論文発表 | 研究業績 | 大阪大学高等共創研究院・大学院理学研究科高分子科学専攻高分子材料設計学

Synergetic improvement in the mechanical properties of polyurethanes with movable crosslinking and hydrogen bonds
Jin, C.; Park, J.; Shirakawa, H.; Osaki, M.; Ikemoto, Y.; Yamaguchi, H.; Takahashi, H.; Ohashi, Y.; Harada, A.; Matsuba, G.; Takashima, Y.
Soft Matter 2022, accepted.
(DOI:10.1039/D2SM00408A)
Supramolecular Nylon-Based Actuators with a High Work Efficiency Based on Host-Guest Complexation and Mechanoisomerization of Azobenzene.
Park, J.; Tamura, H.; Yamaguchi, H.; Harada, A.; Takashima, Y.
Polym. J. 2022,, 1-11.
(DOI:10.1038/s41428-022-00666-4)
Fabrication and Mechanical Properties of Knitted Dissimilar Polymeric Materials with Movable Cross-Links.
Ikura, R.; Murayama, S.; Park, J.; Ikemoto, Y.; Osaki, M.; Yamaguchi, H.; Harada, A.; Matsuba, G.; Takashima, Y.
Molecular Systems Design & Engineering, 2022, accepted.
(DOI:10.1039/D2ME00016D)
One-step synthesis of gelatin-conjugated supramolecular hydrogels for dynamic regulation of adhesion contact and morphology of myoblasts.
Hayashi, K; Matsuda, M.; Mitake, N.; Nakahata, M.; Munding, N.; Harada, A.; Kaufmann, S.; Takashima, Y.; Tanaka, M.
ACS Appl. Polym. Mater., 2022, 4, 2595-2603.
(DOI:10.1021/acsapm.1c01902)
Design of Self-Healing and Self-Restoring Materials Utilizing Reversible and Movable Crosslinks.
Ikura, R.; Park, J.; Osaki, M.; Yamaguchi, H.; Harada, A.; Takashima, Y.
NPG Asia Mater., 2022, 14:10, 1-17.
(DOI:10.1038/s41427-021-00349-1)
Preparation of Dual Cross-Network Polymers by Knitting Method and Evaluation of Their Mechanical Properties.
Kawai, Y.; Park, J.; Ishii, Y.; Urakawa, O.; Murayama, S.; Ikura, R.; Osaki, M.; Ikemoto, Y.; Yamaguchi, H.; Harada, A.; Inoue, T.; Washizu, H.; Matsuba, G.; Takashima, Y.
NPG Asia Mater., 2022, 14:32, 1-11
(DOI:10.1038/s41427-021-00348-2)
Cellulose Nanofiber Composite Polymeric Materials with Reversible and Movable Crosslinks and Evaluation of Their Mechanical Properties.
Tsuchiya, H.; Asaki, Y.; Sinawang, G.; Asoh, T.; Osaki, M.; Park, J.; Ikemoto, Y.; Yamaguchi, H.; Harada, A.; Uyama, H.; Takashima, Y.
ACS Appl. Polym. Mater. 2022, 4, 403-412.
(DOI:10.1021/acsapm.1c01332)
Behavior of Supramolecular Cross-Links Formed by Host-Guest Interaction in Hydrogels Responding to Water Contents.
Ueda, C.; Park, J.; Hirose, K.; Konishi, S.; Ikemoto, Y.; Osaki, M.; Yamaguchi, H.; Harada, A.; Tanaka, M.; Watanabe, G.; Takashima, Y.
Supramol. Mater., 2022, 1, 100001.
(DOI:10.1016/j.supmat.2021.100001)
Time-strain inseparability in multiaxial stress relaxation of supramolecular gels formed via host-guest interactions.
Kimura, T.; Aoyama, T.; Nakahata, M.; Takashima, Y.; Tanaka, M.; Harada, A.; Urayama, K.;
Soft Matter, 2022, accepted
(DOI:10.1039/d2sm00285j)
Design of molecularly imprinted hydrogels with thermoresponsive drug binding sites.
Toyoshima, Y.; Kawamura, A.; Takashima, Y.; Miyata, T.;
J. Mater. Chem. B, 2022, accepted
(DOI:10.1039/d2tb00325b)
Thermoresponsive Hydrogels Reinforced with Supramolecular Cellulose Filler.
Sugawara, A.; Asoh, T.; Takashima, Y.; Harada, A.; Uyama, H.;
Chemisty Letters, 2022, 51, 145-148.
(DOI:10.1246/cl.210658)
State- and Water Repellency-Controllable Molecular Glass of Pillar[5]arene with Fluoroalkyl Groups by Guest Vapor.
Onishi, K.; Ohtani, S.; Kato, K.; Fa, S.; Sakata, Y.; Akine, S.; Ogasawara, M.; Asakawa, H.; Nagano, S.; Takashima, Y.; Mizuno, M.; Ogoshi, T.
Chem. Sci., 2022, 13, 4082-4087.
(DOI:10.1039/D2SC00828A)

Mechanical Properties with Respect to Water Content of Host-Guest Hydrogels.
Osaki, M.; Yonei, S.; Ueda, C.; Ikura, R.; Park, J.; Yamaguchi, H.; Harada, A.; Tanaka, M.; Takashima, Y.
Macromolecules, 2021, 54, 8067-8076.
(DOI:10.1021/acs.macromol.1c00970)
Material Adhesion through Direct Covalent Bond Formation Assisted by Noncovalent Interactions.
Osaki, M.; Sekine, T.; Yamaguchi, H.; Takashima, Y.; Harada A.
ACS Appl. Polym. Mater. 2021, 3, 2189-2196.
(DOI:10.1021/acsapm.1c00223)
Preparation and Activity of Ruthenium Catalyst based on β-Cyclodextrin for Ring-Opening Metathesis
Yoshida, D.; Sinawang, G.; Osaki, M.; Yamaguchi, H.; Harada A.; Takashima, Y.
Tetrahedron Lett. 2021, 63, 152712.
(DOI:10.1016/j.tetlet.2020.152712)
強靭でリサイクル可能な自己修復性超分子材料の表面保護コーティングへの応用
朴峻秀、原田明、髙島義徳
車載テクノロジー10月号(技術情報協会) 2021, 9, 90-95.
自己修復性ポリマーの基礎と設計
金昌明、朴峻秀、大﨑基史、原田明、髙島義徳
刺激応答性高分子の開発動向（Recent Development in Stimuli-Responsive Polymers）(シーエムシー出版) 2021, 第6章, 67-77.
(ISBN:978-4-7813-1611-6)
[総説]可逆性結合を用いた高分子材料の設計とその機能、応用
小西昴、以倉崚平、大﨑基史、原田明、髙島義徳
重合開始剤,硬化剤,架橋剤の選び方、使い方とその事例（技術情報協会） 2021, 第3章, 第20節, 383-395.
(ISBN:978-4-86104-840-1)
強靭でリサイクル可能な自己修復性超分子材料
大﨑基史、原田明、髙島義徳
ペトロテック（石油学会） 2021, 44(5), 348-352.
分子空間の精密制御を駆使した高分子材料の機能創製
髙島義徳
化学と工業０２（日本化学会） 2021, 74.
自己修復する強靭な超分子材料の新展開――可逆的な架橋構造が生みだす多彩な機能
大﨑基史、髙島義徳、原田明
化学（化学同人） 2021, 76, 51-55.
(定期刊行物コード:023902)
Supramolecular Polymers and Materials Formed by Host-Guest Interactions.
Harada, A.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.
Bull. Chem. Soc. Jpn., 2021, 94, 2381-2389.
(DOI:10.1246/bcsj.20210233)
Mechano-Responsive Hydrogels Driven by the Dissociation of a Host-Guest Complex
Sugawara, A.; Asoh, T.; Takashima, Y.; Harada, A.; Uyama, H.
ACS Macro Letters 2021, 10, 971-977.
(DOI:10.1021/acsmacrolett.1c00357)
Dynamics of the Topological Network Formed by Movable Crosslinks: Effect of Sliding Motion on Dielectric and Viscoelastic Relaxation Behavior.
Kashiwagi, Y.; Urakawa, O.; Zhao, S.; Takashima, Y.; Harada A.; Inoue T.
Macromolecules 2021, 54, 3321-3333.
(DOI:10.1021/acs.macromol.0c02568)
Molecule‐Responsive Polymer Monolith as a Smart Gate Driven by Host-Guest Interaction with Morphology Restoration
Mizuno, S.; Asoh, T.; Takashima, Y.; Harada, A.; Uyama, H.
Macromol. Chem. Phys. 2021, 222, 2000392.
(DOI:10.1002/macp.202000392)

Palladium nanoparticle loaded β-cyclodextrin monolith as flow reactor for concentration enrichment and conversion of pollutants based on molecular recognition
Mizuno, S.; Asoh, T.; Takashima, Y.; Harada, A.; Uyama, H.
Chem. Commun. 2020, 56(92), 14408-14411.
(DOI:10.1039/D0CC06684B)
Design and mechanical properties of supramolecular polymeric materials based on host-guest interactions: the relation between relaxation time and fracture energy
Konishi, S.; Kashiwagi, Y.; Watanabe, G.; Osaki, M.; Katashima, T.; Urakawa, O.; Inoue, T. ; Yamaguchi, H.; Harada, A.; Takashima, Y.
Polym. Chem. 2020, 11(42), 6811-6820.
(DOI:10.1039/D0PY01347A)
Extremely Rapid Self-healable and Recyclable Supramolecular Materials through Planetary Ball Milling and Host-guest Interactions.
Park, J.; Murayama, S.; Osaki, M.; Yamaguchi, H.; Harada, A.; Matsuba, G.; Takashima, Y.
Adv. Mater. 2020, 32(39), 2002008.
(DOI:10.1002/adma.202002008)
【EurekAlert!】【AlphaGalileo】
Mechanical stimulation of single cells by reversible host-guest interactions in 3D microscaffolds
Hippler, H.; Weißenbruch, K.; Richler, K.; Lemma, E.; Nakahata, M.; Richter, B.; Barner-Kowollik, C.; Takashima, Y.; Harada, A.; Blasco, E.; Wegener, M.; Motomu, T.; Martin, B.
Science Advances 2020, 6(39), eabc2648.
(DOI:10.1126/sciadv.abc2648)
Supramolecular biocomposite hydrogels formed by cellulose and host-guest polymers assisted by calcium ion complexes
Tsuchiya, H.; Sinawang, G.; Asoh, T.; Osaki, M.; Ikemoto, Y.; Higuchi, Y.; Yamaguchi, H.; Harada, A.; Uyama, H.; Takashima, Y.
Biomacromolecules 2020, 21(9), 3936-3944.
(DOI:10.1021/acs.biomac.0c01095)
Biofunctional Hydrogels Based on Host-Guest Interactions.
Sinawang, G.; Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Polym.J. 2020, 52, 839-859.
(DOI:10.1038/s41428-020-0352-7)
Photoresponsive Polymeric Actuator Cross-Linked by an 8-Armed Polyhedral Oligomeric Silsesquioxane.
Osaki, M.; Ito, K.; Ikemoto, Y.; Yamaguchi, H.; Chujo, Y.; Harada, A.; Tanaka, K.; Takashima, Y.
Eur. Polym. J. 2020, 2020(134), 109806.
(DOI:10.1016/j.eurpolymj.2020.109806)
Reinforced Polystyrene through Host-guest Interactions Using Cyclodextrin as An Additive.
Park, J.; Murayama, S.; Osaki, M.; Yamaguchi, H.; Harada, A.; Matsuba, G.; Takashima, Y.
Eur. Polym. J. 2020, 2020(134), 109807.
(DOI:10.1016/j.eurpolymj.2020.109807)
Composite hydrogels reinforced by cellulose-based supramolecular filler.
Sugawara, A.; Asoh, T.; Takashima, Y.; Harada, A.; Uyama, H.
Polym. Degrad. Stab. 2020, 2020(177), 109157.
(DOI:10.1016/j.polymdegradstab.2020.109157)
Self-Healing Thermoplastic Polyurethane Linked via Host-Guest Interactions.
Jin, C.; Sinawang, G.; Osaki, M.; Zheng, Y.; Yamaguchi, H.; Harada, A.; Takashima, Y.
Polymers 2020, 12(6), 1393.
(DOI:10.3390/polym12061393)
Citric-acid-modified Cellulose-based Tough and Self-healable Composite Formed by Two Kinds of Non-Covalent Bonding.
Sinawang, G.; Asoh, T.; Osaki, M.; Yamaguchi, H.; Harada, A.; Uyama, H.; Takashima, Y.
ACS Appl. Polym. Mater. 2020, 2(6), 2274-2283.
(DOI:10.1021/acsapm.0c00250)
Preparation of Hydrophilic Polymeric Materials with Movable Cross-Linkers and their Mechanical Property.
Ikura, R.; Ikemoto, Y.; Osaki, M.; Yamaguchi, H.; Harada, A.; Takashima, Y.
Polymer 2020, 196, 122465.
(DOI:10.1016/j.polymer.2020.122465)
Redox-responsive supramolecular polymeric networks having double-threaded inclusion complexes.
Aramoto, H.; Osaki, M.: Konishi, S.; Ueda, C.; Takashima, Y.; Harada, A.; Yamaguchi, H.
Chem.Sci. 2020, 11(17), 4322-4331
(DOI:10.1039/c9sc05589d)
Supramolecular self-healing materials from non-covalent cross-linking host-guest interactions.
Sinawang, G.; Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Commun. 2020, 56(32), 4381-4395
(DOI:10.1039/D0CC00672F)
Bulk Copolymerization of Host-Guest Monomers with Liquid-type Acrylamide Monomers for Supramolecular Materials Applications.
Okano, N.; Osaki, M.: Ikura, R.; Takashima, Y.; Yamaguchi, H.; Harada, A.
ACS Appl. Polym. Mater. 2020, 2(4), 1553-1560.
(DOI:10.1021/acsapm.9b01220)
Mechanical Polymeric Materials Based on Cyclodextrins as Artificial Muscles (Chapter 7)
Mechanically Responsive Materials for Soft Robotics, Koshima, H. Ed., Wiley-VCH. Weinheim, 2020, 177-208.
Harada, A.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.
(Print ISBN:9783527346202 , Online ISBN:9783527822201)
X-ray crystal structures of α-cyclodextrin-5-hydroxypentanoic acid, β-cyclodextrin-5-hydroxypentanoic acid, β-cyclodextrin-ε-caprolactone, and β-cyclodextrin-ε-caprolactam inclusion complexes.
Osaki, M.; Takashima, Y.; Kamitori, S.; Yamaguchi, H.; Harada, A.
J. Incl. Phenom. Macrocycl. Chem. 2020, 96(1-2), 93-99.
(DOI:10.1007/s10847-019-00953-3)

For more! (結晶構造ギャラリー)

[総説] ポリマーを用いた自己修復材料の動向とそのアプローチ
朴峻秀、大﨑基史、髙島義徳、原田明
日本画像学会誌 2020, 59(4), 395-403.
(DOI:10.11370/isj.59.395)

Supramolecular Elastomers with Movable Cross-Linkers Showing High Fracture Energy Based on Stress Dispersion
Ikura, R.; Park, J.; Osaki, M.; Yamaguchi, H.; Harada, A.; Takashima, Y.
Macromolecules 2019,52(18),6953-6962.
(DOI:10.1021/acs.macromol.9b01198)
Self-healing and shape-memory properties of polymeric materials cross-linked by hydrogen bonding and metal-ligand interactions
Kobayashi, Y.; Hirase, T.; Takashima, Y.; Harada, A.; Yamaguchi H.
Polym. Chem 2019,10(33),4519-4523.
(DOI:10.1039/C9PY00450E)
Mechanical and self-recovery properties of supramolecular ionic liquid elastomers based on host-guest interaction and correlation with ionic liquid content
Sinawang, G.; Kobayashi, Y.; Osaki, M.; Takashima, Y.; Harada, A.; Yamaguchi, H.
RSC Advances 2019,9(39),22295-22301.
(DOI:10.1039/C9RA04623B5)
Effect of Host-Guest Interaction on Swelling Behavior and Equilibrium Swollen State of Host-Guest Gel
Kashiwagi, Y.; Katashima, T.; Takashima, Y.; Harada, A.; Inoue, T.
J. Soc. Rheol. Jpn. 2019, 47(3), 99-104.
(DOI:10.1678/rheology.47.99)
Preparation of cyclodextrin-based porous polymeric membrane by bulk polymerization of ethyl acrylate in the presence of cyclodextrin
Kobayashi, Y.; Nakamitsu, Y.; Zheng, Y.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Polymer 2019, 2019(177), 208-213.
(DOI:10.1016/j.polymer.2019.06.015)
Preparation of Supramolecular Ionic Liquid Gels based on Host-Guest Interactions and Their Swelling and Ionic Conductive Properties
Sinawang, G.; Kobayashi, Y.; Yongtai, Z.; Takashima, Y.; Harada, A.; Yamaguchi, H.
Macromolecules 2019, 52(8), 2932-2938.
(DOI:10.1021/acs.macromol.8b02395)
Self-Healing Alkyl Acrylate-Based Supramolecular Elastomers Cross-Linked via Host-Guest Interactions
Nomimura, S.; Osaki, M.; Park, J.; Ikura, R.; Takashima, Y.; Yamaguchi H.; Harada, A.
Macromolecules 2019, 52(7), 2659-2668.
(DOI:10.1021/acs.macromol.9b00471)
Mechanical properties of supramolecular polymeric materials cross-linked by donor-acceptor interactions
Itano, M.; Kobayashi, Y.; Takashima, Y.; Harada, A.; Yamaguchi H.
Chem. Commun. 2019, 55(26), 3809-3812.
(DOI:10.1039/C9CC01472A)

Cyclodextrin cross-linked polymer monolith for efficient removal of environmental pollutants by flow-through method

Polym. Degrad. Stab.

2019

2019(160)

Polymeric Actuators Based on Structure Change of Supramolecules
Takashima, Y.; Osaki, M.; Harada, A.
Kogaku 2019, 48(2).
Light-Driven Moving Gel
Harada, A.; Takashima, Y.; Osaki, M.
化学工学 (化学工学会) 2019, 83(11).
Development of Supramolecular Materials by Using Cyclodextrins
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A
Fine Chemical 2019, 48(11), 19-25
(ISBN 0913-6150)
[総説] 超分子形成でキズを復元する自己修復高分子材料とその応用・展開
高島義徳、大崎基史、原田明
次世代のポリマー・高分子開発, 新しい用途展開と将来展望, - 生分解, 自己修復, 生物模倣, 刺激応答, 超分子, 医療用途など -
第2章第3節, 技術情報協会 2019
[総説] 新たな分子設計による自己修復材料の実現＜切ってもつながる、柔軟・強靭な新材料＞
大崎基史、高島義徳、原田明
プラスチックス 2019年7月号 2019, 70(7), 37-42
[総説] シクロデキストリンとフォトクロミック分子による光応答性高分子マテリアル
高島義徳、大崎基史、原田明
光機能性有機・高分子材料における新たな息吹, 第5編第3章, シーエムシー出版 2019
(ISBN 978-4-7813-1414-3)
Functional Materials Formed by Macroscopic Spramolecular Assemblies
Osaki, M.; Takashima, Y.; Harada, A.
CSJ Current Review, 超分子ポリマー 2019, 33, 164-173
(ISBN 978-4-7598-1393-7)

Solvent-Free Photoresponsive Artificial Muscles Rapidly Driven by Molecular Machines
Ikejiri, S.; Takashima, Y.; Osaki M.; Yamaguchi H.; Harada, A.
Journal of the American Chemical Society 2018, 140, 17308-17315.
(DOI:10.1021/jacs.8b11351)
Mechanical properties of supramolecular polymeric materials formed by cyclodextrins as host molecules and cationic alkyl guest molecules on the polymer side chain
Takashima, Y.; Otani K.; Kobayashi Y.; Aramoto H.; Nakahata M.; Yamaguchi H.; Harada, A.
Macromolecules 2018, 51(16), 6318-6326
(DOI:10.1021/acs.macromol.8b01410)
A Photoresponsive Polymeric Actuator Topologically Cross-Linked by Movable Units Based on a [2]Rotaxane
Takashima, Y.; Hayashi, Y.; Osaki, M.; Kaneko, F.; Yamaguchi, H.; Harada, A.
Macromolecules 2018, 56(12), 4688-4693
(DOI:10.1021/acs.macromol.8b00939)
Physical and adhesion properties of supramolecular hydrogels crosslinked by movable cross-linking molecule and host-guest interactions
Kobayashi, Y.; Zheng, Y.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chemistry Letters 2018, 47(11), 1387-1390
(DOI:10.1246/cl.180646)
Adhesion of dissimilar materials through host-guest interactions and its re-adhesion properties
Takashima, Y.; Shojima Y.; Sekine T.; Osaki M.; Kobayashi Y.; Yamaguchi H.; Sekito T.; Hatano K.; Nakajima K.; Harada, A.
Chemistry Letters 2018, 47(10), 1255-1257
(DOI:10.1246/cl.180528)
Formation of Inclusion Complexes of Poly(hexafluoropropyl ether)s with Cyclodextrins
Nomimura, S.; Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chemistry Letters 2018, 47, 322-325
(DOI:10.1246/cl.171112)
Control of the threading ratio of cyclic molecules in polyrotaxane consisting of poly(ethylene glycol) and a-cyclodextrins
Kobayashi, Y.; Nakamitsu, Y.; Zheng, Y.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chemical Communications 2018, 54, 7066-7069
(DOI:10.1039/C8CC01776J)
Visible chiral discrimination via macroscopic selective assembly
Zheng, Y.; Kobayashi, Y.; Sekine, T.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
Communications Chemistry 2018, 1, 4
(DOI:10.1038/s42004-017-0003-x)
Linear Viscoelastic Studies on a Transient Network Formed by Host-Guest Interaction
Kashiwagi, Y.; Katashima, T.; Nakahata, M.; Takashima, Y.; Harada, A.; Inoue, T.
Journal of Polymer Science Part B: Polymer Physics 2018, 56(15), 1109-1117
(DOI:10.1002/polb.20180033)
Functional Supramolecular Materials Formed by Non-covalent Bonds
Takashima, Y.; Kobayashi Y.; Osaki M.; Harada, A.
Designed Molecular Space in Material Science and Catalysis 2018, Chapter 9, 183-225., Springer
(ISBN 978-981-13-1256-4)
(DOI:10.1007/978-981-13-1256-4)
ポリロタキサンの高分子材料への応用
小林裕一郎、高島義徳、原田明
科学と工業 = Science and industry 2018, 92(10), 283-290.
ホストゲスト相互作用を利用した刺激応答性超分子材料
高島義徳、大崎基史、原田明
刺激応答性高分子ハンドブック(エヌ・ティーエス) 2018, 第1編第2章第9節.
分子接着技術を駆使した材料間接着
高島義徳、大崎基史、関根智子、庄島靖、原田明
日本接着学会誌 ADHESION 2018, 54(6), 201-211.

Dynamic Mechano-Regulation of Myoblast Cells on Supramolecular Hydrogels Cross-Linked by Reversible Host-Guest Interactions
Horning, M.#; Nakahata, M.#; Linke, P.; Yamamoto, A.; Veschgini, M.; Kaufmann, S.; Takashima, Y.; Harada, A.; Tanaka, M.
Scientific Reports 2017, 7, 7660.
(DOI:10.1038/s41598-017-07934-x)
(#co-first author)
Movable cross-linked polymeric materials from bulk polymerization of reactive polyrotaxane cross-linker with acrylate monomers
Koyanagi, K.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2017, 50, 5695-5700
(DOI:10.1021/acs.macromol.7b00797)
Multifunctional Stimuli-Responsive Supramolecular Materials with Stretching, Coloring, and Self-Healing Properties Functionalized via Host?Guest Interactions
Takashima, Y.; Yonekura, K.; Koyanagi, K.; Iwaso, K.; Nakahata, M.; Yamaguchi, H.; Harada, A.
Macromolecules, 2017, 50, 4144-4150
(DOI:10.1021/acs.macromol.7b00875)
Supramolecular Materials Cross-Linked by Host-Guest Inclusion Complexes: The Effect of Side Chain Molecules on Mechanical Properties
Takashima, Y.; Sawa, Y.; Iwaso, K.; Nakahata, M.; Yamaguchi, H.; Harada, A.
Macromolecules, 2017, 50, 3254-3261.
(DOI:10.1021/acs.macromol.7b00266)
Functioning via host-guest interactions
Takashima, Y.; Harada, A.
J. Incl. Phenom. Macrocycl. Chem. 2017, 87, 313-330.
(DOI:10.1007/s10847-017-0702-z)
Cyclodextrin
Hashidzume, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Comprehensive Supramolecular Chemistry II; Elsevier: Oxford, 2017, 269-316.
(DOI:10.1016/B978-0-12-409547-2.13829-6)
Supramolecular Polymeric Materials Containing Cyclodextrins
Nakahata, M.; Takashima, Y.; Harada, A.
Chem. Pharm. Bull. 2017, 65(4), 330-335
(DOI: 10.1248/cpb.c16-00778)
非共有結合と共有結合を利用した材料間の直接接着
高島義徳、関根智子、原田明
表面科学 2017, 38,2, 61-66.
(DOI: 10.1380/jsssj.38.61)
光に応答する超分子マテリアル
原田明、高島義徳
化学と工業 2017, 70(4), 333-335.
超分子研究会アニュアルレビュー 2017.

Fast response dry-type artificial molecular muscles with [c2]daisy chains
Iwaso, K.; Takashima, Y.; Harada, A.
Nat. Chem. 2016, 8, 625-632.
(DOI:10.1038/nchem.2513)
Self-healing materials formed by cross-linked polyrotaxanes with reversible bonds
Nakahata, M.; Mori, S.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem 2016, 1, 766-775.
Highlighted in Chem
(DOI:10.1016/j.chempr.2016.09.013)
Highly Flexible, Tough, and Self-Healing Supramolecular Polymeric Materials Using Host?Guest Interaction
Nakahata, M.; Takashima, Y.; Harada, A.
Macromol. Rapid Commun. 2016, 37, 86-92.
(DOI:10.1002/marc.201500473)
Radical polymerization by supramolecular catalyst: cyclodextrin with a RAFT reagent
Koyanagi, K.; Takashima, Y.; Nakamura, T.; Yamaguchi, H.; Harada, A.
Beilstein J. Org. Chem. 2016, 12, 2495-2502.
(DOI:10.3762/bjoc.12.244)
Direct Adhesion of Dissimilar Materials Using Sonogashira Cross-coupling Reaction
Sekine, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Lett. 2016, 45, 1250-1252.
(DOI:10.1246/cl.160637)
共有結合形成を利用した異種材料間の直接接着
高島義徳、原田明
エレクトロニクス実装学会誌 2016, 2, 103-110.

Manual control of catalytic reactions: Reactions by an apoenzyme gel and a cofactor gel
Kobayashi, Y,: Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
Scientific Reports, 2015, 5, 16254
(DOI:10.1038/srep16254)
Self-healing, Expansion-Contraction, and Shape-Memory Properties of Preorganized Supramolecular Hydrogel through Host-Guest Interactions
Miyamae, K.; Nakahata, M.; Takashima, Y.; Harada, A.
Angew. Chem. Int. Ed, 2015, 54, 8984-8987
(DOI:10.1002/anie.201502957)
Direct Covalent Bond Formation between Materials Using Copper(I)-Catalyzed Azide Alkyne Cycloaddition Reactions
Sekine, T.; Takashima, Y.; Harada, A.
RSC Advances, 2015, 5, 56130-56135
(DOI:10.1039/C5RA08553E)
Macroscopic Self-assembly Based on Complementary Interaction between Nucleobase Pairs
Nakahata, M.; Takashima, Y.; Hashidzume, A.; Harada, A.
Chem. Eur. J., 2015, 21(7), 2770-2774
(DOI:10.1002/chem.201404674)
Adhesion between Semihard Polymer Materials Containing Cyclodextrin and Adamantane Based on Host?Guest Interactions
Kakuta, T.; Takashima, Y.; Sano, T.; Nakamura, T.; Kobayashi, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2015, 48, 732-738.
(DOI:10.1021/ma502316d)
高分子側鎖におけるホスト-ゲスト相互作用を利用した酸化還元応答性超分子材料の創製
中畑雅樹、高島義徳、橋爪章仁、山口浩靖、原田明
高分子論文集 2015, 72, 573-581.
(DOI:10.1295/koron.2015-0019)
ソフトマテリアル界面における共有結合形成を利用した接着
関根智子、高島義徳、橋爪章仁、山口浩靖、原田明
高分子論文集 2015, 72, 590-596.
(DOI:10.1295/koron.2015-0040)
超分子構造に基づく自己修復
中畑雅樹、高島義徳、原田明
日本画像学会誌 2015, 213-220.
(DOI:10.11370/isj.54.213)
刺激応答性超分子材料の機能とその動向
高島義徳、中畑雅樹、関根智子、原田明
塗装工学 2015, VOL.50 NO. 4 120(20).
シクロデキストリンの分子認識による自己修復ゲル
高島義徳、原田明
糖鎖の新機能開発応用ハンドブック～創薬・医療から食品開発まで～秋吉一成（京都大学）監修　第2章第10節, NTS出版 2015
(ISBN: 978-4-86043-409-0)

A Metal-Ion-Responsive Adhesive Material via Switching of Molecular Recognition Properties
Nakamura, T.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
Nature Communications 2014, 5, 4622.
(DOI:10.1038/ncomms5622)
Supramolecular Polymeric Materials via Cyclodextrin?Guest Interactions
Harada, A.; Takashima, Y.; Nakahata, M.
Acc. Chem. Res. 2014, 47 (7), 2128?2140.
(DOI:10.1021/ar500109h)
Redox?Responsive Macroscopic Gel Assembly Based on Discrete Dual Interactions
Nakahata, M.; Takashima, Y.; Harada, A.
Angew.Chem,Int.Ed. 2014, 53(14), 3617-3621.
(DOI:10.1002/anie.201310295)
A Macroscopic Reaction: Direct Covalent Bond Formation between Materials Using a Suzuki-Miyaura Cross-Coupling Reaction
Sekine, T.; Kakuta, T.; Nakamura, T.; Kobayashi, Y.; Takashima, Y.; Harada, A.
Scientific Reports. 2014, 4, 6348.
(DOI:10.1038/srep06348)
pH^- and Sugar-Responsive Gel Assemblies Based on Boronate-Catechol Interactions
Nakahata, M.; Mori, S.;Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
ACS Macro Lett., 2014, 3, 337-340.
(DOI:10.1021/mz500035w)
Supramolecular Adhesives to Hard Surfaces: Adhesion between Host Hydrogels and Guest Glass Substrates through Molecular Recognition
Takashima, Y.; Sahara, T.; Sekine, T.; Kakuta, T.; Nakahata, M.; Otsubo, M.: Kobayashi, Y.; Harada, A.
Macromol.Rapid Commun., 2014, 35(19), 1646-1652.
(DOI:10.1002/marc.201400324)
Cover Picture

シクロデキストリンによるホストーゲスト相互作用を用いた自己修復ポリマーの開発
原田明・高島義徳・中畑雅樹・岩曽一恭・畠中省伍
月刊ファインケミカル, 2014, 12月号.
刺激に応じて形態の変化する超分子ゲルアクチュエータ
原田明・高島義徳・中畑雅樹・岩曽一恭・畠中省伍
精密工学会誌, 2014, 80(8), 722.
シクロデキストリンを触媒とする高分子合成
原田明・高島義徳
高分子, 2014, 63, 174-175.
非共有結合を利用した超分子材料の作製ー自己修復性材料及びアクチュエータ材料への展開
高島義徳
化学と工業, 2014, 67(3), 248-249.
分子認識ゲル
原田明・高島義徳・中畑雅樹
ゲルテクノロジーハンドブック　中野義夫(東京工業大学)監修, 第7章第2節, 209, NTS出版, 2014.
ISBN: 978-4-86469-074-4.
トポロジカル超分子
高島義徳・原田明
高分子ナノテクノロジーハンドブック～最新ポリマーABC, 第2編第3章第1節, NTS出版, 2014.
ISBN: 978-4-86043-410-6.
非共有結合型ポリマー
高島義徳・原田明
化学便覧応用科学編第7版, 5.3.5, 日本化学会編, 丸善出版株式会社, 2014.
ISBN: 978-4-621-08759-6.

Redox‐Generated Mechanical Motion of a Supramolecular Polymeric Actuator Based on Host?Guest Interactions
Nakahata, M.,: Takashima, Y.; Hashidzume, A.; Harada, A
Angew.Chem,Int.Ed. 2013, 52(22), 5731-5735.
(10.1002/anie.201300862)
Preorganized Hydrogel: Self-Healing Properties of Supramolecular Hydrogels Formed by Polymerization of Host?Guest-Monomers that Contain Cyclodextrins and Hydrophobic Guest Groups
Kakuta, T,: Takashima, Y.; Nakahata, M.; Otsubo, M,; Yamaguchi, H.; Harada, A
Adv. Mater. 2013, 25, 2849-2853.
Inside Front Cover
(DOI:10.1002/adma.201205321)
Reversible self-assembly of gels through metal-ligand interactions
Kobayashi, Y,: Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A
Scientific Reports 2013, 3, 1243.
(DOI:10.1038/srep01243)
Macroscopic Self-Assembly Based on Molecular Recognition: Effect of Linkage between Aromatics and the Polyacrylamide Gel Scaffold, Amide versus Ester
Hashidzume, A.; Zheng, Y.; Takashima, Y.; Yamaguchi, H.; Harada, A
Macromolecules, 2013, 46, 1939?1947.
(DOI:10.1021/ma302344x)
Ring-Opening Metathesis Polymerization by a Ru Phosphine Derivative of Cyclodextrin in Water
Takashima, Y.; Uramatsu, K.; Jomori, D.; Harima, A; Otsubo, M; Yamaguchi, H.; Harada, A
ACS Macro Lett., 2013, 2, 384-387.
(DOI:10.1021/mz4001942)
Reversible self-assembly of gels through metal-ligand interactions
Kobayashi, Y,: Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
Scientific Reports 2013, 3, 1243.
(DOI:10.1038/srep01243)
Macroscopic Self-Assembly Based on Molecular Recognition: Effect of Linkage between Aromatics and thePolyacrylamide Gel Scaffold, Amide versus Ester
Hashidzume, A.; Zheng, Y.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2013, 46, 1939-1947.
(DOI:10.1021/ma302344x)

Photoswitchable gel assembly based on molecular recognition
Yamaguchi, H.;Kobayashi, Y.; Kobayashi, R.; Takashima,Y.; Hashidzume, A.; Harada, A.
Nature Communications 2012, 3, 603.
(DOI:10.1038/ncomms1617 )
Switching of macroscopic molecular recognition selectivity using a mixed solvent system
Zheng, Y.; Hashidzume, A.; Takashima, Y.; Yamaguchi, H.; Harada, A
Nature Communications 2012, 3, 831.
(DOI:10.1038/ncomms1841)
Expansion?contraction of photoresponsive artificial muscle regulated by host?guest interactions
Takashima, Y.; Hatanaka, S.; Otsubo, M.; Nakahata, M.; Kakuta, T.; Hashidzume, A.; Yamaguchi, H.; Harada, A
Nature Communications 2012, 3, 1270.
(DOI:10.1038/ncomms2280)
[Naute Com. Press releases Dec.11th]
Temperature-Sensitive Macroscopic Assembly Based on Molecular Recognition
Zheng, Y.; Hashidzume, A.; Takashima, Y.; Yamaguchi, H.; Harada, A
ACS Macro Letters 2012, 1, 1083-1085.
(DOI:10.1021/mz300338d)
Supramolecular Hydrogels Formed from Poly(viologen) Crosslinked with Cyclodextrin Dimers and Their Physical Properties
Takashima, Y.; Yang, Y.; Otsubo, M; Yamaguchi, H.; Harada, A
Beilstein J. Org. Chem. 2012, 8, 1594-1600.
(DOI:10.3762/bjoc.8.182)
Emission Properties of Cyclodextrin Dimers Linked with Perylenediimide - Effect of Cyclodextrin Tumbling
Takashima, Y.; Fukui, Y.; Otsubo, M.; Hamada, N.; Yamaguchi, H.; Yamamoto, H.; Harada, A.
Polymer Journal 2012, 44, 278-285.
(DOI:10.1038/pj.2011.128)
Cyclodextrin-Based Supramolecular Polymers
Harada, A.; Hashidzume, A.; Yamaguchi, H.; Takashima, Y.
"Polyrotaxanes" The 4th Edition, Encyclopedia of Polymer Science and Technology, 2012, in press.
(ISBN: 978-0-471-44026-0)
酸化還元反応に応答するゾル - ゲル変換材料の分子設計とその自己修復性
高島義徳、中畑雅樹、原田明
月刊ファインケミカル 2012年9月号
ホスト - ゲスト相互作用を利用した自己修復性超分子材料の構築とその刺激応答性
高島義徳、角田貴洋、中畑雅樹、原田明
日本ゴム協会誌 2012, 85 (8), 260-264.
分子認識を"この目で"見る - 巨視的世界で実現した超分子のホスト - ゲスト相互作用 -
原田明、山口浩靖、高島義徳、橋爪章仁
月刊化学 2012, 67 (6), 26-30.
自己組織化超分子ポリマーの機能化 - 分子認識に基づく特異的なゲル集積 -
山口浩靖、橋爪章仁、高島義徳、原田明
化学工業 2012, 63 (2), 96-104.
ホスト-ゲスト相互作用により機能化された自己修復性超分子マテリアルの構築
高島義徳、角田貴洋、中畑雅樹、原田明
化学工業 2012, 63 (6), 415-420.

Macroscopic Self-Assembly through Molecular Recognition
Harada, A.; Kobayashi, R.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.
Nature Chem. 2011, 3, 34-37.
[Nature.com] [Nature | Research Highlights] [RSC:Chemistry World]
Redox-responsive self-healing materials formed from host－guest polymers
Nakahata, M.; Takashima, Y.; Yamaguchi H.;Harada, A.
Nature Communications 2011, 2, 511.
(DOI:10.1038/ncomms1521)
[Natureasia:日本版]
Artificial Molecular Clamp: A Novel Device for Synthetic Polymerases
Takashima, Y.; Osaki, M.; Ishimaru, Y.; Yamaguchi, H.; Harada, A.
Angew. Chem. Int. Ed. 2011, 33, 7524-7528.
Hot paper : Back cover, [Nature | Research Highlights] [RSC:Chemistry World]
[RSC: Education in Chemistry, 2011, 48(5), "Distillates"]
Selective Photoinduced Energy Transfer from a Thiophene Rotaxane to Acceptor
Sakamoto, K.; Takashima, Y.; Hamada, N.; Ichida, H.; Yamaguchi, H.; Yamamoto, H.; Harada, A.
Org. Lett. 2011, 13 (4), 672-675.
Photoresponsive Formation of Pseudo[2]rotaxane with Cyclodextrin derivatives
Wang, Z.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Org. Lett. 2011, 13 (16), 4356-4359.
Self-Assembly of Gels through Molecular Recognition of Cyclodextrins: Shape Selectivity for Linear and Cyclic Guest Molecules
Yamaguchi, H.; Kobayashi, R.; Takashima, Y.; Hashidzume, A.; Harada, A.
Macromolecules 2011, 44 (8), 2395-2399.
Macroscopic Observations of Molecular Recognition: Discrimination of the Substituted Position on the Naphthyl Group by Polyacrylamide Gel Modified with β-Cyclodextrin
Zheng, Y.; Hashidzume, A.; Takashima, Y.; Yamaguchi, H.; Harada, A
Langmuir 2011, 27 (22), 13790-13795.
(DOI;10.1021/la2034142)
Double Threaded Dimer and Supramolecular Oligomer Formed by Stilbene Modified Cyclodextrin ? Effect of Acyl Migration and Photo Stimuli
Kanaya, A.; Takashima, Y.; Harada A.
J. Org. Chem. 2011, 76 (2), 492-499.
Photochemically-controlled Supramolecular Curdlan/Single-Walled Carbon Nanotube Composite Gel: Preparation of Molecular Distaff by Cyclodextrin Modified Curdlan and Phase Transition Control
Tamesue,S.; Takashima, Y.; Yamaguchi, H.;Shinkai, S.; Harada, A.
Eur. J. Org. Chem. 2011, 2801-2806.
Supramolecular Spherical b-Cyclodextrin32-Dendrimer: Inclusion Property and Supramolecular Structure
Takashima, Y.; Oka, T.; Yoshida, S.; Yamaguchi, H.; Harada, A.
Chem. Lett. 2011, 40, 742-743. [Editor's Choice]
pH Responsive [2] Rotaxanes with 6-Modified-a-Cyclodextrins
Omori, K.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Lett. 2011, 40, 758-759.
Cyclodextrin-Based Supramolecular Polymers
Harada, A.; Takashima, Y.
In "Supramolecular Polymer Chemistry" Ed. by Harada, A.Wiley-VCH, Weinhein, Germany, 29-50, 2011.
(ISBN:978-3-527-32321-0)
自己修復（キズ復元）材料の最新技術、メーカー採用のトレンド
原田明、高島義徳
技術情報協会, 2011.
光刺激応答性超分子マテリアル - ホスト-ゲスト相互作用を利用したヒドロゲルのゾルゲルスイッチング -
為末真吾、高島義徳、山口浩靖、新海征治、原田明
高分子論文集 2011, 68, 669-678.
(DOI:10.1295/ koron.68.669)
刺激応答性超分子マテリアルの構築とその性質
高島義徳、原田明
化学工業 2011, 62 (12), 903-909.

Photoswitchable Supramolecular Hydrogels Formed by Cyclodextrin and Azobenzene Polymers
Tamesue, S.; Takashima, Y.;Yamaguchi, H.; Shinkai, S.; Harada, A.
Angew. Chem. 2010, 122 (41), 7623-7626; Angew. Chem. Int. Ed. 2010, 49 (41), 7461-7464.
Switching from altro-α-Cyclodextrin Dimer to pseudo [1] Rotaxane Dimer through Tumbling
Yamauchi, K.; Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Org. Lett. 2010, 12 (6), 1284-1286.
A Molecular Reel: Shuttling of a Rotor by Tumbling of a Macrocycle
Yamauchi, K.; Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Org. Chem. 2010, 75 (4), 1040-1046.
[J. Org. Chem. Featured Article]
Photocontrolled Size Changes of Doubly-Threaded Dimer Based on an α-CD Derivative with Two Recognition Sites
Li, S.; Taura, D.; Hashidzume, A.; Takashima, Y.; Yamaguchi, H.; Harada A.
Chem. Lett. 2010, 39 (3), 242-243.

Polymeric Rotaxanes
Harada, A.; Hashidzume, A.; Yamaguchi, H.; Takashima, Y.
Chem. Rev. 2009, 109 (11), 5974-6023.
Cyclodextrin-Based Supramolecular Polymers
Harada, A.; Takashima, Y.; Yamaguchi, H.
Chem. Soc. Rev. 2009, 38,　875 - 882.
Social Self-Sorting: Alternating Supramolecular Oligomer Consisting of Isomers
Tomimasu, N.; Kanaya, A.; Takashima,Y.; Yamaguchi, H.; Harada, A.*
J. Am. Chem. Soc. 2009, 131 (34), 12339-12343.
Face Selective Translation of a Cyclodextrin Ring along an Axle
Oshikiri, T.; Yamaguchi, H.; Takashima, Y.; Harada, A.
Chem. Commun. 2009, (37), 5515-5517.
[Chem. Commun. Hot Article !!] [A News Release] [A News Release]
Cover Picture: Chem. Commun.
Nanospheres with Polymerization Ability Coated by Polyrotaxane
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Org. Chem. 2009, 74 (5), 1858-1863.
Switching of Polymerization Activity of Cinnamoyl-alpha-Cyclodextrin
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Org. Biomol. Chem. 2009, 7, 1646 - 1651.
Supramolecular Assemblies of Oligothiophene Derivatives Bearing β-Cyclodextrin
Sakamoto, K.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Synthetic Metals 2009, 159 (9-10), 977-981.
共役高分子の超分子形成による機能化に関する研究
高島義徳、原田明
次世代共役ポリマーの超階層制御と革新機能、赤木和夫監修、CMC出版, 2009, 88-96.
切れてもつながるゴム?！
高島義徳、原田明
化学、化学同人, 2009, 2, 59-60.
シクロデキストリンによる包接と超分子形成
高島義徳、原田明
超分子サイエンス＆テクノロジー ‐基礎からイノベーションまで‐、国武豊喜監修, NTS, 2009, 105-118.

Ring-Opening Polymerization of Cyclic Esters by Cyclodextrins
Harada, A.; Osaki, M.; Takashima, Y.; Yamaguchi, H.
Acc. Chem. Res. 2008, 41 (9), 1143-1152.
Single-Molecular Imaging of Rotaxane Based on Glass Substrates : Observations of Rotary Movement of a Rotor
Nishimura, D.; Takashima, Y.; Aoki, H.; Takahashi, T.; Yamaguchi, H.; Ito, S.; Harada, A.
Angew. Chem. Int. Ed. 2008, 47 (32), 6077-6079.
[Angew. Chem. News Release] [Science Daily News Release] [Nano Werk News Release] [Nanotechwire News Release] [Innovations report News Release] [Medical News Today News Release]
Molecular Puzzle Ring: pseudo[1]Rotaxane from a Flexible Cyclodextrin Derivative
Miyawaki, A.; Kuad, P.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2008, 130, 17062-17069.
Switching between Supramolecular Dimer and Non-Threaded Supramolecular Self-Assembly of Stilbene Amide alpha-Cyclodextrin by Photoirradiation
Yamauchi, K.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2008, 130 (15), 5024-5025.
Formation of Supramolecular Isomers; Poly[2]rotaxane and Supramolecular Assembly
Miyawaki, A.; Miyauchi, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Commun. 2008, (4), 456 - 458.
Relative Rotational Motion between alpha-Cyclodextrin Derivatives and a Stiff Axle Molecule
Nishimura, D.; Oshikiri, T.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.; Harada, A.
J. Org. Chem. 2008, 73 (7), 2496-2502.
Stereo Selective Complex Formation between Polybutadiene and Cyclodextrins in Bulk
Kuratomi, Y.; Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromol. Rapid Commun. 2008, 29 (11), 910-913.
Branched Supramolecular Polymers Formed by Bifunctional Cyclodextrin Derivatives
Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Tetrahedron 2008, 64, 8355-8361.
Construction of Chemical-Responsive Supramolecular Hydrogels from Guest-Modified Cyclodextrins
Deng, W.; Yamaguchi, H.; Takashima, Y.; Harada, A.
Chem. Asian J. 2008, 3 (4), 687-695.
Cover Picture: Chemistry An Asian Journal p.639.
Preparation and Properties of Polyrotaxanes Formed by Cyclodextrins and Oligo(thiophene)s : Effect of Insulating Cyclodextrins
Takashima, Y.; Sakamoto, K.; Yamaguchi, H.; Kamitori, S.; Harada, A.
"In Chemistry, Physics, and Biology in Macromolecular Science," Proceedings of OUMS '07, Takahiro Sato, Eds., Osaka University Press, Suita, Osaka, Japan, 2008, 13-29.

A Chemical-Responsive Supramolecular Hydrogel from Modified Cyclodextrins
Deng, W.; Yamaguchi, H.; Takashima, Y.; Harada, A.
Angew. Chem. Int. Ed. 2007, 46 (27), 5144-5147.
An Artificial Molecular Chaperone: Poly-pseudo-rotaxane with an Extensible Axle
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2007, 129 (46), 14452-14457.
External Stimulus-Responsive Supramolecular Structures Formed by a Stilbene Cyclodextrin Dimer
Kuad, P.; Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2007, 129 (42), 12630-12631.
Thermal and Photochemical Switching of Conformation of Poly(ethylene glycol)-Substituted Cyclodextrin with an Azobenzene Group at the Chain End
Inoue, Y.; Kuad, P.; Okumura, Y.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2007, 129 (20), 6396-6397.
Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs and Cyclodextrins
Ogoshi, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2007, 129 (16), 4878-4879.
Face Selective [2] and [3] Rotaxanes: Kinetic Control of Threading Direction of Cyclodextrins
Oshikiri, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Eur. J. 2007, 13 (25), 7091-7098.
Contraction of Supramolecular Double-Threaded Dimer Formed by alpha-Cyclodextrin with a Long Alkyl Chain
Tsukagoshi, S.; Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Org. Lett. 2007, 9 (6), 1053-1055.
Preparation and Properties of Rotaxanes Formed by Dimethyl-beta-cyclodextrin and Oligo(thiophene)s with beta-Cyclodextrin Stoppers
Sakamoto, K.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Org. Chem. 2007, 72 (2), 459-465.
Self-Threading and Dethreading Dynamics of Poly(ethylene glycol)-Substituted Cyclodextrins with Different Chain Lengths
Inoue, Y.; Miyauchi, M.; Nakajima, H.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2007, 40 (9), 3256-3262.
Polymerization of Lactones Initiated by Cyclodextrins: Effects of Cyclodextrins on the Initiation and Propagation Reactions
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2007, 40 (9), 3154-3158.
Supramolecular Polymers Formed by Bifunctional Cyclodextrin Derivatives
Miyawaki, A.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Lett. 2007, 36 (7), 828-829.
Polymerization of Lactones and Lactides Initiated by Cyclodextrins
Osaki, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Kobunshi Ronbunshu, 2007, 64 (10), 607-616.

Cyclodextrin-Based Supramolecular Polymers
Harada, A.; Hashidzume, A.; Takashima, Y.
Adv. Polym. Sci. 2006, 201, 1-43.
Self-Threading of a Poly(ethylene glycol) Chain in a Cyclodextrin-Ring: Control of the Exchange Dynamics by Chain Length
Inoue, Y.; Miyauchi, M.; Nakajima, H.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2006, 128 (28), 8994-8995.
Cyclodextrin-Grafted Poly(phenylene ethynylene) with Chemical-Responsive Properties
Ogoshi, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Chem. Commun. 2006, (35), 3702-3704.
Selection between Pinching-Type and Supramolecular Polymer-Type Complexes by alpha-Cyclodextrin-beta-Cyclodextrin Hetero-Dimer and Hetero-Cinnamamide Guest Dimers
Takahashi, H.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Org. Chem. 2006, 71 (13), 4878-4883.
Spectroscopic Study on the Interaction of Cyclodextrins with Naphthyl Groups Attached to Poly(acrylamide) Backbone
Harada, A.; Ito, F.; Tomatsu, I.; Shimoda, K.; Hashidzume, A.; Takashima, Y.; Yamaguchi, H.; Kamitori, S.
J. Photochem. Photobiol., A 2006, 179 (1-2), 13-19.
Complex Formation of Cyclodextrins with Various Thiophenes and Their Polymerization in Water: Preparation of pseudo-Polyrotaxanes Containing Poly(thiophene)s
Takashima, Y.; Sakamoto, K.; Oizumi, Y.; Yamaguchi, H.; Kamitori, S.; Harada, A.
J. Incl. Phenom. Macrocycl. Chem. 2006, 56 (1-2), 45-53.
Syntheses of Group 4 Transition Metal Complexes Bearing 2-Pyridinethiolate Ligands and their Catalytic Activities for Ethylene Polymerization
Takashima, Y.; Nakayama, Y.; Hashiguchi, M.; Hosoda, T.; Yasuda, H.; Hirao T.; Harada, A.
Polymer 2006, 47 (16), 5762-5774.
Polymer Formation Utilizing 'Crisscross' Addition (Crisscross Addition Polymerization) of Acetaldehyde Azine and 1,4-Phenylene Diisocyanate
Hashidzume, A.; Shiota, J.; Ueno, Y.; Noda, T.; Takashima, Y.; Harada, A.; Kamachi, M.
Polymer 2006, 47 (2), 501-505.
Formation of Chiral Supramolecular Polymer Based on Modified Cyclodextrin by Host-Guest Interactions
Miyawaki, A.; Miyauchi, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Kobunshi Ronbunshu 2006, 63 (5), 306-314.
バイオインスパイアードマテリアル
原田明、山口浩靖、高島義徳
ファイバースーパーバイオミメティックス～近未来の新技術創成～第6編第2章第1節 2, NTS, 東京, 1086-1092.

Kinetic Control of Threading of Cyclodextrins onto Axle Molecules
Oshikiri, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2005, 127 (35), 12186-12187.
Chiral Supramolecular Polymers Formed by Host-Guest Interactions
Miyauchi, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
J. Am. Chem. Soc. 2005, 127 (9), 2984-2989.
Preparation of Supramolecular Polymers from a Cyclodextrin Dimer and Ditopic Guest Molecules: Control of Structure by Linker Flexibility
Ohga, K.; Takashima, Y.; Takahashi, H.; Kawaguchi, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2005, 38 (14), 5897-5904.
Cover Picture : Macromolecules 2005, 38 (20-26)
Supramolecular Polymers Formed from -Cyclodextrins Dimer Linked by Poly(ethylene glycol) and Guest Dimers
Hasegawa, Y.; Miyauchi, M.; Takashima, Y.; Yamaguchi, H.; Harada, A.
Macromolecules 2005, 38 (9), 3724-3730.
Supramolecular Polymers from a Cyclodextrin Dimer and Ditopic Guest Molecules
Ohga, K.; Takashima, Y.; Takahashi, H.; Miyauchi, M.; Kawaguchi, Y.; Yamaguchi, H.; Harada, A.
Chem. Lett. 2005, 34 (3), 320-321.

Cyclodextrin-Initiated Polymerization of Cyclic Esters in Bulk: Formation of Polyester-Tethered Cyclodextrins
Takashima, Y.; Osaki, M.; Harada, A.
J. Am. Chem. Soc. 2004, 126 (42), 13588-13589.
One-Pot Synthesis of g -Cyclodextrin Polyrotaxane: Trap of g -Cyclodextrin by Photodimerization of Anthracene-Capped pseudo-Polyrotaxane
Okada, M.; Takashima, Y.; Harada, A.
Macromolecules, 2004, 37 (19), 7075-7077.
Crystal Structure of the Complex of b-Cyclodextrin with Bithiophene and Their Oxidative Polymerization in Water
Takashima, Y.; Oizumi, Y.; Sakamoto, K.; Miyauchi, M.; Kamitori, S.; Harada, A.;
Macromolecules 2004, 37 (11), 3962-3964.
Complex Formation between Polyisoprene and Cyclodextrins
Michishita, T.; Takashima, Y.; Harada, A.
Macromol. Rapid Commun. 2004, 25 (12), 1159-1162.
Cover Picture: Macromol. Rapid Commun. 12/2004 (p 1129)
Bis(amino)titanium Complexes Having Chelating Diaryloxo Ligands Bridged by Sulfur or Methylene and Their Catalytic Behaviour for Ring-Opening Polymerization of Cyclic Esters
Takashima, Y.; Nakayama, Y.; Hirao, T.; Yasuda, H.; Harada, A.
J. Organomet. Chem. 2004, 689, 612-619.
Complex Formation and Gelation between Copolymers Containing Pendant Azobenzene Groups and Cyclodextrin Polymers
Takashima, Y.; Nakayama, T.; Miyauchi, M.; Kawaguchi, Y.; Yamaguchi, H.; Harada, A.
Chem. Lett. 2004, 33, 890-891.
レドックス制御による超分子構造形成
山口浩靖、高島義徳、原田明
化学, 2004, 59 (10), 72-73.

Inclusion Complex Formation and Hydrolysis of Lactones by Cyclodextrins
Takashima, Y.; Kawaguchi, Y.; Nakagawa, S.; Harada, A.
Chem. Lett., 2003, 32, 1122-1123.

Polymerizations of Cyclic Esters Catalyzed by Titanium Complexes Having Chalcogen-Bridged Chelating Diaryloxo Ligands.
Takashima, Y.; Nakayama, Y.; Watanabe, K.; Itono, T.; Ueyama, N.; Nakamura, A.; Yasuda, H.; Harada, A.
Macromolecules, 2002, 35, 7538-7544.
Steric Isomerization of Alkyne Dialkyltungsten Complexes with a Chelating Diaryloxo Ligand: Crystal Structures of Cs- and C1-W(h2-RCCR)[2,2'-S(4-Me-6-R'C6H2O)2](CH2SiMe3)2.
Takashima, Y.; Nakayama, Y.; Yasuda, H.; Nakamura, A.; Harada,
J. Organomet. Chem., 2002, 664, 234-244.
Synthesis of cis-Dichloride Complexes of Group 6 Transition Metal Complexes Bearing Alkyne and Chalcogen-Bridged Chelating Bis(aryloxo) Ligands as Catalyst Precursors for Ring-Opening Metathesis Polymerization.
Takashima, Y.; Nakayama, Y.; Yasuda, H.; Nakamura, A.; Harada, A.,
J. Organomet. Chem., 2002, 654, 74-82.
Synthesis of Novel Oxo Complexes of Tungsten and Molybdenum with Various Chalcogen-Bridged Chelating Bis(aryloxo) Ligands and their Catalytic Behavior for Ring-Opening Metathesis Polymerization.
Takashima, Y.; Nakayama, Y.; Yasuda, H.; Harada, A.
J. Organomet. Chem., 2002, 651, 114-123.
Ring-Opening Metathesis Polymerization by Tungsten Complexes with O,S,O- or O,N,O- Tridentate Chelating Ligands.
Takashima, Y.; Nakayama, Y.; Yasuda, H.; Nakamura, A.; Harada, A.
Kobunshi Ronbunshu, 2002, 59, 298-308.

Synthesis of a Novel Oxotungsten(VI) Complex Having a Chelating Bis(aryloxo) Ligand and its Catalytic Behavior for Ring-Opening Metathesis Polymerization.
Takashima, Y.; Nakayama, Y.; Harada, A.
Chem. Lett., 2001, 488-489.

高等共創研究院・大学院理学研究科
高分子科学専攻高分子材料設計学

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