as Cationogen and Catalyst-Modifying Reagent: Effect of Lewis Acids and Alcohols on Living Nature
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 2509–2516.

  103. Chain Multiplying Controlled Cationic Polymerization of Isobutyl Vinyl Ether Using Pyrrole: Increment of Propagating Chains by Efficient “Initiator-Like” Transfer Agent.
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2010, 43, 3682–3689.

  104. Living Cationic Polymerization of Vinyl Ether with Methanol/Metal Chloride Initiating Systems: Relationship between Polymerization Behavior and the Nature of Lewis Acids.
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2010, 43, 2739–2747.

  105. Living Cationic Polymerization of Isobutyl Vinyl Ether Using a Variety of Metal Oxides as Heterogeneous Catalysts: Robust, Reusable, and Environmentally Benign Initiating Systems
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 916–926.

  106. Major Progress in Catalysts for Living Cationic Polymerization of Isobutyl Vinyl Ether: Effectiveness of a Variety of Conventional Metal Halides
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Macromolecules 2009, 42, 3965–3972. [Open Access]

  107. Heterogeneously Catalyzed Living Cationic Polymerization of Isobutyl Vinyl Ether Using Iron (III) Oxide
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Am. Chem. Soc. 2007, 129, 2420-2421.
  108. Fast Living Cationic Polymerization of Vinyl Ethers with Iron(III) Chloride in the Presence of a Cyclic Ether: Most Active and Environmentally Benign Catalyst for the Living Cationic Polymerization of Vinyl Ethers
    Kanazawa, A.; Hirabaru, Y.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 5795-5800.
  109. Instant living cationic polymerization using SnCl4/EtAlCl2 with a weak Lewis base: Ultrafast polymerization in seconds
    Yoshida, T.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 4288-4291.

2. 総説・解説 Reviews and Tutorial Papers (2000-)


[論文誌 Journals]
  1. カチオン重合 (Cationic Polymerization)
    青島 貞人, 金澤 有紘, 金岡 鐘局 (Aoshima, S.; Kanazawa, A.; Kanaoka, S.)
    ネットワークポリマー (Network Polymer) 2017, 38, 21–28. [written in Japanese]
  2. ビニル付加・開環同時カチオン共重合：ビニルエーテルとオキシラン間の交差生長反応を伴う共重合系の開発 (Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization: Copolymerization through Crossover Propagation Reactions between Vinyl Ethers and Oxiranes)
    金澤 有紘 (Kanazawa, A.)
    高分子論文集 (Kobunshi Ronbunshu) 2016, 73, 442–452. [written in Japanese]
  3. Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization of Vinyl Ethers and Oxiranes
    Kanazawa, A.; Aoshima, S.
    Polym. J. 2016, 48, 679–687.
  4. Recent Progress in Living Cationic Polymerization of Vinyl Ethers
    Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    Chem. Lett. 2010, 39, 1232-1237.
  5. New Stage in Living Cationic Polymerization: An Array of Effective Lewis Acid Catalysts and Fast Living Polymerization in Seconds
    Aoshima, S.; Yoshida, T.; Kanazawa, A.; Kanaoka, S.
    J. Polym. Sci., Part A: Polym. Chem. (Highlight) 2007, 45, 1801-1813.
[本 Books]
  1. Living Cationic Polymerisation
    Kanazawa, A.
    Routledge Resources Online - Polymers, Materials, and Technology, Mishra, M. K.; Takeuchi, D.; Sudo, A. Eds.; Taylor & Francis Group, 2025
  2. Cationic Polymerisation
    Kanazawa, A.
    Routledge Resources Online - Polymers, Materials, and Technology, Mishra, M. K.; Takeuchi, D.; Sudo, A. Eds.; Taylor & Francis Group, 2025
  3. カチオン重合
    青島 貞人, 金澤 有紘 (Aoshima, S.; Kanazawa, A.)
    高分子材料の事典 （高分子学会 編集）, 2022, 6-5, 550–551. [written in Japanese]
  4. リビングカチオン重合による刺激応答性高分子の精密設計
    青島 貞人, 金澤 有紘 (Aoshima, S.; Kanazawa, A.)
    刺激応答性高分子ハンドブック （宮田 隆志 監修）, 2018, 61–68. [written in Japanese]
  5. Sequence-Controlled Polymers via Cationic Polymerization
    Aoshima, S.; Kanazawa, A.
    Sequence-Controlled Polymers, Lutz, J.-F. Ed., 2018, Chapter 11, 327–348.
  6. カチオン重合 (Cationic Polymerization)
    青島 貞人, 金澤 有紘 (Aoshima, S.; Kanazawa, A.)
    精密重合が拓く高分子合成（CSJカレントレビュー20）(Polymer Synthesis Developed by Precision Polymerization (CSJ Current Review 20) ) 2016, Part II, 2章, 50–62. [written in Japanese]
  7. Polyethers
    Kanazawa, A.
    Encyclopedia of Polymeric Nanomaterials, Kobayashi, S.; Müllen, K. Eds.; Springer 2014, DOI 10.1007/978-3-642-36199-9_251-1
  8. リビングカチオン重合における触媒技術の動向と展望
    金澤 有紘, 金岡 鐘局, 青島 貞人 (Kanazawa, A.; Kanaoka, S.; Aoshima, S.)
    触媒技術の動向と展望２０１３ (Annual Survay of Catalytic Science and Technologies) 2013, 43–53. [written in Japanese]
[学会誌等 Publication by Academic Societies]
  1. 「異種」モノマーのカチオン共重合
    金澤 有紘
    高分子 (Kobunshi) (展望) (Highlight Reviews) 2025, 74, 603–605. [written in Japanese]
  2. The "Solid-State" Cationic Ring-Opening Polymerization of 1,3,5-Trioxane
    Suemitsu, C.; Kanazawa, A.; Aoshima, S.
    高分子 (Kobunshi) (Hot Topics) 2021, 70, 491.
  3. ルイス酸触媒系によるビニルエーテルの精密リビングカチオン重合 (Living Cationic Polymerization of Vinyl Ethers by Lewis Acid Catalysts)
    青島 貞人, 金澤 有紘, 金岡 鐘局 (Aoshima, S.; Kanazawa, A.; Kanaoka, S.)
    触媒 (Shokubai) 2016, 58, 20–26. [written in Japanese]
  4. Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization of Vinyl Ethers and Oxiranes
    Kanazawa, A.
    高分子 (Kobunshi) (Hot Topics) 2016, 65, 59.
  5. “じゃんけん”共重合：配列制御ポリマー合成に向けた戦略 ("Rock-Paper-Scissors" Copolymerization)
    金澤 有紘, 青島 貞人 (Kanazawa, A.; Aoshima, S.)
    化学と工業 (Chemistry & Chemical Industry)（Division Topics） 2015, 68, 1110. [written in Japanese]
  6. 刺激応答性高分子材料：構造の制御された温度応答性ポリマーの展開 (Stimuli-Responsive Polymers: Recent Advances in Thermosensitive Polymers with Well-Controlled Structures)
    青島 貞人, 金澤 有紘, 金岡 鐘局 (Aoshima, S.; Kanazawa, A.; Kanaoka, S.)
    オレオサイエンス (Oleoscience) 2014, 14, 73-80. [written in Japanese]
  7. 配列は規則正しく　ビニルモノマーのつなぎ順を制御した高分子
    金澤 有紘, 青島 貞人 (Kanazawa, A.; Aoshima, S.)
    化学 (Chemistry) 2013, 68, 67-68. [written in Japanese]
  8. リビングカチオン重合を用いた機能性材料への挑戦 (New Generation Functional Polymers by Living Cationic Polymerization)
    青島 貞人, 金澤 有紘 (Aoshima,S.; Kanazawa, A.)
    高分子 (Kobunshi) 2013, 62, 233-235. [written in Japanese]
  9. 刺激応答性ポリマーにみるリビングカチオン重合の威力
    青島 貞人, 金澤 有紘, 金岡 鐘局 (Aoshima,S.; Kanazawa, A.; Kanaoka, S.)
    現代化学 (Chemistry Today) 2012, 495, 36-41. [written in Japanese]

3. その他 Miscellaneous Publication

  1. 境遇に感謝 (Gratitude to Circumstances)
    金澤 有紘 (Kanazawa, A.)
    高分子 (Kobunshi)（先輩からのメッセージ ー仕事と私事ー）(Messages: "Work and Life") 2021, 70, 662. [written in Japanese]
  2. 泥臭くスマートに (Studying Diligently and Smartly)
    金澤 有紘 (Kanazawa, A.)
    高分子 (Kobunshi)（グローイングポリマー）(Polymer Science and I: A Personal Account) 2016, 65, 374. [written in Japanese]

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