Research Center for Structural Thermodynamics, Graduate School of Science, Osaka University



  1. Detailed Analysis of the Crystal Structure and Magnetic Properties of a Dysprosium(III) Phthalocyaninato Sextuple-Decker Complex: Weak f-f Interactions Suppress Magnetic Relaxation
    Chem. Eur. J. Accepted, doi/10.1002/chem.201805368. (2019).
  2. Y. Horii, K. Katoh, K. Sugimoto, R. Nakanishi, B. K. Breedlove, M. Yamashita

  1. Unexpected Rise of Glass Transition Temperature of Ice Crystallized from Antifreeze Protein Solution
    J. Phys. Chem. Lett. 9, 4512-4515 (2018).
  2. N. Azuma, Y. Miyazaki, M. Nakano and S. Tsuda
  3. A Bis(μ-oxido)dinickel(III) Complex with a Triplet Ground State
    Y. Morimoto, Y. Takagi, T. Saito, T. Ogura, N. Tohnai, M. Nakano, S. Itoh
    Angew. Chem. Int. Ed. 25, 7640-7643 (2018).
  4. Stability of Two-Dimensional Polymorphs for 10,12-Pentacosadyn-1-ol on Graphite Investigated by SPM
    D. Takajo and K. Sudoh
    Appl. Sci. 8(4), 503(1-7) (2018).
  5. Supramolecular Approach for Enhancing Single-Molecule Magnet Properties of Terbium(III)-Phthalocyaninato Double-Decker Complexes with Crown Moieties
    Y. Horii, S. Kishiue, M. Damjanovic, K. Katoh, B. K. Breedlove, M. Enders, M. Yamashita
    Chem. Eur. J. 24, 4320-4327 (2018).
  6. Paramagnetism Enhancement by in situ Electrochemical Hole Doping into Prussian Blue Thin Film
    M. Noguchi, M. Nakano, S. Kang, O. Sato, S. Seki
    Mater. Chem. Front. 2, 1004-1008 (2018).
  7. Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation
    Y. Horii, H. Horie, K. katoh, B. K. Breedlove, M. Yamashita
    Inorg. Chem. 57, 565-574 (2018).

  1. Charge-Transfer Phase Transition of a Cyanide-Bridged FeII/FeIII Coordination Polymer
    K. Zhang, S. Kang, Z. Yao, K. Nakamura, T. Yamamoto, Y. Einaga, N. Azuma, Y. Miyazaki, M. Nakano, S. Kanegawa, and O. Sato
    Angew. Chem. Int. Ed. 55(20), 6047-6050 (2016).
  2. Studies on the Magnetic Ground State of a Spin Mobius Strip
    G. N. Newton, N. Hoshino, T. Matsumoto, T. Shiga, M. Nakano, H. Nojiri, W. Wernsdorfer, Y. Furukawa, and H. Oshio
    Chem. Eur. J. 22(40), 14205-14212 (2016).
  3. Terahertz Absorption Spectroscopy Study of Structural Changes in D-Penicillaminato CuI8CuII6 Clusters Induced by Water Desorption
    H. Suzuki, C. Otani, N. Yoshinari, and T. Konno
    Inorg. Chem. Front. 3, 274-278 (2016).
  4. Magnetocaloric Effect of High-Spin Cluster with Ni9W6 Core
    M. Gajewski, R. Pe-ka, M. Fitta, Y. Miyazaki, Y. Nakazawa, M. Ba-anda, M. Reczy-ski, B. Nowicka, and B. Sieklucka
    J. Magn. Magn. Mater. 414, 25-31 (2016).
  5. Magnetocaloric Effect in Mn2-pyrazole-[Nb(CN)8] Molecular Magnet by Relaxation Calorimetry
    R. Pe-ka, M. Gajewski, Y. Miyazaki, S. Yamashita, Y. Nakazawa, M. Fitta, D. Pinkowicz, and B. Sieklucka
    J. Magn. Magn. Mater. 419, 435-441 (2016).
  6. The Mixing Behavior of Alkanes Adsorbed on Hexagonal Boron Nitride
    M. Forster, J. E. Parker, A. Inaba, C. A. Murray, N. A. Strange, J. Z. Larese, and T. Arnold
    J. Phys. Chem. C 120(45), 25796-25805 (2016).
  7. Mechanocaloric Properties of Poly(dimethylsiloxane) and Ethylene-Propylene Rubbers
    T. Matsuo, N. Azuma, Y. Toriyama, and T. Yoshioka
    J. Therm. Anal. Calorim. 123(3), 1817-1824 (2016).
  8. Rotational Dynamics of Li+ Ions Encapsulated in C60 Cages at Low Temperatures
    H. Suzuki, M. Ishida, M. Yamashita, C. Otani, K. Kawachi, Y. Kasama, and E. Kwon
    Phys. Chem. Chem. Phys. 18, 31384-31387 (2016).
  9. Polymer Morphological Change Induced by Terahertz Irradiation
    H. Hoshina, H Suzuki, C. Otani, M. Nagai, K. Kawase, A. Irizawa, and G. Isoyama
    Sci. Rep. 6, 27180(1-6) (2016).

  1. Proton Order-Disorder Phenomena in a Hydrogen-Bonded Rhodium-η5-Semiquinone Complex: A Possible Dielectric Response Mechanism
    M. Mitsumi, K. Ezaki, Y. Komatsu, K. Toriumi, T. Miyatou, M. Mizuno, N. Azuma, Y. Miyazaki, M. Nakano, Y. Kitagawa, T. Hanashima, R. Kiyanagi, T. Ohhara, and K. Nakasuji
    Chem. Eur. J. 21(27), 9682-9696 (2015).
  2. Structural Switching from Paramagnetic to Single-Molecule Magnet Behaviour of LnZn2 Trinuclear Complexes
    P. L. Then, C. Takehara, Y. Kataoka, M. Nakano, T. Yamamura, and T. Kajiwara
    Dalton Trans. 44(41), 18038-18048 (2015).
  3. Slow Magnetic Relaxation of Light Lanthanide-Based Linear LnZn2 Trinuclear Complexes
    C. Takehara, P. L. Then, Y. Kataoka, M. Nakano, T. Yamamura, and T. Kajiwara
    Dalton Trans. 44(41), 18276-18283 (2015).
  4. Synthesis, Molecular Structure, and Morphological Properties of Dendritic Tetra-2-thienylmethane
    K. Matsumoto, S. Kugo, T. Suzuki, D. Takajo, A. Inaba, Y. Hirao, H. Kurata, and T. Kubo
    Heterocyles. 91(12), 2343-2353 (2015).
  5. Calorimetric Measurements on Li4C60 and Na4C60
    A. Inaba, Y. Miyazaki, P. P. Michalowski, E. Gracia-Espino, B. Sundqvist, and T. Wagberg
    J. Chem. Phys. 142(16), 164706(1-6) (2015).
  6. Thermal Properties of [Cr(NH3)6](BF4)3 Studied by Adiabatic and Relaxation Calorimetry
    N. Gorska, R. Pelka, A. Inaba, E. Mikuli, and M. Mihalik
    J. Chem. Thermodyn. 89, 223-227 (2015).
  7. Third Derivative Thermodynamic Quantities of Aqueous Tetrahydrofuran at 25 ℃
    K.Yoshida, P.Westh, A. Inaba, M. Nakano, and Y. Koga
    J. Mol. Liq. 202, 40-45 (2015).
  8. Pressure Modulation of Backbone Conformation and Intermolecular π-Figuration of Their Conjugated System
    Y. Noguchi, A. Saeki, T. Fujiwara, S. Yamanaka, M. Kumano, T. Sakurai, N. Matsuyama, M. Nakano, N. Hirao, Y. Ohishi, and S. Seki
    J. Phys. Chem. B 119(24), 7219-7230 (2015).
  9. Enhancement of Proton Ordering in the Hexagonal Ice in Contact with Polyethylene Glycol Crystal
    A. Nagoe, M. Oguni, and H. Fujimori
    J. Phys. Chem. C 119(42), 23910-23916 (2015).
  10. Crystallization and Fusion Behaviors, Observed by Adiabatic Calorimetry, of Benzene Confined in Silica Mesopores with Uniform Diameters
    A. Nagoe, M. Oguni, and H. Fujimori
    J. Phys.: Condens. Matter 27(10), 105101(1-9) (2015).
  11. Low-Temperature Heat Capacities of Confined Liquid Benzene, Implying the Behavior of Ordinary Bulk Liquids
    A. Nagoe, M. Oguni, and H. Fujimori
    J. Phys.: Condens. Matter 27(45), 455103(1-10) (2015).
  12. A Ferromagnetically Coupled Fe42 Cyanide-Bridged Nanocage
    S. Kang, H. Zheng, T. Liu, K. Hamachi, S. Kanegawa, K. Sugimoto, Y. Shiota, S. Hayami, M. Mito, T. Nakamura, M. Nakano, M. L. Baker, H. Nojiri, K. Yoshizawa, C. Duan, and O. Sato
    Nature Commun. 6, 5955(1-6) (2015).
  13. Assembling an Alkyl Rotor to Access Abrupt and Reversible Crystalline Deformation of a Cobalt(II) Complex
    S.-Q. Su, T. Kamachi, Z.-S. Yao, Y.-G. Huang, Y. Shiota, K. Yoshizawa, N. Azuma, Y. Miyazaki, M. Nakano, G. Maruta, S. Takeda, S. Kang, S. Kanegawa, and O. Sato
    Nature Commun. 6, 8810(1-7) (2015).
  14. Low-Temperature Thermal Properties of the Aqueous Solutions of Simple Aminoalcohols: Finding of Peculiarities in 1-Amino-2-propanol Solutions
    Y. Shen, A. Nagoe, M. Oguni, H. Kawaji, and H. Fujimori
    Thermochim. Acta 605, 115-120 (2015).

  1. Gradual Crossover in Molecular Organization of Stable Liquid H2O at Moderately High Pressure and Temperature
    Y. Koga, P. Westh, K. Yoshida, A. Inaba, and Y. Nakazawa
    AIP Adv. 4(9), 097116(1-11) (2014).
  2. Ferromagnetic Interaction and Slow Magnetic Relaxation in a Co3 Cluster-Based ThreeDimensional Framework
    B.-Y. Wu, C.-I. Yang, M. Nakano, and G.-H. Lee
    Dalton Trans. 43(1), 47-50 (2014).
  3. A Semi-Flexible Aminotriazine-Based Bis-methylpyridine Ligand for the Design of Nickel(II) Spin Clusters
    Y.-W. Tzeng, C.-J. Lin, M. Nakano, C.-I. Yang, W.-L. Wan, and L.-L. Lai
    Dalton Trans. 43(8), 3044-3047 (2014)
  4. Multifunctional One-Dimensional Rhodium(I)-Semiquinonato Complex: Substituent Effects on Crystal Structures and Solid-State Properties
    M. Mitsumi, S. Ohtake, Y. Kakuno, Y. Komatsu, Y. Ozawa, K. Toriumi, N. Yasuda, N. Azuma, and Y. Miyazaki
    Inorg. Chem. 53(21), 11710-11720 (2014).
  5. Measurement of Extreme Hyperfine Fields in Two-Coordinate High-Spin Fe2+ Complexes by Mossbauer Spectroscopy: Essentially Free-Ion Magnetism in the Solid State
    A. M. Bryan, C.-Y. Lin, M. Sorai, Y. Miyazaki, H. M. Hoyt, A. Hablutzel, A. LaPointe, W. M. Reiff, P. P. Power, and C. E. Schulz
    Inorg. Chem. 53(22), 12100-12107 (2014).
  6. Bistable Multifunctionality and Switchable Strong Ferromagnetic-to-Antiferromagnetic Coupling in a One-Dimensional Rhodium(I)-Semiquinonato Complex
    M. Mitsumi, T. Nishitani, S. Yamasaki, N. Shimada, Y. Komatsu, K. Toriumi, Y. Kitagawa, M. Okumura, Y. Miyazaki, N. A. Inaba, A. Kanda, and N. Hanasaki
    J. Am. Chem. Soc. 136(19), 7026-7037 (2014).
  7. A Comprehensive Study on Crystal Structure, Thermal Behavior, and Molecular Dynamics of [Sr(DMSO)4(NO3)2]
    N. Gorska, E. Szostaka, K. Druzbickiab, E. Mikulia, A. Inabac and Y. Hiraoc
    J. Coord. Chem. 67(19), 3135-3154 (2014).
  8. Magnetocaloric Effect in {[Fe(pyrazole)4]2[Nb(CN)8]・4H2O}n Molecular Magnet
    R. Pelka P. Konieczny, P. M. Zielinski , T. Wasiutynski , Y. Miyazaki, A. Inaba, D. Pinkowicz, and B. Sieklucka
    J. Magn. Magn. Mater. 354, 359-362 (2014).
  9. Heat Capacity of Paramagnetic Nickelocene: Comparison with Diamagnetic Ferrocene
    M. Sorai, Y. Kaneko, and T. Hashiguchi
    J. Phys. Chem. Solids 75(5), 656-661 (2014).
  10. Pressure Dependence of the Liquid-Liquid Phase Transition of Nanopore Water Doped Slightly with Hydroxylamine, and a Phase Behavior Predicted for Pure Water
    A. Nagoe, S. Iwaki, M. Oguni, and K. Tozaki
    J. Phys. Soc. Jpn. 83(9), 094601(1-7) (2014).
  11. Anomalies in the Third Derivatives of Gibbs Energy and Their Temperature Dependence in Aqueous 2-Butoxyethanol and Glycerol: On the so Called Koga Lines
    K. Yoshida, A. Inaba, and Y. Koga
    J. Solution Chem. 43(4), 663-674 (2014).
  12. Two-Dimensional Solid-State Topochemical Reactions of 10,12-Pentacosadiyn-1-ol Adsorbed on Graphite
    D. Takajo, A. Inaba, and K. Sudoh
    Langmuir 30(10), 2738-2744 (2014).
  13. Molecular Motor-Driven Abrupt Anisotropic Shape Change in a Single Crystal of a Ni Complex
    Z.-S. Yao, M. Mito, T. Kamachi, Y. Shiota, K. Yoshizawa, N. Azuma, Y. Miyazaki, K. Takahashi, K. Zhang, T. Nakanishi, S. Kang, S. Kanegawa, and O. Sato
    Nature Chem. 6(12), 1079-1083 (2014).
  14. Temperature-Independent Energy Expenditure in Early Development of the African Clawed Frog Xenopus laevis
    Y. Nagano and K. L. Ode
    Phys. Biol. 11(4), 046008(1-12) (2014).
  15. Proton Dynamics of Two-Dimensional Oxalate-Bridged Coordination Polymers
    S. Miyatsu, M. Kofu, A. Nagoe, T. Yamada, M. Sadakiyo, T. Yamada, H. Kitagawa, M. Tyagi, V. Garcia Sakai, and O. Yamamuro
    Phys. Chem. Chem. Phys. 16(32), 17295?17304 (2014).
  16. Two Polymorphic Forms of 10,12-Pentacosadiyn-1-ol Molecular Layers on Graphite Transferred from an Aqueous Surface
    D. Takajo, A. Inaba, and K. Sudoh
    Surf. Sci. 620, 38-44 (2014).

Review & Book

  1. Rotational Dynamics of Li+ Ions Encapsulated in Fullerene C60 Cages
    Hal Suzuki
    The Bulletin of the Nano Science and Technology 16(2), 59-65 (2018).
  2. 物質化学100問集
    大阪大学インタラクティブ物質科学・カデットプログラム物質化学100問集出版プロジェクト 編/今田 勝巳, 奥村 光隆, 久保 孝史, 塚原 聡, 中澤 康浩 監修 A4版,276頁

  1. アトキンス 物理化学(下)第10版(P. W. Atkins and J. de Paula 著 (10th Edition))
    中野 元裕, 上田 貴洋, 奥村 光隆, 北河 康隆(訳)B5版,560頁
  2. アトキンス 物理化学(上)第10版(P. W. Atkins and J. de Paula 著 (10th Edition))
    中野 元裕, 上田 貴洋, 奥村 光隆, 北河 康隆(訳)B5版,560頁

  1. 双安定な多重機能性を示す一次元ロジウム-セミキノナト錯体の構造物性相関
    満身 稔,宮崎 裕司,北河 康隆
    日本結晶学会誌 58(3), 145-151 (2016).
  2. エンゲル・リード 物理化学(下)(T. Engel and P. Reid 著;Physical Chemistry (3rd Edition))
    稲葉 章(訳)B5版,608頁
  3. アトキンス 物理化学要論(第6版)(P. W. Atkins and J. de Paula 著;Elements of Physical Chemistry (6th Edition))
    稲葉 章(訳)B5版,600頁
  4. ボール 物理化学(第2版)(下)(D. W. Ball 著;Physical Chemistry (2nd Edition))
    阿竹 徹,彌田 智一,大谷 文章,川路 均,田中 一義,中澤 康浩(訳)(田中 一義,阿竹 徹(監訳))B5,480頁
  5. XYスピンで作るイジング鎖
    中野 元裕
    低温センターだより 164-165, 5-9 (2016).
  6. 一次元ロジウム(I)-セミキノナト錯体の熱容量と相転移
    宮崎 裕司,中野 元裕
    低温センター研究報告書(平成26年度)44-49 (2016).

  1. 現代に生きる実験熱力学研究
    中野 元裕
    生産と技術 67(2), 59-61 (2015).
  2. 細孔水へのヒドロキシルアミン添加効果:液-液相転移の発現とその組成・圧力依存性
    名越 篤史,小國 正晴
    熱測定 42(2), 54-61 (2015).
  3. 熱力学との対比による複雑系科学の展望
    長野 八久
    唯物論と現代 53, 29-44 (2015).
  4. 平和学習のためのフィールドワーク -日雇い労働者の街,釜ヶ崎とその周辺を歩く
    長野 八久
    日本の科学者 50(10), 26-31 (2015).
  5. エンゲル・リード 物理化学(上)(T. Engel and P. Reid 著;Physical Chemistry (3rd Edition))
    稲葉 章(訳)B5 版,584 頁
    東京化学同人 (2015 年 6 月 25 日発行).

  1. Phase Transitions Due to Charge Transfer in Mixed-Valence Assembled Metal Complexes, A[FeIIFeIII(dto)3] (A = (n-CnH2n+1)4N, Spiropyran; dto = C2O2S2)
    N. Kojima, M. Itoi, and Y. Miyazaki
    Curr. Inorg. Chem. 4(2), 85-99 (2014).
  2. Low-Temperature Thermal Properties of Channel Water Confined in Nanopores with Hydrophilic Crystalline and Silica Non-Crystalline Walls
    K. Watanabe, A. Nagoe, and M. Oguni
    Curr. Inorg. Chem. 4(3), 167-179 (2014).
  3. Calorimetry of Low-Dimensional Metal-Assembled Complexes
    Y. Miyazaki
    Curr. Inorg. Chem. 4(3), 180-190 (2014).
  4. 分子集合体の多彩さに魅せられて―幻の秩序氷を求めて
    菅 宏
    化学 69(9), 47-51 (2014).
  5. 単一分子磁石の磁化反転緩和と熱測定
    中野 元裕
    熱測定 41(3), 113-119 (2014).
  6. 平和研究入門 人間性の起源と暴力の克服
    長野 八久(木戸 衛一(編))A5 版,300 頁
    大阪大学出版会(2014 年 4 月発行).
  7. アトキンス 生命科学のための物理化学(第 2 版)(P. W. Atkins and J. de Paula 著;Physical Chemistry for the Life Sciences (2nd Edition))
    稲葉 章,中川 敦史(訳)B5 版,624 頁
    東京化学同人(2014 年 9 月 1 日発行).
  8. Editorial-Calorimetry of Functional Inorganic Materials: Part I
    M. Sorai and Y. Nakazawa
    Curr. Inorg. Chem. 4(1), 1 (2014).
  9. Editorial-Calorimetry of Functional Inorganic Materials: Part II
    M. Sorai and Y. Nakazawa
    Curr. Inorg. Chem. 4(2), 73 (2014).
  10. Editorial-Calorimetry of Functional Inorganic Materials: Part III
    M. Sorai and Y. Nakazawa
    Curr. Inorg. Chem. 4(3), 145 (2014).