• 2023.09 張路明君がThe 12th China-Japan Joint Symposium on Calorimetry and Thermal Analysis(CATS-2023)で最優秀ポスター賞を受賞しました

• 2022.10 張路明君が熱測定討論会のオンライン討論会で優秀講演賞を受賞しました

• 2022.03 熱・エントロピー科学研究センターシンポジウムが開催されました

• 2021.06 熱・エントロピー国際若手熱力学研究者会ISTES-YT-2021が開催されました

• 2020.10 山下智史博士が2020年度日本熱測定学会の奨励賞を受賞しました

• 2020.09 野本哲也君が分子科学会のオンライン討論会で優秀講演賞を受賞しました

• 2019.07 松村祐希さんがMultis2019のStudent Travel Grantsに採択しました

• 2018.11 今城周作博士が強磁場コラボラトリー研究会で優秀ポスター賞を受賞しました

• 2018.11熱測定討論会が開催されました

• 森健彦先生（東工大名誉教授）のバンド計算プログラムへのリンクです

さらなる情報

中澤研主な装置を紹介します。低温熱測定を行うために不可欠な低温、真空装置と電子計測器が配置されています。

低温と真空装置

クライオスタット(Cryostat)は低温恒温器のこと。研究室では主に超伝導磁石つきの恒温器を使うので、マグネットまたは電磁石と呼ぶ人も多いです。有機でよく使われるNMRと似たような仕組みですが、試料スペースが広い分、電磁石や寒剤タンクのサイズも大きくなります。ステンレス製で一個200kgくらい、しっかりした恒温器です。 　15Tのような数字が最大かけられるテスラ単位の磁場です。目安として、よく使われる永久磁石が最大0.3T(酸化鉄)または1.5T(ネオジム)くらいの磁場を維持できます。また、超伝導磁石に最大磁場をかけたら、磁気エネルギーがちょうど200mlスーパーカップと同じレベルなので、超伝導磁石がquenchしたら大変なことになります。 　寒剤液体ヘリウムと抵抗線などの加熱器を組み合わせて、1.5K(-271.65℃、ヘリウム４減圧排気)から室温まで連続的な温度制御が可能で、プローブに希釈冷凍機などを実装すれば、温度範囲を広げることもできます。	15Tクライオスタット 中澤研で最も強い磁場をかけられるクライオスタットです。	8Tクライオスタット 汎用性の高いクライオスタットです。	7Tsplitクライオスタット 横磁場タイプのクライオスタットです。
	簡易型クライオスタット あまり使用されてはいませんが、ここぞというときに役立ちます。	吸着型クライオスタット 今は奥で眠っています。。。	9Tクライオスタット 新入りのクライオスタットです。

probeを油拡散pumpに繋いで真空断熱を維持して、cryostatに入れて、温度、磁場可変測定を行います。	測定プローブ		油拡散ポンプ 熱測定に欠けられない、断熱高真空にするための装置です。
	油回転ポンプ 拡散ポンプの補助引きとヘリウム減圧排気のに使われた汎用性の高い中真空ポンプです。エアコンの取り付け工事も同種のポンプを使います。

測定プローブに取り付けて、希釈冷凍機で最低50mKとヘリウム3減圧排気で0.5Kまで冷やせます。詳しくはこちら

希釈冷凍機 フェルミ粒子である3Heとボース粒子である4Heのエントロピー差を利用して、10mK程度の極低温を実現します。

3He減圧システム 3Heを減圧するための装置です。

SQUID SQUIDとは"Superconducting Quantum Interference Device"の略で、超伝導量子干渉計のことです。磁化率の測定に用います。 ※中澤研が管理していますが、共同利用装置です。

液体窒素タンク 室温から低温に下げるのに使います。77K(-196℃)まで下げることができます。仕組み

液体 4Heベッセル 更に極低温まで下げるのに使います。4K(-269℃)まで下げることができます。仕組み

合成装置

電解セル		ドラフト		電解セル電源		薬品庫		冷蔵恒温器
電荷移動錯体は電解酸化によって合成するため、それを行うためのセルです。		危険なものを扱うときはこの中で行います。		これを使って電解酸化を行います。		毒物・劇物を含め、たくさんの試薬があります。		この中で定温度電解を行います。

実際に電解を行う様子

計測器

位相検波

lock-in-amp 　時間相関のあるシグナルを測定する際によく使われる計測器です。SR850と5210など4台ぐらいあります。ノイズの多い入力シグナルから、狭い周波数範囲の部分だけを取り出すBPF(band-pass-filter)+交流電圧計と理解できます。 　有効シグナルと同期するために、PLL(phase lock loop)が使えますが、lock-in-ampの内部発振器でシステムを制御したら、PLLを使わずに自動的に同期できます。この方法の汎用性が非常に高いです。後で述べる交流抵抗計、誘電測定計、また高周波回路でよく使われるspectrum analyzerとnetwork analyzer、I/Q変調器も、全部この原理に基づいて、作られたものです。	SR850	5210
交流抵抗計	lakeshore社370 研究室で一番多い低励起低温用抵抗計	LR700 古い型番ですが綺麗な結果が得られます。
	CTR6500 高精度抵抗計	F700
誘電測定システム	AMETEK社1260A Frequency Response Analyzer+High impedance interface 1296A	TOYO 6252
capacitance bridge	2500A 3ppmほど高い確度を誇る変圧器平衡bridge容量計
3132,3131など 直流から5kHzまでの直流隔離増幅器、lockinampなどの補助予増幅器として使われます	thermal graph camera、赤外カメラ お値段が思った以上高い

実際に測定を行う様子

電源

高精度電流源	横河7651	keithley社K6220
任意波形発生器	TEGAM 2414B
直流電源	各種電源	超伝導磁石電源 5V150Aくらいの低圧大電流で電磁石を励磁します。
商用電源フィルターと隔離変圧器

電圧計

~ 新しく購入した装置 ~

• 2022.02 Keisight(HP→Aglient→Keisight)社の34420A nano-volt meterを購入しました～1mV rangeでも7.5桁の分解能を持ち、熱電対の測定での性能を期待しています。

• 2022.03 Keithley社のK2182nano-volt meterを購入しました

POST	NAME	address@chem.sci.osaka-u.ac.jp
教授	中澤 康浩 (Yasuhiro Nakazawa) researchmap	nakazawa
准教授	圷　広樹 (Hiroki Akutsu) researchmap	akutsu
助教	山下 智史 (Satoshi Yamashita) researchmap	sayamash
秘書	中本　美智代 (Michiyo Nakamoto)	nakamotom20
D2	張　路明(Zhang Luming)	zhangl20
D1	張　瑜(Zhang Yu)
	増田　崇利(Masuta Takato)
	Vivian Arthurs
M2	山延　謙斗(Yamanobe)
	中島(Nakajima)
	池井(Ikei)
	新舎(Sinsya)
	桑原(Kuwahara)
M1	穆　原氷(Mu Yuanbing)
	岡本　佳樹(Okamoto)
	葛西　健(Kassai)
	長谷川　頒吉(Hasegawa)
	森川　怜(Morikawa)
B4	橋本 佳子
	石橋 駿
	十倉 昂平
	WEI GUANHAO

Graduation date	NAME	Degree
2024.3	前田　大樹(Taiki Maeda)	Master
2024.3	真鍋　開人(Haruhito Manabe)	Master
2023.3	吉田　奈央(Yoshida Nao)	Ona seminar
2022.9	Yesil Emre	Doctor
2022.3	松村　祐希(Yuki Matsumura)	Doctor
2022.3	宇野　陽亮 (Yousuke Uno)	Master
2022.3	尾山　泰聖(Taiki Oyama)	Master
2021.9	安　東(An Dong)	Master
2021.3	野本　哲也(Tetsuya Nomoto) researchmap	Doctor
2018.3	今城　周作(Shusaku Imajo) researchmap	Doctor

下記のサイトにはShift JISを使用しているので文字化けが生じることが多いです。

2013年のメンバーpage
2009年のメンバーpage
2007年のメンバーpage

下記のサイトにはShift JISを使用しているので文字化けが生じることが多いです。

中泽先生の诞生日会2011

忘年会

修論・D論お疲れ様会

新歓2011

構造熱科学研究センターとの合同芋掘り＆BBQ

院試壮行会2011

大西さん帰国祝い　～2年ぶりにマラウイより帰国～

昔のgallery

Heat Capacity of Poly(N-vinylpyrrolidone)
K. Ishikiriyama, K. Kondo, Y. Miyazaki, Y. Sasada, K. Sawada, R. Endo, N. Man, M. Nakano, and Y. Nakazawa
Thermochim. Acta 722, 179456 (2023) (14 pages).

Porous Mn2+ Magnet with a Pt-Cl Framework: Correlation between Water Vapor Adsorption/Desorption and Slow Magnetic Relaxation H. Nakajima, K. Uchida, T. Yoshida, Y. Horii, T. Sato, Z. Luming, S. Yamashita, Y. Nakazawa, V. C. Agulto, M. Nakajima, B. K. Breedlove, M. Yamashita, H. Iguchi, and S. Takaishi
ChemPhysChem 24(4), e202200618 (2023)

Magnetoelectric, Spectroscopic, Optical and Elastic Properties of Co-Doped BaTiO3 Ceramics R. Bujakiewicz-Koronska, Ł. Gondek, L. Vasylechko, M. Balanda, E. Juszynska-Galazka, M. Galazka, D. Majda, W. Piekarczyk, A. Zywczak, A. Cizman, M. Sitarz, P. Jelen, W. Salamon, P. Czaja, J. Jedryka, K. Koronski, A. Kalvane, K. Gornicka, E. Markiewicz, S. Yamashita, and Y. Nakazawa J. Alloys Compounds 946, 169344 (2023)

Thermal Conductivity Measurement System for Molecules-Based Compounds Available in a Wide Temperature Region L. Zhang, T. Nomoto, S. Yamashita, H. Akutsu, A. I. Krivchikov, and Y. Nakazawa Low Temp. Phys. 49(5), 539 (2023).

Correlation-Driven Organic 3D Topological Insulator with Relativistic Fermions T. Nomoto, S. Imajo, H. Akutsu, Y. Nakazawa, and Y. Kohama Nat. Commun. 14, 2130 (2023) (7 pages).

Thermodynamic Properties of the Mott Insulator-Metal Transition in a Triangular Lattice System without Magnetic Order E. Yesil, S. Imajo, S. Yamashita, H. Akutsu, Y. Saito, A. Pustogow, A. Kawamoto, and Y. Nakazawa Phys. Rev. B 107(4), 045133 (2023)

Magnetic Field Induced Transition in the Charge-Glass Former -(BEDT-TTF)2CsCo(SCN)4 T. Nomoto, S. Yamashita, H. Akutsu, and Y. Nakazawa Phys. Rev. B 107(8), 085121 (2023)

Pseudogap Formation in Organic Superconductors S. Imajo, T. Kobayashi, Y. Matsumura, T.Maeda, Y. Nakazawa, H. Taniguchi, and K. Kindo Phys. Rev. Mater. 7(12), 124803 (2023)

分子性電荷移動塩の超伝導ギャップの構造と対称性の熱力学的解析 今城周作，中澤康浩 日本物理学会誌 78(2), 79-84 (2023).

スピン液体物質における三角格子異方性による熱力学的特徴への影響 山下智史，圷 広樹，中澤康浩 大阪大学低温センター研究報告書（令和 4 年度） (2023)

Electronic Heat Capacity and Lattice Softening of Partially Deuterated Compounds of - (BEDT-TTF)2Cu[N(CN)2]Br
Y. Matsumura, S. Imajo, S. Yamashita, H. Akutsu, and Y. Nakazawa
Crystals 12(1), 2 (2022) (12 pages).

A 2D Interactive Spin Ladder System, -(BEDT-TTF)2ClC2H4SO3H2O
H. Akutsu, S. S. Turner, and Y. Nakazawa
Cryst. Growth Des. 22(9), 5143–5147 (2022).

Enantiopure and Racemic Radical-Cation salts of B(mandelate)2  and B(2- chloromandelate)2  Anions with BEDT-TTF
T. J. Blundell, J. R. Lopez, K. Sneade, J. D. Wallis, H. Akutsu, Y. Nakazawa, S. J. Coles, C. Wilson, and L. Martin
Dalton. Trans. 51(12), 4843–4852 (2022).

Role of the Anion Layer’s Polarity in Organic Conductors -(BEDT-TTF)2XC2H4SO3 (X = Cl and Br)
H. Akutsu, M. Uruichi, S. Imajo, K. Kindo, Y. Nakazawa, and S. S. Turner
J. Phys. Chem. C 126(38), 16529–16538 (2022).

Enhancements of Superconductivity and Insulating Electrical Resistivity under the Same Uniaxial Strain in a Moleculra Conductor
Y. Okii, T. Yamamoto, T. Naito, K. Konishi, H. Akutsu, and Y. Nakazawa
J. Phys. Soc. Jpn. 91(3), 034707 (2022) (9 pages).

Thermodynamic measurements of doped dimer-Mott organic superconductor under pressure
Y. Matsumura, S. Yamashita, H. Akutsu, and Y. Nakazawa
Low Temp. Phys. 48(1), 51–56 (2022).

Molecular Conductors from Bis(ethylenedithio)tetrathiafulvalene with Tris(oxalato)gallate and Tris(oxalato)iridate
T. J. Blundell, A. L. Morritt, E. K. Rusbridge, L. Quibell, J. Oakes, H. Akutsu, Y. Nakazawa, S. Imajo, T. Kadoya, J. Yamada, S. J. Coles, J. Christensen, and L. Martin
Mater. Adv. 3(11), 4724–4735 (2022).

Persistence of Fermionic Spin Excitations through a Genuine Mott Transition in -Type Organics
S. Imajo, N. Kato, R. J. Marckwardt, E. Yesil, H. Akutsu, and Y. Nakazawa
Phys. Rev. B 105(12), 125130 (2022) (7 pages).

Systematic Study on Thermal Conductivity of Organic Triangular Lattice Systems - X[Pd(dmit)2]2
T. Nomoto, S. Yamashita, H. Akutsu, Y. Nakazawa, and R. Kato
Phys. Rev. B 105(24), 245133 (2022) (7 pages).

電荷ガラス状態を形成する分子性化合物の熱輸送特性
野本哲也，山下智史，圷 広樹，中澤康浩
大阪大学低温センター研究報告書（令和 2 年度）21–25 (2022).

巻頭言 コロナ禍から未来にむけて
中澤康浩
熱測定 49(1), 1 (2022).

Large-Amplitude Thermal Vibration-Coupled Valence Tautomeric Transition Observed in a Conductive One-Dimensional Rhodium–Dioxolene Complex
M. Mitsumi, Y. Komatsu, M. Hashimoto, K. Toriumi, Y. Kitagawa, Y. Miyazaki, H. Akutsu, and H. Akashi
Chem. Eur. J. 27(9), 3074–3084 (2021).

Comprehensive Thermodynamic Study of Three Co(II)- and Fe(II)-Based Octacyanoniobates
R. Pełka, P. Konieczny, Y. Miyazaki, Y. Nakazawa, T. Wasiutyński, A. Budziak, D. Pinkowicz, and B. Sieklucka
Phys. Rev. B 104(21), 214428 (2021) (18 pages).

Chiral Metal Down to 4.2 K – a BDH-TTP Radical-Cation Salt with Spiroboronate Anion B(2-chloromandelate)2
− T. J. Blundell, M. Brannan, H. Nishimoto, T. Kadoya, J. Yamada, H. Akutsu, Y. Nakazawa, and L. Martin
Chem. Commun. 57(44), 5406–5409 (2021).

Fermi Surface Structure and Isotropic Stability of Fulde-Ferrell-Larkin-Ovchinnikov Phase in Layered Organic Superconductor -(BEDT-TTF)2SF5CH2CF2SO3
S. Sugiura, H. Akutsu, Y. Nakazawa, T. Terashima, S. Yasuzuka, J. A. Schlueter, and S. Uji
Crystals 11(12), 1525 (2021) (10 pages).

Structural, Magnetic and Mössbauer Spectroscopic Studies of the [Fe(3-bpp)2](CF3COO)2 Complex: Role of Crystal Packing Leading to an Incomplete Fe(II) High Spin ⇋ Low Spin Transition
K. H. Sugiyarto, D. Onggo, H. Akutsu, V. R. Reddy, H. Sutrisno, Y. Nakazawa, and A. Bhattacharjee
CrystEngComm 23(15), 2854–2861 (2021)

Exceptionally High Temperature Spin Crossover in Amide-Functionalised 2,6-Bis(pyrazol1-yl)pyridine Iron(II) Complex Revealed by Variable Temperature Raman Spectroscopy and Single Crystal X-Ray Diffraction
M. Attwood, H. Akutsu, L. Martin, T. J. Blundell, P. Le Maguere, and S. S. Turner
Dalton Trans. 50(34), 11843–11851 (2021)

Thermodynamic Measurements of Doped Dimer-Mott Organic Superconductor under Pressure
Y. Matsumura, S. Yamashita, H. Akutsu, and Y. Nakazawa
Fiz. Nizk. Temp. 48, 56 (2021) (6 pages).

Asymmetric N-Heteroacene Tetracene Analogues as Potential n-Type Semiconductors
M. Attwood, D. K. Kim, J. H. L. Hadden, A. Maho, W. Ng, H. Wu, H. Akutsu, A. J. P. White, S. Heutz, and M. Oxborrow
J. Mater. Chem. C 9(47), 17073–17083 (2021).

Magnetic Properties of S = 1/2 Distorted Kagome Antiferromagnet CdCu3(OH)6Cl2 with Low-Symmetry Orbital Arrangement
H. K. Yoshida, N. Noguchi, Y. Ishii, M. Oda, J. Chen, K. Yamaura, S. Yamashita, Y. Nakazawa, T. Kida, Y. Narumi, and M Hagiwara
J. Phys. Soc. Jpn. 90(4), 044714 (2021) (6 pages).

Lattice and Charge Fluctuations in a Molecular Superconductors
T. Yamamoto, T. Naito, M. Uruichi, H. Akutsu, and Y. Nakazawa
J. Phys. Soc. Jpn. 90(6), 063708 (2021) (5 pages).

New Spin-Crossover Compounds Containing the [Ni(mnt)] Anion (mnt = Maleonitriledithiolate)
S. S. Turner, J. Daniell, H. Akutsu, P. N. Holton, S. J. Coles, and V. Schünemann
Magnetochemistry 7(5), 72 (2021) (12 pages).

First Molecular Superconductor with the Tris(Oxalato)Aluminate Anion, -(BEDTTTF)4(H3O)Al(C2O4)3C6H5Br, and Isostructural Tris(Oxalato)Cobaltate and Tris(Oxalato)Ruthenate Radical Cation Salts
T. J. Blundell, M. Brannan, J. Mburu-Newman, H. Akutsu, Y. Nakazawa, S. Imajo, and L. Martin
Magnetochemistry 7(7), 90 (2021) (12 pages).

Structures and Properties of New Organic Molecule-Based Metals, (D)2BrC2H4SO3 [D = BEDT-TTF and BETS]
H. Akutsu, Y. Koyama, S. S. Turner, and Y. Nakazawa
Magnetochemistry 7(7), 91 (2021) (13 pages).

Symmetry Change of d-Wave Superconductivity in -Type Organic Superconductors
S. Imajo, K. Kindo, and Y. Nakazawa
Phys. Rev. B 103(6), L060508 (2021) (5 pages).

Thermodynamic Evidence for the Formation of a Fulde-Ferrell-Larkin-Ovchinnikov Phase in the Organic Superconductor -(BETS)2GaCl4
S. Imajo, T. Kobayashi, A. Kawamoto, K. Kindo, and Y. Nakazawa
Phys. Rev. B 103(22), L220501 (2021) (5 pages).

Extraordinary -Electron Superconductivity Emerging from a Quantum Spin Liquid
S. Imajo, S. Sugiura, H. Akutsu, Y. Kohama, T. Isono, T. Terashima, K. Kindo, S. Uji, and Y. Nakazawa
Phys. Rev. Res. 3(3), 033026 (2021) (9 pages).

Electric Dipole Induced Bulk Ferromagnetism in Dimer Mott Molecular Compounds
R. Yoshimoto, S. Yamashita, H. Akutsu, Y. Nakazawa, T. Kusamoto, Y. Oshima, T. Nakano, H. M. Yamamoto, and R. Kato
Sci. Rep. 11, 1332 (2021) (10 pages).

1 Experimental Heat Capacity of Low-Dimensional Systems: Carbon Nanotubes and 1D Atomic and Molecular Chains of Adsorbates
M. Barabashko and Y. Nakazawa
Netsu Sokutei 48(4), 164–170 (2021).

化学便覧 基礎編 改訂 6 版
中澤康浩（日本化学会編，執筆分担）
B5，1536 頁 丸善（2021 年 1 月発行）．

たった 1 つの−CH 基の向きの違いで物性が変った 不斉中心を有する有機伝導体-(BEDT-TTF)2(rac-および S-PROXYL-CONHCH2SO3) の構造と物性の比較
圷 広樹
低温センターだより 171, 2–8 (2021).

音を奏でる気柱振動ヘリウム液面計
圷 広樹
低温センターだより 171, 13–14 (2021).

フロギストン 核スピンの超微細構造
中澤康浩
熱測定 48(4), 172–173 (2021).

フロギストン 回転トンネル現象
中澤康浩
熱測定 48(4), 173 (2021).

Single-Crystal-to-Single-Crystal Installation of Ln4(OH)4 Cubanes in an Anionic Metallosupramolecular Framework
N. Yoshinari, N. Meundaeng, H. Tabe, Y. Yamada, S. Yamashita, Y. Nakazawa, and T. Konno
Angew. Chem. Int. Ed. 59(41), 18048–18053 (2020).

Chiral Molecular Conductor with an Insulator-Metal Transition Close to Room Temperature
J. I. Short, T. J. Blundell, S. J. Krivickas, S. Yang, D. J. Wallis, H. Akutsu, Y. Nakazawa, and L. Martin
Chem. Comm. 56(66), 9497–9500 (2020).

Structure and Properties of a New Purely Organic Magnetic Conductor, -(BEDT-TTF)2(PO-CONHCH(cyclopropyl)SO3)1.7H2O
H. Akutsu, A. Kohno, S. S. Turner, and Y. Nakazawa
Chem. Lett. 49(11), 1345–1348 (2020).

Structures and Properties of New Organic Conductors: BEDT-TTF, BEST and BETS Salts of the HOC2H4SO3 Anion
H. Akutsu, Y. Koyama, S. S. Turner, K. Furuta, and Y. Nakazawa
Crystals 10(9), 775 (2020) (13 pages).

Single Crystal Heat Capacity Measurement of Charge Glass Compound -(BEDT-TTF)2CsZn(SCN)4 Performed under Current and Voltage Application
K. Hino, T. Nomoto, S. Yamashita, and Y. Nakazawa
Crystals 10(11), 1060 (2020) (9 pages).

Variation of Electronic Heat Capacity of -(BEDT-TTF)2Cu[N(CN)2]Br Induced by Partial Substitution of Donor Layers
E. Yesil, S. Imajo, T. Nomoto, S. Yamashita, H. Akutsu, and Y. Nakazawa
J. Phys. Soc. Jpn. 89(7), 073701 (2020) (5 pages).

Different Electronic States of Isomorphous Chiral vs. Racemic Organic Conducting Salts, -(BEDT-TTF)2(S- and rac-PROXYL-CONHCH2SO3)
H. Akutsu, A. Kohno, S. S. Turner, S. Yamashita, and Y. Nakazawa
Mater. Adv. 1(9), 3171–3175 (2020).

Thermodynamic Properties of Glassy Phonon States Induced by Strong Electron Correlations in -Type Organic Charge Transfer Salts
T. Nomoto, E. Yesil, S. Yamashita, H. Akutsu, and Y. Nakazawa
Mod. Phys. Lett. B 34(19&20), 2040059 (2020) (7 pages).

Development of Frequency Tuning AC Modulation Method for High-Pressure Heat Capacity Measurements of Molecules-Based Compounds
T. Nomoto, T. Maruyama, S. Yamashita, H. Akutsu, and Y. Nakazawa
Mod. Phys. Lett. B 34(19&20), 2040062 (2020) (8 pages).

Anisotropic Fully Gapped Superconductivity Possibly Mediated by Charge Fluctuations in a Nondimeric Organic Complex
S. Imajo, H. Akutsu, R. Kurihara, T. Yajima, Y. Kohama, M. Tokunaga, K. Kindo, and Y. Nakazawa
Phys. Rev. Lett. 125(17), 177002 (2020) (6 pages).

Mobility of Hydrated Alkali Metal Ions in Metallosupramolecular Ionic Crystals
N. Yoshinari, S. Yamashita, Y. Fukuda, Y. Nakazawa, and T. Konno
Chem. Sci. 10(2), 587–593 (2019).

Above Room Temperature Spin Crossover in Thioamide-Functionalised 2,6-Bis(pyrazol-1-yl)pyridine Iron(II) Complexes
M. Attwood, H. Akutsu, L. Martin, D. Cruickshank, and S. S. Turner
Dalton Trans. 48(1), 90–98 (2019).

2D Molecular Superconductor to Insulator Transition in the -(BEDT-TTF)2[(H2O)(NH4)2M(C2O4)3]18-crown-6 Series (M = Rh, Cr, Ru, Ir)
A. L. Morritt, J. R. Lopez, T. J. Blundell, E. Canadell, H. Akutsu, Y. Nakazawa, S. Imajo, and L. Martin
Inorg. Chem. 58(16), 10656–10664 (2019).

Gap Symmetry of the Organic Superconductor -(BETS)2GaCl4 Determined by Magnetic-Field-Angle-Resolved Heat Capacity
S. Imajo, S. Yamashita, H. Akutsu, H. Kumagai, T. Kobayashi, A. Kawamoto, and Y. Nakazawa
J. Phys. Soc. Jpn. 88(2), 023702 (2019) (5 pages).

Phonon Glass Induced by Electron Correlation
T. Nomoto, S. Yamashita, H. Akutsu, Y. Nakazawa, and A. I. Krivchikov
J. Phys. Soc. Jpn. 88(7), 073601 (2019) (4 pages).

Construction of a Thermal Conductivity Measurement System for Small Single Crystals of Organic Conductors
T. Nomoto, S. Imajo, S. Yamashita, H. Akutsu, Y. Nakazawa, and A. I. Krivchikov
J. Therm. Anal. Calor. 135(5), 2831–2836 (2019).

Thermal Expansion of Organic Superconductor -(BEDT-TTF)2NH4Hg(SCN)4
A. V. Dolbin, M. V. Khlistuck, V. B. Eselson, V. G. Gavrilko, N. A. Vinnikov, R. M. Basnukaeva, V. A. Konstantinov, K. R. Luchinskii, and Y. Nakazawa
Low Temp. Phys. 45(1), 128–131 (2019).

Electron Transport in Carbon Nanotubes with Adsorbed Chromium Impurities
S. Repetsky, I. Vyshyvana, Y. Nakazawa, S. Kruchinin, and S. Bellucci
Materials 12(3), 524 (2019) (32 pages).

Effects of Electron Correlations and Chemical Pressures on Superconductivity of -Type Organic Compounds
S. Imajo, H. Akutsu, A. Akutsu-Sato, A. L. Morritt, L. Martin, and Y. Nakazawa
Phys. Rev. Res. 1(3), 033184 (2019) (7 pages).

Control of the Spin Dynamics of Single-Molecule Magnets by Using a Quasi OneDimensional Arrangement
K. Katoh, S. Yamashita, N. Yasuda, Y. Kitagawa, K. B. Breedlove, Y. Nakazawa, and M.Yamashita
Angew. Chem. Int. Ed. 57(30), 9262–9267 (2018).

Structure and Properties of a BEDT-TTF-Based Organic Conductor with a Ferrocene-Based Magnetic Anion Octamethylferrocenedisulfonate
H. Akutsu, R. Hashimoto, J. Yamada, S. Nakatsuji, S. S. Turner, and Y. Nakazawa
Eur. J. Inorg. Chem. 2018(27), 3249–3252 (2018).

A New Ni(dmit)2-Based Organic Magnetic Charge-Transfer Salt, (m-PO-CONH-N-methylpyridinium)[Ni(dmit)2]CH3CN
H. Akutsu, S. Ito, T. Kadoya, J. Yamada, S. Nakatsuji, S. S. Turner, and Y. Nakazawa
Inorg. Chim. Acta 482, 654-658 (2018).

Thermodynamic Investigation by Heat Capacity Measurements of -Type Dimer-Mott Organic Compounds with Chemical Pressure Tuning
Y. Matsumura, S. Imajo, S. Yamashita, H. Akutsu, and Y. Nakazawa
Int. J. Mod. Phys. B 32(17), 1840024 (2018) (7 pages).

Development of Light Irradiation Calorimetry System for Molecule-Based Compounds
Y. Matsumura, S. Kataoka, S. Imajo, S. Yamashita, H. Akutsu, and Y. Nakazawa
Int. J. Mod. Phys. B 32(17), 1840035 (2018) (6 pages).

Experimental and Theoretical Aspects of Thermodynamic Properties of Quasi-1D and Quasi-2D Organic Conductors and Superconductors
Y. Nakazawa and S. P. Kruchinin
Int. J. Mod. Phys. B 32(17), 1840036 (2018) (38 pages).

Superconducting Phase Diagram of the Organic Superconductor -(BEDT-TTF)2Cu[N(CN)2]Br above 30 T
S. Imajo, Y. Nakazawa, and K. Kindo
J. Phys. Soc. Jpn. 87(12), 123704 (2018) (5 pages).

Fulde-Ferrell-Larkin-Ovchinnikov Superconductivity in the Layered Organic Superconductor ”-(BEDT-TTF)4[(H3O)Ga(C2O4)3]C6H5NO2
S. Uji, Y. Iida, S. Sugiura, T. Isono, K. Sugii, N. Kikugawa, T. Terashima, S. Yasuzuka, H. Akutsu, Y. Nakazawa, D. Graf, and P. Day
Phys. Rev. B 97(14), 144505 (2018) (9 pages).

Dielectric Jump and Negative Electrostriction in Metallosupramolecular Ionic Crystals
S. Yamashita, Y. Nakazawa, S. Yamanaka, M. Okumura, T. Kojima, N. Yoshinari, and T. Konno
Sci. Rep. 8, 2606 (2018) (8 pages).

New Semiconducting Radical-Cation Salts of Chiral Bis(2-hydroxylpropylthio)ethylenedithio TTF
J. R. Lopez, L. Martin, J. D. Wallis, H. Akutsu, J. Yamada, S. Nakatsuji, C. Wilson, J. Christensend, and S. J. Coles
CrystEngComm 19(32), 4848–4856 (2017).

Pressure Effect Studies on the High Spin ⇆ Low Spin Transition Behavior Observed in [Fe(II)(bpp)2](NCS)22H2O
A. Bhattacharjee, M. Sugimoto, Y. Nakazawa, and H. A. Goodwin
Curr. Smart Mater. 2(1), 65–72 (2017).

Enantiopure and Racemic Radical-Cation Salts of Bis(2-hydroxylpropylthio)(ethylenedithio)TTF with Polyiodide Anions
L. Martin, J. D. Wallis, M. Guziak, P. Maksymiw, F. Konalian-Kempf, A. Christian, S. Nakatsuji, J. Yamada, and H. Akutsu
Dalton Trans. 46(13), 4225–4234 (2017).

Molecular Conductors from Bis(ethylenedithio)tetrathiafulvalene with Tris(oxalato)rhodate
L. Martin, A. L. Morritt, J. R. Lopez, Y. Nakazawa, H. Akutsu, S. Imajo, Y. Ihara, B. Zhang, Y. Zhang, and Y. Guo
Dalton Trans. 46(29), 9542–9548 (2017).

Ambient-Pressure Molecular Superconductor with a Superlattice Containing Layers of Tris(oxalato)rhodate Enantiomers and 18-Crown-6
L. Martin, A. L. Morritt, J. R. Lopez, H. Akutsu, Y. Nakazawa, S. Imajo, and Y. Ihara
Inorg. Chem. 56(2), 717–720 (2017).

Increase in the Magnetic Ordering Temperature (Tc) as a Function of the Applied Pressure for A2Mn[Mn(CN)6] (A = K, Rb, Cs) Prussian Blue Analogues
M. Sugimoto, S. Yamashita, H. Akutsu, Y. Nakazawa, J. G. DaSilva, C. M. Kareis, and J. S. Miller
Inorg. Chem. 56(17), 10452–10457 (2017).

Bulk Kosterlitz-Thouless Type Molecular Superconductor -(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]18-crown-6
L. Martin, J. Lopez, H. Akutsu, Y. Nakazawa, and S. Imajo
Inorg. Chem. 56(22), 14045–14052 (2017).

Anisotropic Field Dependence of the Superconducting Transition in the Magnetic Molecular Superconductor -(BETS)2FeBr4
S. Fukuoka, S. Yamashita, Y. Nakazawa, T. Yamamoto, and H. Fujiwara
J. Phys. Soc. Jpn. 86(1), 014706 (2017) (6 pages).

Unusual Magnetic State with Dual Magnetic Excitations in the Single Crystal of S = 1/2 Kagome Lattice Antiferromagnet CaCu3(OH)6Cl20.6H2O
H. Yoshida, N. Noguchi, Y. Matsushita, Y. Ishii, Y. Ihara, M. Oda, H. Okabe, S. Yamashita, Y. Nakazawa, A. Takata, T. Kida, Y. Narumi, and M. Hagiwara
J. Phys. Soc. Jpn. 86(3), 033704 (2017) (5 pages).

Dimensional Crossover and Its Interplay with In-Plane Anisotropy of Upper Critical Field in -(BDA-TTP)2SbF6
S. Yasuzuka, H. Koga, Y. Yamamura, K. Saito, S. Uji, T. Terashima, H. Akutsu, and J. Yamada
J. Phys. Soc. Jpn. 86(8), 084704 (2017) (6 pages).

New Dmit-Based Organic Magnetic Conductors (PO-CONH-C2H4N(CH3)3)[M(dmit)2]2 (M = Ni, Pd) Including an Organic Cation Derived from a 2,2,5,5-Tetramethyl-3-pyrrolin-1-oxyl (PO) Radical
H. Akutsu, S. S. Turner, and Y. Nakazawa
Magnetochemistry 3(1), 11 (2017) (11 pages).

Fermi Surface in the Absence of a Fermi Liquid in the Kondo Insulator SmB6
M. Hartstein, W. H. Toews, Y.-T. Hsu, B. Zeng, X. Chen, M. Ciomaga Hatnean, Q. R. Zhang, S. Nakamura, A. S. Padgett, G. Rodway-Gant, J. Berk, M. K. Kingston, G. H. Zhang, M. K. Chan, S. Yamashita, T. Sakakibara, Y. Takano, J.-H. Park, L. Balicas, N. Harrison, N. Shitsevalova, G. Balakrishnan, G. G. Lonzarich, R. W. Hill, M. Sutherl, and S. E. Sebastian
Nature Phys. (2017) (doi:10.1038/nphys4295).

Thermodynamics of the Quantum Spin Liquid State of the Single-Component Dimer Mott System -H3(Cat-EDT-TTF)2
S. Yamashita, Y. Nakazawa, A. Ueda, and H. Mori
Phys. Rev. B 95(18), 184425 (2017) (5 pages).

Anion Polarity-Induced Self-Doping in a Purely Organic Paramagnetic Conductor, --(BEDT-TTF)2(PO-CONH-m-C6H4SO3)H2O where BEDT-TTF is Bis(ethylenedithio) tetrathiafulvalene and PO Is the Radical 2,2,5,5-Tetramethyl-3-pyrrolin-1-oxyl
H. Akutsu, K. Ishihara, S. Ito, F. Nishiyama, J. Yamada, S. Nakatsuji, S. S. Turner, and Y. Nakazawa
Polyhedron 136, 23–29 (2017).

Magnetocaloric Effect of High-Spin Cluster with Ni₉W₆ Core
M. Gajewski, R. Pełka, M. Fitta, Y. Miyazaki, Y. Nakazawa, M.Bałanda, M. Reczyński, B. Nowicka, and B. Sieklucka
J. Magn.Magn. Mater. 414, 25–31 (2016).

Magnetocaloric Effect in Mn2-pyrazole-[Nb(CN)₈] Molecular Magnet by Relaxation Calorimetry
R. Pełka, M. Gajewski, Y. Miyazaki, S. Yamashita, Y. Nakazawa, M. Fitta, D. Pinkowicz, and B. Sieklucka
J. Magn. Magn. Mater. 419, 435–441 (2016).

A Strongly Polarized Organic Conductor
H. Akutsu, K. Ishihara, J. Yamada, S. Nakatsuji, S. S. Turner, and Y. Nakazawa
CrystEngComm 18(42), 8151–8154 (2016).

New Family of Six Stable Metals with a Nearly Isotropic Triangular Lattice of Organic Radical Cations and Diluted Paramagnetic System of Anions: k (k_&perp)-(BDH-TTP)₄MX₄Solv, where M = Co^II, Mn^II; X = Cl, Br, and Solv = (H₂O)₅, (CH₂X₂)
A. A. Bardin, H. Akutsu, and J. Yamada
Cryst. Growth Des. 16(3), 1228–1246 (2016).

Enantiopure and Racemic Radical-Cation Salts of B(malate)2 Anions with BEDT-TTF
J. R. Lopez, L. Martin, J. D. Wallis, H. Akutsu, Y. Nakazawa, J. Yamada, T. Kadoya, S. J. Coles, and C. Wilson
Dalton Trans. 45(22), 9285–9293 (2016).

Rotational Tunneling of Methyl Groups and the Electronic Heat Capacity of EtMe3Sb[Pd(dmit)2]2 under Magnetic Fields
S.Yamashita, M.Yoshizumi, H.Akutsu, Y.Nakazawa, K.Ueda, and R.Kato
Int. J. Mod. Phys. B 30(13), 1642007 (2016).

Quadratic Temperature Dependence of Electronic Heat Capacities in the -Type Organic Superconductors
S. Imajo, S. Yamashita, H. Akutsu, and Y. Nakazawa
Int. J. Mod. Phys. B 30(13), 1642014 (2016) (7 pages).

Thermodynamics of the d-Wave Pairing in Organic Superconductors
S. Kruchinin, A. Zolotovsky, S. Yamashita, and Y. Nakazawa
Int. J. Mod. Phys. B 30(13), 1642020 (2016).

Thermodynamic Evidence of d-Wave Superconductivity of the Organic Superconductor -(BETS)2GaCl4
S. Imajo, N. Kanda, S. Yamashita, H. Akutsu, Y. Nakazawa H. Kumagai, T. Kobayashi, and A. Kawamoto
J. Phys. Soc. Jpn. 85(4), 043705 (2016) (4 pages) (Editors’ Choice).

Anisotropic Field Dependence of the Superconducting Transition in the Magnetic Molecular Superconductor -(BETS)2FeBr4
S. Fukuoka, S. Yamashita, Y. Nakazawa, T. Yamamoto, and H. Fujiwara
J. Phys. Soc. Jpn. (2016) in press.

Construction of Relaxation Calorimetry for 101–2 Micro-gram Samples and Heat Capacity Measurements of Organic Complexes
S. Imajo, S. Fukuoka, S. Yamashita, and Y. Nakazawa
J. Therm. Anal. Calorim. 123(3), 1871–1876 (2016).

Cooling-Rate-Controlled Heat Capacity Measurements of Organic Superconductor (TMTSF)2ClO4
S. Morishita, R. Yoshimoto, S. Fukuoka, S. Yamashita, H. Akutsu, and Y. Nakazawa
J. Therm. Anal. Calorim. 123(3), 1877–1881 (2016).

Thermal Anomaly around the Superconductive Transition of -(BEDT-TTF)2Cu(NCS)2 with External Pressure and Magnetic Field Control
Y. Muraoka, S. Imajo, S. Yamashita, H. Akutsu, and Y. Nakazawa
J. Therm. Anal. Calorim. 123(3), 1891–1897 (2016).

Peculiarities of Thermal Expansion of Quasi-Two-Dimensional Organic Conductors -(BEDT-TTF)2Cu[N(CN)2]Cl
A. V. Dolbin, M. V. Khlistuck, V. B. Eselson, V. G. Gavrilko, N. A. Vinnikov, R. M. Basnukaeva, V. V. Danchuk, V. A. Konstantinov, and Y. Nakazawa
Low Temp. Phys. 42(9), 788–793 (2016).

Thermodynamic Properties of Antiferromagnetic Ordered States of -d Interacting Systems of -(BETS)2FeX4 (X = Br, Cl)
S. Fukuoka, S. Yamashita, Y. Nakazawa, T. Yamamoto, H. Fujiwara, T. Shirahata, and K. Takahashi
Phys. Rev. B 93(24), 245136 (2016) (7 pages).

AC Calorimetry System Using Commercially Available Microchip Device and its Application for Tiny Single Crystals of Molecule-Based Compounds
M. Murase, S. Yamashita, R. Yoshimoto, S. Imajo, Y. Nakazawa, K. Ueda, and R. Kato
Thermochim. Acta (2016) in press.

Chirality in Charge-Transfer Salts of BEDT-TTF of Tris(oxalato)chromate(III)
L. Martin, H. Akutsu, P. N. Horton and M. B. Hursthouse CrystEngComm 17(14), 2783-2790 (2015).

Radical-Cation Salts of BEDT-TTF with Lithium Tris(oxalato)metallate(III)
L. Martin, H. Engelkamp H. Akutsu, S. Nakatsuji, J. Yamada, P. Horton, and M. B. Hursthouse Dalton Trans. 44(13), 6219-6223 (2015).

Chiral Radical-Cation Salts of BEDT-TTF Containing a Single Enantiomer of Tris(oxalato)aluminate(III) and -chromate(III)
L. Martin, H. Akutsu, P. N. Horton, M. B. Hursthouse, R. W. Harrington, and W. Clegg Eur. J. Inorg. Chem. 2015(11), 1865-1870 (2015).

Structures and Properties of New Ferrocene-Based Paramagnetic Anion Octamethylferrocenedisulfonate and Its TTF Salt
H. Akutsu, R. Hashimoto, J. Yamada, S. Nakatsuji, Y. Nakazawa, and S. S. Turner Inorg. Chem. Commun. 61, 41-47 (2015).

Transitions in Pressure Collapsed Clathrate Hydrates
O. Andersson and Y. Nakazawa J. Phys. Chem. B 119(9), 3846-3853 (2015).

Construction of Relaxation Calorimetry for 101-2 Micro-gram Samples and Heat Capacity Measurements of Organic Complexes
S. Imajo, S. Fukuoka, S. Yamashita, and Y. Nakazawa J. Therm. Anal. Calorim. (2015) in press.

Cooling-Rate-Controlled Heta Cpacity Measurements of Organic Superconductor (TMTSF)₂ClO₄
S. Morishita, R. Yoshimoto, S. Fukuoka, S. Yamashita, H. Akutsu, and Y. Nakazawa J. Therm. Anal. Calorim. (2015) in press.

Heat Capacity of Spin Liquid System of EtMe₃Sb[Pd(dmit)₂]₂
S. Yamashita, R. Yoshimoto, S. Fukuoka, Y. Nakazawa, and R. Kato Quantum Matter 4(4), 314-318 (2015).

exo-Methylene-BEDT-TTF and Alkene-Functionalised BEDT-TTF Derivatives: Synthesis and Radical Cation Salts
M. Zecchini, J. R. Lopez, S. W. Allen, S. J. Coles, C. Wilson, H. Akutsu, L. Martin, and J. D. Wallis RSC Adv. 5(39), 31104-31112 (2015).

Structures and Properties of Diradical Compounds Containing Disulfide and Nitroxide Groups
K. Fujikura, H. Akutsu, J. Yamada, S. Nakatsuji, and M. Satoh, Synth. Met. 208, 17-20 (2015).

Radical-Cation Salt with Novel BEDT-TTF Packing Motif Containing Tris(oxalato)germanate(IV)
J. R. Lopez, H. Akutsu, and L. Martin Synth. Met. 209, 188-191 (2015).

Gradual Crossover in Molecular Organization of Stable Liquid H₂O at Moderately High Pressure and Temperature
Y. Koga, P. Westh, K. Yoshida, A. Inaba, and Y. Nakazawa AIP Adv. 4(9), 097116 (2014) (11 pages).

Stereoisomeric Semiconducting Radical Cation Salts of Chiral Bis(2- hydroxypropylthio)ethylenedithioTTF with Tetrafluoroborate Anions
L. Martin, J. D. Wallis, M. A. Guziak, J. Oxspring, J. R. Lopez, S. Nakatsuji, J. Yamada, and H. Akutsu CrystEngComm 16(24), 5424-5429 (2014).

Thermodynamic Investigation by Heat Capacity Measurements of Ferrimagnetic A₂Mn[Mn(CN)₆] (A = K, Rb, Cs) Prussian Blue Compounds
Y. Kawamoto, S. Yamashita, R. Yoshimoto, Y. Nakazawa, J. G. DaSilva, C. M. Kareis, and J. S. Miller J. Phys.: Condens. Matter 26(1), 016001 (2014) (6 pages).

Magnetic Torque Studies of π- d System κ -(BDH-TTP)₂FeX₄ (X = Br, Cl) 7
K. Sugii, K. Takai, S. Tsuchiya, S. Uji, T. Terashima, H. Akutsu, A. Wada, S. Ichikawa, J. Yamada, and T. Enoki J. Phys. Soc. Jpn. 83(2), 023704 (2014) (4 Pages).

Property of the Valence-Bond Ordering in Molecular Superconductor with a QuasiTriangular Lattice
T. Yamamoto, Y. Nakazawa, M. Tamura, A. Nakao, A. Fukaya, R. Kato, and K. Yakushi J. Phys. Soc. Jpn. 83(5), 053703 (2014) (5 Pages).

A Series of Two Oxidation Reactions of ortho-Alkenylbenzamide with Hypervalent Iodine(III): A Concise Entry into (3R,4R)-4-Hydroxymellein and (3R,4R)-4-Hydroxy-6- methoxymellein
T. Takesue, M. Fujita, T. Sugimura, and H. Akutsu Org. Lett. 16(17), 4634-4637 (2014).

Coupling of Charge and Lattice Degrees of Freedoms in θ-Type BEDT-TTF Compound Probed by Low-Temperature Heat Capacity Measurements
R. Yoshimoto, Y. Takane, K. Hino, S. Yamashita, and Y. Nakazawa Physica B 449, 19-24 (2014).

Heat Capacity of Spin Liquid System of EtMe₃Sb[Pd(dmit)₂]₂
S. Yamashita, R. Yoshimoto, S. Fukuoka, Y. Nakazawa, and R. Kato Quantum Matter (2014) in press.

Crystal Structure of PPh₄[Fe(NO)₂Cl₂]
H. Akutsu, J. Yamada, S. Nakatsuji, and S. S. Turner X-Ray Struct. Anal. Online 30(10), 49-50 (2014).

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〒560-0043
大阪府豊中市待兼山町1-1 G棟1F
大阪大学 大学院理学研究科 化学専攻
物性物理化学研究室
E-mail：nakazawa[at]chem.sci.osaka-u.ac.jp

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